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Material Safety Data Sheet Date of Issue: |Revision Date: Apr. 1, 2013|Revision Number: | |CYCRE-PSDS--01 Imperial Supplies Part Number: 0051500 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: Manganese dioxide lithium battery CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: 1.3. Name, Address, and Telephone of the Responsible Party Company Panasonic Corporation, Automotive & Industrial Systems Company Energy Device Business Division 1-1 Matsushita-cho, Moriguchi City, Osaka, 570-8511, Japan Phone: +81-6-6994-4537 1.4. Emergency Telephone Number Emergency | +81-6-6991-1141 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Not | applicable. | | | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) | | | | | | Signal Word (GHS-US) | Hazard Statements (GHS-US) | Precautionary Statements | (GHS-US) | 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Positive electrode |1313-13-9 |25~45 | Manganese dioxide | | | Negative electrode |7439-93-2 |2~ 5 | Lithium metal | | | Electrolyte | | | 1,2- dimethoxyethane |110-71-4 |3~ 5 | Organic electrolyte |- |5~17 | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Remove to fresh air immediately. Take a medical treatment. First-aid Measures After Skin Contact: Wash the contact areas off immediately with plenty of water and soap. If appropriate procedures are not taken, this may cause sores on the skin. First-aid Measures After Eye Contact: Flush the eyes with plenty of clean water for at least 15 minutes immediately, without rubbing. Take a medical treatment. If appropriate procedures are not taken, this may cause an eye irritation. First-aid Measures After Ingestion: 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Alcohol-resistant foam and dry sand are effective. Unsuitable Extinguishing Media: 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Take up with absorbent cloth. Move the battery away from the fire. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: When packing the batteries, do not allow battery terminals to contact each other, or contact with other metals. Be sure to pack batteries by providing partitions in the packaging box, or in a separate plastic bag so that the single batteries are not mixed together. Use strong material for packaging boxes so that they will not be damaged by vibration, impact, dropping and stacking during their transportation. Do not recharge batteries. Do not deform batteries. Do not mix different type of batteries. Do not solder directly onto batteries. Do not let water penetrate into packaging boxes during their storage and transportation. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Do not store the battery in places of the high temperature or under direct sunlight or in front of a stove. Please also avoid the places of high humidity. Be sure not to expose the battery to condensation, water drop or not to store it under frozen condition. Fire fighting apparatus should be installed. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters (In case of electrolyte leakage from the battery). Acceptable concentration: Not specified in ACGIH. Facilities: Provide appropriate ventilation system such as local ventilator in the storage Place. Protective clothing: Gas mask for organic gases, safety goggle, and safety glove. 8.2. Exposure Controls Appropriate Engineering | Controls | Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection | Skin and Body Protection | Respiratory Protection | Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State | Appearance |Cylindrical shape Odor | Odor Threshold | pH | Relative Evaporation Rate | (butylacetate=1) | Melting Point | Freezing Point | Boiling Point | Flash Point | Auto-ignition Temperature | Decomposition Temperature | Flammability (solid, gas) | Vapor Pressure | Relative Vapor Density at 20 �C | Relative Density | Specific Gravity | Solubility | Partition coefficient: | n-octanol/water | Viscosity | Lower Flammable Limit | Upper Flammable Limit | 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity Since batteries utilize a chemical reaction they are actually considered a chemical product. As such, battery performance will deteriorate over time even if stored for a long period of time without being used. In addition, the various usage conditions such as discharge, ambient temperature, etc. are not maintained within the specified ranges the life expectancy of the battery may be shortened or the device in which the battery is used may be damaged by electrolyte leakage. 10.2 Chemical Stability 10.3 Possibility of Hazardous Reactions 10.4 Conditions to Avoid 10.5 Incompatible Materials 10.6 Hazardous Decomposition Products SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Oral(rat) LD50 > 2,000mg/kg (estimated) . Skin Corrosion/Irritation: Irritating to skin. Serious Eye Damage/Irritation: Irritating to eye. Respiratory or Skin Sensitization: Germ Cell Mutagenicity: Carcinogenicity: Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: Not specified. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity In case of the worn-out battery was disposed in land, the battery case may be corroded, and leak electrolyte. But, we have no ecological information. 12.2. Persistence and Degradability 12.3. Bioaccumulative Potential 12.4. Mobility in Soil 12.5. Other Adverse Effects SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: When the battery is worn out, dispose of it under the ordinance of each local government or the law issued by relating government. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name | Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name | Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Lithium metal batteries Identification Number|UN3090 |<PICTOGRAM PHRASE> Hazard Class |Class9 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> IATA Dangerous Goods Regulations ICAO Technical Instructions for the safe transport of dangerous goods by air. SARA Section 311/312 Hazard Classes | Toxic Substances Control Act (TSCA) | 15.2 US State Regulations <COMPONENT> SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |Apr. 1, 2013 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.