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Material Safety Data Sheet | | Date of issue: |Revision Date: 2/27/2013 |Revision Number: 4/16/2010 | | Imperial Supplies Part Number: 0052650 1. PRODUCT AND COMPANY IDENTIFICATION Manufacturer: US Office Canadian Office Duracell, a P&G Business Duracell, a P&G Business Berkshire Corporate Park 4711 Young Street 14 Research Drive Toronto, Ontario Bethel, CT USA 06401 Canada M2N 6K8 Telephone: (203) 796-4000, (416) 730-4711 Emergency Phone: CHEMTREC Emergency Response Hotline 1-800-424-9300 (US & Canada) Product Name: Alkaline Batteries Product Code(s): ALK NA PSDS Recommended Use: UN-Number: Product Type: Consumer Product 2. HAZARDS IDENTIFICATION Appearance: Finished |Physical State: |Odor: consumer product - | | cylindrical battery | | with | | Duracell� label | | Potential Health Effects Principle Routes of Exposure Acute Effects: Eyes | Skin | Inhalation | Ingestion | Notes: CAUTION: Batteries may explode or leak, and cause burn injury, if recharged, disposed of in fire, mixed with a different battery type, inserted backwards or disassembled. Replace all used batteries at the same time. Do not carry batteries loose in your pocket or purse. Do not remove the battery label. Keep small batteries (i.e., AAA) away from children. If swallowed, consult a physician at once. For information on treatment, call (202) 625-3333 collect. Chronic Effects: Eyes | Skin | Inhalation | Ingestion | Notes: Aggravated Medical Conditions Environmental Hazard 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical/Ingredient Name |CAS-No |Weight% |ACGIH, |OSHA-PE|Other | | |TLV-TWA |L | Manganese Dioxide |1313-13-9 |35-40% |0.2 mg/m3 |5 mg/m3| | | |TWA |Ceiling| Zinc |7440-66-6 |10-25% | | | Potassium Hydroxide |1310-58-3 |5-10% |2 mg/m3 | | | | |Ceiling | | Graphite (natural or |7782-42-5; |1-5% |2 mg/m3 |Natural| synthetic) |7440-44-0 | |TWA |: 15 | | | | |mppcf | | | | |TWA | | | | | | | | | | | | | | | | Notes: The chemicals and metals in this product are contained in a sealed can. Exposure to the contents will not occur unless the battery leaks, is exposed to high temperatures or is mechanically, physically, or electrically abused. Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200. and/or WHMIS under the HPA: 4. FIRST AID MEASURES General Advice Eyes |Immediately flush eyes thoroughly with water for at |least 15 minutes. Seek medical attention if |irritation persists. Skin |Remove contaminated clothing and wash skin with soap |and water. If irritation persists, seek medical |attention. Inhalation |Move to fresh air. If irritation persists, seek |medical attention. Ingestion |Do not induce vomiting. Seek medical attention |immediately. CALL NATIONAL BATTERY INGESTION HOTLINE |at (202)-625-3333 collect, day or night. Notes to Physician | Protection of | First-aiders | Notes |Damaged battery will release concentrated potassium |hydroxide, which is caustic. 5. FIRE-FIGHTING MEASURES Flammability/Flammable | properties | Flash point | Recommended Extinguishing |Use any extinguishing media that is Media |appropriate for the surrounding area. Special Fire-Fighting | Procedures | | Explosion Data | Sensitivity to Mechanical | Impact | Sensitivity to Static | Discharge | | Specific Hazards from | Chemical | | Protective Equipment |Protection of Firefighters: Specific Hazards |Arising from the Material: Batteries may burst |and release hazardous decomposition products |when exposed to a fire situation. Protective |Equipment and Precautions for Firefighters: |Firefighters should wear positive pressure |self-contained breathing apparatus and full |protective clothing. NFPA |Health Hazard: |Flammability: |Instability:|Physical Hazard HMIS |Health Hazard: |Flammability: |Physical |PPE: | | |Hazard: | 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Notify safety personnel of large spills. Caustic potassium hydroxide may be released from leaking or ruptured batteries. Clean-up personnel should wear appropriate clothing to avoid eye and skin contact and inhalation of vapors and fumes. Ventilate area. Carefully collect batteries and place in an appropriate container for disposal. Environmental Precautions Methods for Containment Methods for Cleaning Up Notes 7. HANDLING AND STORAGE Handling: Avoid mechanical or electrical abuse. DO NOT short circuit or install incorrectly. Batteries may rupture or vent if disassembled, crushed, recharged or exposed to high temperatures. Install batteries in accordance with equipment instructions. Storage: Store batteries in a dry place at normal room temperature. Do not refrigerate - this will not make them last longer. