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Material Safety Data Sheet Date of issue: |Revision Date: March 2015 |Revision Number: Imperial Supplies Part Number: 0050000.0050080.0050130.0050140.0050144 1. PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Name: Energizer Battery Manufacturing, Inc. Street Address: 25225 Detroit Rd. City, State Zip: Westlake, OH 44145 Country (if applicable) Telephone: 800-383-7323 (USA / CANADA) Emergency Phone Product Name: Eveready Battery Product Code(s): Recommended Use: UN-Number: Product Type: 2. HAZARDS IDENTIFICATION Appearance: Solid |Physical State: |Odor: No odor object | | Potential Health Effects Principle Routes of Exposure Acute Effects: Eyes |Contents of an open battery can cause severe |irritation and chemical burns. Skin |Contents of an open battery can cause skin |irritation and/or chemical burns. Inhalation |Contents of an open battery can cause respiratory |irritation. Ingestion |Swallowing a battery can be harmful. Contents of an |open battery can cause serious chemical burns of |mouth, esophagus, and gastrointestinal tract. Notes: Under normal conditions of use, the battery is hermetically sealed. Chronic Effects: Eyes | Skin | Inhalation | Ingestion | Notes: Aggravated Medical Conditions Environmental Hazard 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical/Ingredient Name |CAS-No |Weight% |ACGIH, |OSHA-PE|Other | | |TLV-TWA |L | Acetylene Black |1333-86-4 |3-7 |3.5 mg/m3 |3.5 | | | |TWA |mg/m3 | | | |(as carbon|TWA | | | |black) |(as | | | | |carbon | | | | |black) | Ammonium Chloride |2125-02-9 |0-10 |10 mg/m3 |None | | | |TWA (fume)|establi| | | | |shed | | | |20 mg/m3 | | | | |STEL | | | | |(fume) | | Manganese Dioxide |1313-13-9 |15-31 |0.2 mg/m3 |5 mg/m3| | | |TWA (as |CEILING| | | |Mn) |(as Mn)| Zinc |7440-66-6 |7-42 |10 mg/m3 |15 | | | |TWA PNOC**|mg/m3 | | | |(inhalable|TWA | | | |particulat|PNOR* | | | |e) 3 mg/m3|(total | | | |TWA PNOC**|dust) 5| | | |(respirabl|mg/m3 | | | |e |TWA | | | |particulat|PNOR* | | | |e) |(respir| | | | |able | | | | |fractio| | | | |n) | Zinc Chloride |7646-85-7 |2-10 |1 mg/m3 |1 mg/m3| | | |TWA (fume)|TWA | | | | |(fume) | | | |2 mg/m3 | | | | |STEL | | | | |(fume) | | Non-Hazardous Components |65997-19-5 |23-28 |None |None | Steel | | |establishe|establi| | | |d |shed | Water, Paper, Plastic and| |Balance |Non |Non | Other | | |establishe|establi| | | |d |shed | Notes: The battery should not be opened or burned. Exposure to the ingredients contained within or their combustion products could be harmful. 4. FIRST AID MEASURES General Advice Eyes |Immediately flush eyes thoroughly with water for at |least 15 minutes, lifting upper and lower lids, until |no evidence of the chemical remains. Seek medical |attention. Skin |Remove contaminated clothing and wash skin with soap |and water. If a chemical burn occurs or if irritation |persists, seek medical attention. Inhalation |Provide fresh air and seek medical attention. Ingestion |Do not induce vomiting or give food or drink. Seek |medical attention immediately. CALL NATIONAL BATTERY |INGESTION HOTLINE for advice and follow-up |(202-625-3333) collect day or night. Notes to Physician | Protection of | First-aiders | Notes | 5. FIRE-FIGHTING MEASURES Flammability/Flammable |Not applicable for an Article properties | Flash point |Not applicable for an Article Recommended Extinguishing | Media | Special Fire-Fighting |In case of fire, it is permissible to use any Procedures |class of extinguishing medium on these |batteries or their packing material. Cool |exterior of batteries if exposed to fire to |prevent rupture. Fire fighters should wear |self-contained breathing apparatus. | Explosion Data | Sensitivity to Mechanical | Impact | Sensitivity to Static | Discharge | | Specific Hazards from | Chemical | | Protective Equipment |Fire fighters should wear self-contained |breathing apparatus. NFPA |Health Hazard: |Flammability: |Instability:|Physical Hazard HMIS |Health Hazard: |Flammability: |Physical |PPE: | | |Hazard: | 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Eye Protection: Wear safety glasses with side shields if handling an open or leaking battery. Gloves: Use neoprene or natural rubber gloves if handling an open or leaking battery. Battery materials should be collected in a leak-proof container. Environmental Precautions Methods for Containment Methods for Cleaning Up Notes: Ventilation Requirements: Room ventilation may be required in areas where there are open or leaking batteries. 7. HANDLING AND STORAGE Handling: Accidental short circuit for a few seconds will not seriously affect the battery. Prolonged short circuit will cause the battery to lose energy, and can cause the safety release vent to open. Sources of short circuits include jumbled batteries in bulk containers, metal jewelry, metal covered tables or metal belts used for assembly of batteries into devices. If soldering or welding to the battery is required, consult your Energizer Battery Manufacturing, Inc. representative for proper precautions to prevent seal damage or short circuit. Storage: Store in a cool, well ventilated area. Elevated temperatures can result in shortened battery life. