Product Categories See All
Track Order Status
SDS Sheet 0052660Printer Friendly View
Safety Data Sheet | | Date of Issue: 02 FEB 10 |Revision Date: 11 MAR 15 |Revision Number: D Imperial Supplies Part Number: 0052660 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: 9-Volt Lithium Manganese Dioxide Batteries (TFSi Style) CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: 1.3. Name, Address, and Telephone of the Responsible Party Company Ultralife Corporation 2000 Technology Parkway Newark, NY 14513 Phone: 800-332-5000 1.4. Emergency Telephone Number Emergency |ChemTrec 800-424-9300 (US), 703-527-3887 (International) number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) This Ultralife| battery | product meets | the definition| of an article.| Under the | Globally | Harmonized | System of | Classification| and Labeling | of Chemicals | (GHS), | "Articles" as | defined in the| Hazard | Communication | Standard (29 | CFR 1910.1200)| of the | Occupational | Safety and | Health | Administration| of the United | States of | America, or by| similar | definition, | are outside | the scope of | the system. | [Rev. 2 (2007)| Part | 126.96.36.199.1]. | | | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) | | | | | | Signal Word (GHS-US) | Hazard Statements (GHS-US) |Do not open or disassemble. |Do not expose to fire or open flame. |Do not mix with batteries of varying sizes, |chemistries or types. |Do not puncture, deform, incinerate or heat above |60ÂºC (140ÂºF). Precautionary Statements | (GHS-US) | 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Manganese Dioxide, MnO2 |1313-13-9 |50-60 | Lithium Metal, Li |7439-93-2 |2-6 | Propylene Carbonate, C4H6O3 |108-32-7 |1-5 | Ethylene Carbonate, C3H4O3 |96-49-1 |1-5 | Ethyl Methyl Carbonate,C4H8O3 |623-53-0 |1-5 | Bis (Trifluoromethane) |90076-65-6 |1-5 | Sulfonimide | | | Lithium (LiTFSi) | | | Non-hazardous components |NA |25-35 | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Avoid inhaling any vented gases. Remove to fresh air immediately. If breathing is difficult, seek emergency medical attention. First-aid Measures After Skin Contact: Exposure to materials from a ruptured or otherwise damaged cell or battery may cause skin irritation. Flush immediately with water and wash affected area with soap and water. First-aid Measures After Eye Contact: Exposure to materials from a ruptured or otherwise damaged cell or battery may cause eye irritation. Flush immediately with copious amounts of water for at least 15 minutes; consult a physician immediately. First-aid Measures After Ingestion: Consult a physician or local poison control center immediately. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Copious amounts of cold water or water-based foam may be used to cool burning cells or batteries. Do not use warm or hot water. A carbon dioxide (CO2) extinguisher is also effective. For fires involving exposed, raw lithium metal (characterized by deep red flames), use only metal (Class D) fire extinguishers. Unsuitable Extinguishing Media: 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Cells or batteries that are damaged, opened or exposed to excessive heat/fire may flame or leak potentially hazardous organic vapors. Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Use a positive pressure self-contained breathing apparatus (SCBA) if cells or batteries are involved in a fire. Full fire fighting protective clothing is necessary. During water application, caution is advised as burning pieces of flammable particles may be ejected from the fire. Protection During Firefighting: SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: In the event a cell or battery is crushed; releasing its contents, rubber gloves must be used to handle all battery components. Avoid inhalation of any vapors that may be emitted. Damaged batteries that are not hot or burning should be placed in a sealed plastic bag or container. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Batteries are not designed to be recharged. Charging a primary cell or battery may result in electrolyte leakage and/or cause the cell or battery to flame. Never disassemble a battery or bypass any safety device. More than a momentary short circuit will generally reduce the battery service life. Batteries with fuses will no longer be functional after being shorted. Extended short-circuiting creates high temperatures in the cell. High temperatures can cause burns in skin or cause the cell to flame. Avoid reversing battery polarity within the battery assembly. To do so may cause cell to flame or to leak. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Batteries should be separated from other materials and stored in a non-combustible, well ventilated structure with sufficient clearance between walls and battery stacks. Do not place batteries near heating equipment, nor expose to direct sunlight for long periods. Do not store batteries above 60ÂºC (140ÂºF) or below -40ÂºC (-40ÂºF). Store batteries in a cool (below 25ÂºC (77ÂºF)), dry area that is subject to little temperature change. Elevated temperatures can result in reduced battery service life. Battery exposure to temperatures in excess of 130ÂºC (266ÂºF) will result in the battery venting flammable liquid and gases. Do not store batteries in a manner that allows terminals to short circuit. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters 8.2. Exposure Controls Appropriate Engineering |Under conditions of normal use, batteries do not Controls |emit hazardous or regulated substances. No |engineering controls are required for handling |batteries that have not been damaged. Personal Protective Equipment|Personal protective equipment for damaged batteries |should include chemical resistant gloves and safety |glasses. In the event of a fire, SCBA should be worn |along with thermally protective outer garments. Materials for Protective | Clothing | Hand Protection | Eye Protection | Skin and Body Protection | Respiratory Protection | Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State | Appearance |Rectangular pack Odor |None Odor Threshold |Not Applicable pH |Not Applicable Relative Evaporation Rate |Not Applicable (butylacetate=1) | Melting Point |Not Available Freezing Point | Boiling Point |Not Available Flash Point |Not Applicable Auto-ignition Temperature |Not Available Decomposition Temperature |Not Available Flammability (solid, gas) |Not Applicable Vapor Pressure |Not Applicable Relative Vapor Density at 20 Â°C |Not Applicable Relative Density |Not Available Specific Gravity | Solubility |Not Applicable Partition coefficient: |Not Applicable n-octanol/water | Viscosity |Not Applicable Lower Flammable Limit |Not Applicable Upper Flammable Limit |Not Applicable 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity 10.2 Chemical Stability Stable. 10.3 Possibility of Hazardous Reactions Hazardous Polymerization: Will Not Occur. 10.4 Conditions to Avoid It is not recommended that this product be stored above 60ÂºC (140ÂºF). 10.5 Incompatible Materials 10.6 Hazardous Decomposition Products Carbon Monoxide (CO), Hydrogen Fluoride (HF) and other VOC's. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: No toxicological impacts are expected under normal use conditions. The electrolytes contained in this cell or battery can irritate eyes with any contact. Prolonged contact of electrolytes with lung tissue, skin or mucous membranes may cause irritation. Detailed information regarding sensitization, carcinogenicity, mutagenicity or reproductive toxicity related to internal cell or battery components has not been included in this document. Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: Germ Cell Mutagenicity: Carcinogenicity: Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity No ecological impacts expected under normal use conditions. Detailed information regarding the ecological impact of internal cell or battery components has not been included in this document. 12.2. Persistence and Degradability 12.3. Bioaccumulative Potential 12.4. Mobility in Soil 12.5. Other Adverse Effects SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Do not dispose in fire. Battery disposal regulations vary on national, state/provincial and local bases. Additional Information: Disposal must be conducted in accordance with the applicable regulations. These batteries contain recyclable materials and recycling is encouraged over disposal. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Lithium metal batteries, packed with equipment Hazard Class |9 |<PICTOGRAM PHRASE> Identification Number|UN 3091 | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |Lithium metal batteries, contained in equipment Hazard Class |9 Identification Number|UN 3091 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Lithium metal batteries Identification Number|UN 3090 |<PICTOGRAM PHRASE> Hazard Class |9 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> Hazard Communication Standard (29 CFR 1910.1200): Article. CERCLA SECTION 304 Hazardous Substances: NA. EPCRA SECTION 302 Extremely Hazardous Substance: NA. EPCRA SECTION 313 Toxic Release Inventory: NA. EPCRA SECTION 312: NA. SARA Section 311/312 Hazard Classes | Toxic Substances Control Act (TSCA) |Components Listed on US Toxic Substances |Control Act (TSCA): Yes. 15.2 US State Regulations <COMPONENT> California Prop 65 Classification: None. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |11 MAR 15 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.