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION NOT APPLICABLE - Finished consumer product Exposure Guidelines Chemical Name |ACGIH TLV |OSHA PEL |NIOSH IDLH |OTHER 1313-13-9 |0.2 mg/m3 TWA|5 mg/m3 | | Manganese Dioxide| |Ceiling | | 7440-66-6 |None |None | | Zinc |established |established | | |for zinc |for zinc metal| | |metal | | | 1310-58-3 |2 mg/m3 | | | Potassium |Ceiling | | | Hydroxide | | | | 7782-42-5; |2 mg/m3 TWA |Natural: 15 | |Synthetic: 7440-44-0 |(respirable |mppcf TWA OSHA| |5 mg/m3 TWA Graphite (natural|dust) |PEL | |(respirable or | | | | synthetic) | | | |dust), 15 | | | |mg/m3 TWA | | | |(total | | | |dust) OSHA | | | |PEL | | | |2 mg/m3 Engineering Measures Personal Protective Equipment Eyes/Face Protection| Skin and Body | Protection | Respiratory | Protection | Ventilation/Other | Hygiene Measures 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance |Finished |Odor | |consumer | | |product - | | |cylindrical | | |battery with | | |Duracell� | | |label | | Odor Threshold | |Physical State | Color | |Viscosity | pH | |Percent Volatile, | | |wt. % | Flash Point | |Auto-ignition | | |Temperature | Decomposition | |Boiling Point/ Range| Temp | | | Melting | |Freezing Point | Point/Range | | | Flammability | |Explosion Limits | Specific Gravity | |Water Solubility | Solubility | |Evaporation Rate | Vapor Pressure | |Vapor Density | VOC content, wt. |Not | | % |applicable - | | |Product not | | |regulated for| | |VOC Content | | |at State | | |or Federal | | |level | | | | | Notes 10. STABILITY AND REACTIVITY Chemical Stability |Finished consumer product - stable under normal |conditions of use. Incompatible Products |Contents are incompatible with strong oxidizing |agents. Conditions to avoid |Do not heat, crush, disassemble, short circuit |or recharge. Hazardous Decomposition |Thermal degradation may produce hazardous fumes Products |of zinc and manganese; hydrogen gas, caustic |vapors of potassium hydroxide and other toxic |by-products. Hazardous Polymerization | Notes 11. TOXICOLOGY INFORMATION Acute Toxicity Product |This battery product is a finished consumer product. It Information |is classified as an "article" and exempt under the |federal OSHA Hazard Communication standard. Inhalation | Eye Contact | Skin Contact | Ingestion | Chemical Name |LD50 Oral |LD50 Dermal |LC50 Inhalation 1313-13-9 |LD50 oral | | Manganese |rat>3478 mg/kg | | Dioxide | | | 7440-66-6 | | | Zinc | | | 1310-58-3 |LD50 oral rat | | Potassium |273 mg/kg | | Hydroxide | | | 7782-42-5; | | | 7440-44-0 | | | Graphite | | | (natural or | | | synthetic) | | | Chronic Toxicity |No chronic health effects reported. Chemical Name |ACGIH |IARC |NTP |OSHA | | | | | | | | Target Organ Effects: No target organs reported. 12. ECOLOGICAL INFORMATION Ecotoxicity The Environmental impact of this product has been fully investigated Chemical Name|Toxicity to |Toxicity to |Tox, to |Daphnia Magna |Algea |Fish |Microorganisms|(water flea) | | | | | | | | | | | | Notes: No eco-toxicity data are available. This product is not expected to present an environmental hazard. Duracell alkaline batteries do not contain any added mercury, cadmium or lead. 