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name |ACGIH TLV |OSHA PEL |NIOSH IDLH |OTHER | | | | | | | | | | | | Engineering Measures Personal Protective Equipment Eyes/Face |Not necessary under normal conditions. Protection | Skin and Body |Gloves: Not necessary under normal conditions. Protection | Respiratory |Not necessary under normal conditions. Protection | Ventilation/Other |Not necessary under normal conditions. Hygiene Measures 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance |Solid object |Odor |No odor Odor Threshold |No odor |Physical State | Color | |Viscosity |Not applicable for | | |an Article pH |Not |Percent Volatile, | |applicable |wt. % | |for an | | |Article | | Flash Point |Not |Auto-ignition |Not applicable for |applicable |Temperature |an Article |for an | | |Article | | Decomposition |Not |Boiling Point/ Range|Not applicable for Temp |applicable | |an Article |for an | | |Article | | Melting |Not |Freezing Point |Not applicable for Point/Range |applicable | |an Article |for an | | |Article | | Flammability |Not |Explosion Limits | |applicable | | |for an | | |Article | | Specific Gravity | |Water Solubility |Not applicable for | | |an Article Solubility | |Evaporation Rate |Not applicable for | | |an Article Vapor Pressure |Not |Vapor Density |Not applicable for |applicable | |an Article |for an | | |Article | | VOC content, wt. | | | % | | | | | | Notes 10. STABILITY AND REACTIVITY Chemical Stability | Incompatible Products | Conditions to avoid | Hazardous Decomposition | Products | Hazardous Polymerization | Notes: Carbon zinc batteries do not meet any of the criteria established in 40 CFR 261.2 for reactivity. 11. TOXICOLOGY INFORMATION Acute Toxicity: Under normal conditions of use, carbon zinc batteries are non-toxic. Product | Information | Inhalation | Eye Contact | Skin Contact | Ingestion | Chemical Name |LD50 Oral |LD50 Dermal |LC50 Inhalation | | | | | | Chronic Toxicity| Chemical Name |ACGIH |IARC |NTP |OSHA | | | | | | | | Target Organ Effects 12. ECOLOGICAL INFORMATION Ecotoxicity The Environmental impact of this product has been fully investigated Chemical Name|Toxicity to |Toxicity to |Tox, to |Daphnia Magna |Algea |Fish |Microorganisms|(water flea) | | | | | | | | | | | | Notes: Issues such as ecotoxicity, persistence and bioaccumulation are not applicable for articles. 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods: Dispose of in accordance with all applicable federal, state and local regulations. Appropriate disposal technologies include incineration and land filling. Contaminated Packaging US EPA Waste number Notes 14. TRANSPORTATION INFORMATION DOT UN-Number | Proper Shipping name| Hazard Class | Packing Group | Description |49 CFR 172.102 Provision 130 Emergency Response | Guide Number | TDG UN-Number | Proper Shipping name| Hazard Class | Packing Group | Description | MEX | UN-Number | Proper Shipping name| Hazard Class | Packing Group | Description | ICAO UN-Number | Proper Shipping name|Not regulated Hazard Class | Packing Group | Description | IATA UN-Number | Proper Shipping name| Hazard Class | Packing Group | ERG Code | Description |A123 IMDG/IMO UN-Number | Proper Shipping name|Not regulated Hazard Class | Packing Group | EmS No. | Description | RID UN-Number | Proper Shipping | name | Hazard Class | Packing Group | Classification Code| Description | ADR/RID-Labels | ADR UN-Number | Proper Shipping |Not regulated name | Hazard Class | Packing Group | Classification Code| Description | ADR/RID-Labels | ADN UN-Number Proper Shipping name Hazard Class Packing Group Classification Code Special Provisions Description Hazard Labels Limited Quantity 15. REGULATORY INFORMATION International Inventories TSCA DSL EINECS ENCS IECSC PICCS AICS U.S. Federal Regulations SARA 313 SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Clean Water Act CERCLA U.S. State Regulations U.S. State Right-to-Know Regulations: SARA/TITLE III - As an article, this battery and its contents are not subject to the requirements of the Emergency Planning and Community Right-To-Know Act. International Regulations: Batteries marketed by Energizer Battery Manufacturing, Inc. are not classified as dangerous goods by the US Department of Transportation or the major international regulatory bodies and are therefore not regulated. Canada 16. OTHER INFORMATION Prepared By: Revision Date: March 2015 Company: Energizer Battery Manufacturing, Inc. Revision number Telephone number: 800-383-7323 (USA / CANADA) Notes Other Information: None. Disclaimer information END OF MATERIAL SAFETY DATA SHEET
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.