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SDS Sheet 0047490Printer Friendly View
Safety Data Sheet Date of Issue: 24-Nov-2015 |Revision Date: 24-Nov-2015 |Revision Number: 3 Imperial Supplies Part Number: 0047490 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: 6749-0 GARAGE DOOR LUBE CAS No: Synonyms: None 1.2. Intended Use of the Product Use of the substance/mixture: 1.3. Name, Address, and Telephone of the Responsible Party Company Imperial Supplies LLC 789 Armed Forces Drive P.O. Box 11008 Green Bay, WI 53407-1008 Phone: 1.4. Emergency Telephone Number Emergency | Chemtrec 1-800-424-9300, 734-721-5930 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Skin |Category 2 corrosion/irri| tation | Serious eye |Category 2B damage/eye | irritation | Specific |Category 3 target organ | toxicity | (single | exposure) | Aspiration |Category 1 toxicity | Flammable |Category 1 aerosols | Gases under |Compressed Gas pressure | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Exclamat|Health |Flame |Gas | | |ion mark|hazard | |cylinder| | Signal Word (GHS-US) |DANGER Hazard Statements (GHS-US) |Causes skin irritation |Causes eye irritation |May cause respiratory irritation. May cause |drowsiness or dizziness |May be fatal if swallowed and enters airways |Extremely flammable aerosol |Contains gas under pressure; may explode if heated Precautionary Statements |Prevention: (GHS-US) |Wash face, hands and any exposed skin thoroughly |after handling |Wear protective gloves/protective clothing/eye |protection/face protection |Avoid breathing dust/fume/gas/mist/vapors/spray |Use only outdoors or in a well-ventilated area |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking |Do not spray on an open flame or other ignition |source |Pressurized container: Do not pierce or burn, even |after use |Response: |Specific treatment (see first aid on this label) |IF IN EYES: Rinse cautiously with water for several |minutes. Remove contact lenses, if present and easy |to do. Continue rinsing. |If eye irritation persists: Get medical |advice/attention |IF ON SKIN: Wash with plenty of soap and water. |Take off contaminated clothing and wash before reuse | |If skin irritation occurs: Get medical |advice/attention |IF INHALED: Remove person to fresh air and keep |comfortable for breathing. |Call a POISON CENTER or doctor/physician if you feel |unwell |IF SWALLOWED: Immediately call a POISON CENTER or |doctor/physician |Do NOT induce vomiting |Storage: |Store locked up |Store in a well-ventilated place. Keep container |tightly closed |Protect from sunlight. Do not expose to temperatures |exceeding 50 Â°C/122 Â°F |Disposal: |Dispose of contents/container to an approved waste |disposal plant 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None. 2.4. Unknown Acute Toxicity (GHS-US) Toxic to aquatic life with long lasting effects 1.9E-05% of the mixture consists of ingredient(s) of unknown toxicity. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |%* |Classification | | |(GHS-US) HYDROTREATED LIGHT DISTILLATES |64742-47-8 |20-30 | NAPHTHENIC OIL, SEVERLY HYDROT |64742-52-5 |20-30 | KEROSENE |8008-20-6 |10-20 | PETROLEUM DISTILLATES |64742-47-8 |10-20 | POLYMERIC VISCOSITY MODIFIER |MIXTURE |1-10 | 2-BUTOXYETHANOL |111-76-2 |1-10 | CARBON DIOXIDE |124-38-9 |1-10 | *The exact percentage (concentration) of composition has been withheld as a trade secret. SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: If symptoms persist, call a physician. Protection of First-aiders: Absorb with sand ,clay, or other suitable material. Hard surfaces may be mopped with water. First-aid Measures After Inhalation: Move to fresh air. If breathing is difficult, give oxygen. Artificial respiration and/or oxygen may be necessary. If breathing has stopped, contact emergency medical services immediately. Immediate medical attention is not required. If symptoms persist, call a physician. Move to fresh air in case of accidental inhalation of vapors or decomposition products. First-aid Measures After Skin Contact: Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If skin irritation persists, call a physician. Immediate medical attention is not required. First-aid Measures After Eye Contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. If symptoms persist, call a physician. Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. First-aid Measures After Ingestion: Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Drink plenty of water. Call a physician or Poison Control Center immediately. Clean mouth with water and drink afterwards plenty of water. Consult a physician. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: May cause respiratory irritation. Symptoms/Injuries After Skin Contact: Causes skin irritation. Symptoms/Injuries After Eye Contact: Causes eye irritation Symptoms/Injuries After Ingestion: May be harmful if swallowed and cause lung damage. Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Notes to physician: Treat symptomatically. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use:. Dry chemical. Carbon dioxide (CO 2). Water spray. Alcohol-resistant foam. Unsuitable Extinguishing Media: Decomposition by contact with water may generate vapors which can be ignited by heat or open flame. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Keep product and empty container away from heat and sources of ignition. Risk of ignition. Explosion Hazard: Sensitivity to Mechanical Impact: none. Sensitivity to Static Discharge: Yes. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Avoid contact with eyes. Avoid breathing vapors or mists. Contents under pressure. Do not puncture or incinerate cans.Do not stick pin or any other sharp object into opening on top of can. Avoid skin contact. Use with adequate ventiliation. Keep container away from heat , flames, and all other sources of ignition. Keep can away from all sources of electricity such as electric motors and batteries. Do not spray on hot surfaces. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Remove all sources of ignition. Pay attention to flashback. Take precautionary measures against static discharges. Absorb with sand ,clay, or other suitable material. Hard surfaces may be mopped with water. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Prevent further leakage or spillage if safe to do so. Do not allow material to contaminate ground water system. Prevent product from entering drains. Do not flush into surface water or sanitary sewer system. Should not be released into the environment. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up: Pick up and transfer to properly labeled containers. Soak up with inert absorbent material. Clean contaminated surface thoroughly. After cleaning, flush away traces with water. Prevent product from entering drains. Take precautionary measures against static discharges. Dam up. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Wear personal protective equipment. Avoid contact with skin, eyes and clothing. Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharges. Use only in area provided with appropriate exhaust ventilation. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded. Keep away from heat, sparks and open flame. No smoking. Do not breathe vapors or spray mist. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapors). Avoid breathing vapors or mists. Contents under pressure. Do not puncture or incinerate cans. Do not stick pin or any other sharp object into opening on top of can. Hygiene Measures: When using, do not eat, drink or smoke. Provide regular cleaning of equipment, work area and clothing. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Technical measures/Storage conditions: Keep container tightly closed in a dry and well-ventilated place. Keep away from open flames, hot surfaces and sources of ignition. Keep in properly labeled containers. Keep out of the reach of children. Store locked up. Keep containers tightly closed in a cool, well-ventilated place. Keep away from heat. Incompatible products: Strong acids, alkalis, or oxidizing agents. Aerosol Level: 3. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Control parameters: Exposure Guidelines: Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH HYDROTREATED LIGHT DISTILLATES 64742-47-8 TWA: 200 PPM 8 hours - - KEROSENE 8008-20-6 TWA: 200 mg/m3 total hydrocarbon vapor application restricted to conditions in which there are negligibl aerosol Exposures Skin - potential significant contribution to overall exposure by the cutaneous route - TWA: 100 mg/m3 2-BUTOXYETHANOL 111-76-2 TWA: 20 ppm TWA: 50 ppm TWA: 240 mg/m3 (vacated) TWA: 25 ppm (vacated) TWA: 120 mg/m3 (vacated) S* S* IDLH: 700 ppm TWA: 5 ppm TWA: 24 mg/m3 CARBON DIOXIDE 124-38-9 STEL: 30000 ppm TWA: 5000 ppm TWA: 5000 ppm TWA: 9000 mg/m3 (vacated) TWA: 10000 ppm (vacated) TWA: 18000 mg/m3 (vacated) STEL: 30000 ppm (vacated) STEL: 54000 mg/m3 IDLH: 40000 ppm TWA: 5000 ppm TWA: 9000 mg/m3 STEL: 30000 ppm STEL: 54000 mg/m3 Other Exposure Guidelines: Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). 8.2. Exposure Controls Appropriate Engineering |Showers Controls |Eyewash stations |Ventilation systems. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Tightly fitting safety goggles. Skin and Body Protection |Chemical resistant apron. Protective gloves. Respiratory Protection |If exposure limits are exceeded or irritation is |experienced, NIOSH/MSHA approved respiratory |protection should be worn. Positive-pressure |supplied air respirators may be required for high |airborne contaminant concentrations. Respiratory |protection must be provided in accordance with |current local regulations. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Aerosol Appearance |opaque Odor |Solvent Odor Threshold | pH |No information available Relative Evaporation Rate (butyl |No information available acetate=1) | Melting Point |No information available Freezing Point |No information available Boiling Point |No information available Flash Point |49 Â°C / 120 Â°F (based on components) Auto-ignition Temperature |No information available Decomposition Temperature | Flammability (solid, gas) |No information available Vapor Pressure |No information available Relative Vapor Density at 20 Â°C |No information available Relative Density | Specific Gravity | Solubility |Practically insoluble Partition coefficient: | n-octanol/water | Viscosity |No information available Lower Flammable Limit |No information available Upper Flammable Limit |No information available 9.2. Other Information VOC Content(%): 35.38 SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No data available. 10.2 Chemical Stability Stable under recommended storage conditions. 10.3 Possibility of Hazardous Reactions None under normal processing. 10.4 Conditions to Avoid Heat, flames and sparks. 10.5 Incompatible Materials Strong acids, alkalis, or oxidizing agents. 10.6 Hazardous Decomposition Products None known based on information supplied. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: 1.9E-05% of the mixture consists of ingredient(s) of unknown toxicity The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 3381 mg/kg ATEmix (dermal) 11563 mg/kg ATEmix (inhalation-dust/mist) 31.7 mg/l Skin Corrosion/Irritation: Irritating to skin. Serious Eye Damage/Irritation: Irritating to eyes. Irritating to eyes, respiratory system and skin. Respiratory or Skin Sensitization: None known. Germ Cell Mutagenicity: None known. Carcinogenicity: The table below indicates whether each agency has evaluated a listed ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA 2-BUTOXYETHANOL 111-76-2 A3 Group 3 - - Reproductive Toxicity: This product does not contain any known or suspected reproductive hazards. Specific Target Organ Toxicity (Single Exposure): May cause respiratory irritation. May cause drowsiness and dizziness. Specific Target Organ Toxicity (Repeated Exposure): None under normal use conditions. Aspiration Hazard: May be fatal if swallowed and enters airways. Symptoms/Injuries After Inhalation: Vapors may irritate throat and respiratory system. May cause drownsiness and dizziness based on components. May cause irritation of respiratory tract. Avoid breathing vapors or mists. Symptoms/Injuries After Skin Contact: Irritating to skin. Repeated exposure may cause skin dryness or cracking. Prolonged skin contact may defat the skin and produce dermatitis. Avoid contact with skin. Symptoms/Injuries After Eye Contact: Irritating to eyes. Avoid contact with eyes and skin. Symptoms/Injuries After Ingestion: May be harmful if swallowed. Aspiration into the lungs during swallowing may cause serious lung damage which may be fatal. Chronic Symptoms: May cause adverse liver effects. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity 12.2. Persistence and Degradability 12.3. Bioaccumulative Potential Chemical Name log Pow 2-BUTOXYETHANOL 111-76-2 0.81 12.4. Mobility in Soil 12.5. Other Adverse Effects No information available. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Additional Information: Contaminated packaging: Do not re-use empty containers. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |CONSUMER COMMODITY ORM-D or LIMITED QUANTITY Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS, FLAMMABLE Hazard Class |2.1 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |AEROSOLS, FLAMMABLE Identification Number|UN1950 |<PICTOGRAM PHRASE> Hazard Class |2.1 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA 313: Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Chemical Name CAS-No Weight %* SARA 313 - Threshold Values % 2-BUTOXYETHANOL - 111-76-2 111-76-2 1-10 1.0 Clean Water Act: This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). CERCLA: This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material. SARA Section 311/312 Hazard Classes |Acute Health Hazard - Yes |Chronic Health Hazard - Yes |Fire Hazard - Yes |Sudden Release of Pressure Hazard - no |Reactive Hazard - no Toxic Substances Control Act (TSCA) |Chemical Name |TSCA | |HYDROTREATED LIGHT DISTILLATES |X | |NAPHTHENIC OIL, SEVERLY HYDROT |X | |KEROSENE |X | |PETROLEUM DISTILLATES |X | |2-BUTOXYETHANOL |X | |CARBON DIOXIDE |X | 15.2 US State Regulations <COMPONENT> California Proposition 65: This product does not contain any known Proposition 65 chemicals. U.S. State Right-to-Know Regulations: Chemical Name New Jersey Massachusetts Pennsylvania KEROSENE 8008-20-6 X X X 2-BUTOXYETHANOL 111-76-2 X X X CARBON DIOXIDE 124-38-9 X X X EPA Pesticide Registration Number: Not applicable. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |24-Nov-2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.