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods: Dispose of in compliance with federal, state/provincial and local regulations. Non-Household Setting (US Federal): Alkaline batteries covered by this PSDS, in their original form (finished consumer product), when disposed of as waste, are considered non-hazardous waste according to Federal RCRA regulation (40 CFR 261). Non-Household Setting (California): None Household Use: Alkaline batteries can be safely disposed of with normal household waste. Do not accumulate large quantities used batteries for disposal as accumulation could cause batteries to short-circuit. Do not incinerate. Contaminated Packaging US EPA Waste number Notes 14. TRANSPORTATION INFORMATION DOT UN-Number | Proper Shipping name| Hazard Class | Packing Group | Description |49 CFR172.102 Special Provision 130 Emergency Response | Guide Number | TDG UN-Number | Proper Shipping name| Hazard Class | Packing Group | Description | MEX | UN-Number | Proper Shipping name| Hazard Class | Packing Group | Description | ICAO UN-Number | Proper Shipping name| Hazard Class | Packing Group | Description |Special Provision A123 (54th Edition - 2013) The |words 'NOT RESTRICTED' and the 'Special Provision |A123' must be included on the description of the |substance on the Air Waybill, when air waybill is |issued. IATA UN-Number | Proper Shipping name| Hazard Class | Packing Group | ERG Code | Description |Special Provision A123 (54th Edition - 2013) The |words 'NOT RESTRICTED' and the 'Special Provision |A123' must be included on the description of the |substance on the Air Waybill, when air waybill is |issued. IMDG/IMO UN-Number | Proper Shipping name| Hazard Class | Packing Group | EmS No. | Description |NONE RID UN-Number | Proper Shipping name| Hazard Class | Packing Group | Classification Code | Description | ADR/RID-Labels | ADR UN-Number | Proper Shipping name| Hazard Class | Packing Group | Classification Code | Description | ADR/RID-Labels | ADN UN-Number Proper Shipping name Hazard Class Packing Group Classification Code Special Provisions Description Hazard Labels Limited Quantity 15. REGULATORY INFORMATION International Inventories TSCA: All intentionally-added components of this product are listed on the US TSCA Inventory. DSL EINECS ENCS IECSC PICCS AICS U.S. Federal Regulations SARA 313: Manganese compounds 35-40%; Zinc 10-25% SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Clean Water Act CERCLA U.S. State Regulations: California: This product has been evaluated and does not require warning labeling under California Proposition 65. U.S. State Right-to-Know Regulations: The following ingredients present in the finished product are listed on state right-to-know lists or state worker exposure lists: Ingredient CAS # Level CERCLA RQ State IL MA NJ PA RI Manganese Dioxide 1313-13-9 35-40% None Y Y N Y Y Zinc 7440-66-6 10-25% 1000 lbs Y Y Y Y N Potassium Hydroxide 1310-58-3 5-10% 1000 lbs Y Y Y Y Y Graphite 7782-42-5 7440-44-0 1-5% None Y Y N Y Y International Regulations Canada: All ingredients are CEPA approved for import to Canada by Procter & Gamble. This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and this MSDS contains all information required by the Controlled Products Regulations. 16. OTHER INFORMATION Prepared By: Revision Date: 2/27/2013 Company: Duracell, a P&G Business Revision number Telephone number: (203) 796-4000, (416) 730-4711 Notes Other Information Disclaimer information: This PSDS is intended to provide a brief summary of our knowledge and guidance regarding the use of this material. The information contained here has been compiled from sources considered by Procter & Gamble to be dependable and is accurate to the best of the Company's knowledge. It is not meant to be an all-inclusive document on worldwide hazard communication regulations. This information is offered in good faith. Each user of this material needs to evaluate the conditions of use and design the appropriate protective mechanisms to prevent employee exposures, property damage or release to the environment. Procter & Gamble assumes no responsibility for injury to the recipient or third persons or for any damage to any property resulting from misuse of the product. END OF MATERIAL SAFETY DATA SHEET
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.