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Material Safety Data Sheet | | Date of issue: |Revision Date: 08/27/10 |Revision Number: Imperial Supplies Part Number: 0047400 1. PRODUCT AND COMPANY IDENTIFICATION Manufacturer By: Manufacturer For: AMERICAN JETWAY CORPORATION IMPERIAL, INCORPORATED 34136 MYRTLE STREET 789 PACKER DRIVE P.O. BOX 11008 WAYNE, MICHIGAN 48184-0126 GREEN BAY, WISCONSIN 54307 Telephone: Telephone: 920-494-7474 Emergency Phone: CHEMTREC 1-800-424-9300 Emergency Phone: 920-494-7474 Product Name: 4640 GALLON GLASS CLEANER Product Code(s): 0147-76, F01661 Recommended Use: GLASS CLEANER UN-Number: Product Type: 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: May cause severe eye irritation. Causes skin irritation. Appearance: CLEAR |Physical State: LIQUID |Odor: MILD Potential Health Effects Principle Routes of Exposure: Skin Contact, Inhalation, Ingestion, Eye Contact. Acute Effects: Eyes |Contact with eyes may cause irritation. May cause |pain disproportionate to the level of irritation to |eye tissues. May cause moderate eye irritation which |may be slow to heal. May cause slight corneal |injury. Vapor may cause eye irritation experienced |as mild discomfort and redness. Skin |Prolonged contact with liquid may cause slight |temporary irritation. Prolonged exposure not likely |to cause significant skin irritation. Repeated |exposure may cause irritation and possibly a burn. Inhalation |Inhaling large quantities of mist or vapors may |cause some irritation to nose, throat, lungs. Ingestion |Ingestion is not considered to be a hazard |encountered in normal industrial use. Irritating to |mouth, throat and stomach. Moderately toxic if |swallowed. Small amounts swallowed incidentally as a |result of normal handling operations are not likely |to cause injury; however, swallowing larger amounts |may cause injury. Notes: Chronic Effects: No Information. Eyes | Skin | Inhalation | Ingestion | Notes: Aggravated Medical Conditions Environmental Hazard 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical/Ingredient Name |CAS-No |Weight% |ACGIH, |OSHA-PE|Other | | |TLV-TWA |L | 2-BUTOXYETHANOL |111-76-2 |1 - 10 |25 PPM |25 PPM |N.E. | | |SKIN |SKIN | | | |STEL N.E. |PEL-CEI| | | | |LING 50| | | | |PPM | | | | |SKIN | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | Notes 4. FIRST AID MEASURES General Advice Eyes |Holding eyelids open, flush eyes with running water |for 5 minutes. Remove contact lenses if wearing and |flush open eyes with running water for at least 15 |minutes. Seek medical attention. Skin |Wash with soap and large amounts of water. Remove |contaminated clothing. Get medical attention if |irritation develops or persists. Inhalation |Remove to fresh air. If not breathing, give |artificial respiration. If breathing is difficult, |give oxygen. Get immediate medical attention. Ingestion |If swallowed, do NOT induce vomiting. Give victim a |glass of water or milk. Call a physician or poison |control center immediately. Never give anything by |mouth to an unconscious person. If swallowed, do NOT |induce vomiting. Call physician immediately. Notes to Physician | Protection of | First-aiders | Notes | 5. FIRE-FIGHTING MEASURES Flammability/Flammable | properties | Flash point |NONE. Recommended Extinguishing |Alcohol Foam, CO2, Dry Chemical, Foam, Water Media |Fog. Special Fire-Fighting |Containers can build up pressure if exposed to Procedures |heat (fire). As in any fire, wear |self-contained breathing apparatus |pressure-demand (MSHA/NIOSH approved or |equivalent) and full protective gear. Keep |containers and surroundings cool with water |spray. Beware of vapors accumulating to form |explosive concentrations. Vapors can |accumulate in low areas. | Explosion Data |"Empty" containers retain product residue |(liquid and/or vapor) and can be dangerous. Do |not pressurize, cut, weld, braze, solder, |drill, grind, or expose such containers to |heat, flame, sparks, static electricity, or |other sources of ignition; they may explode |and cause injury or death. Sensitivity to Mechanical | Impact | Sensitivity to Static | Discharge | | Specific Hazards from | Chemical | | Protective Equipment | NFPA |Health Hazard: |Flammability: |Instability:|Physical Hazard HMIS |Health Hazard: |Flammability: 1|Physical |PPE: |2 | |Hazard: 0 | 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Environmental Precautions Methods for Containment Methods for Cleaning Up Notes: Steps to be Taken in Case Material is Released or Spilled: Use recommended personal protective equipment. Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. 7. HANDLING AND STORAGE Handling: Wash thoroughly after handling. Avoid contact with eyes, skin, clothing. Avoid breathing spray mist. Promptly clean residue from closures with cloth dampened with water. Promptly clean up spills. Use only in well-ventilated area. Storage: Keep away from heat, sparks and flame. Keep from freezing. Keep container closed when not in use. Do not store in aluminum, fiberglass, copper, brass, zinc, or galvanized containers. Keep out of the reach of children! 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name |ACGIH TLV |OSHA PEL |NIOSH IDLH |OTHER | | | | | | | | | | | | Engineering Measures: Good general ventilation should be sufficient to control airborne levels. Local exhaust ventilation may be necessary to control any air contaminants to within their TLVs during the use of this product. Personal Protective Equipment Eyes/Face |Wear safety glasses with side shields or goggles when Protection |using this product. Wear safety glasses with side |shields (or goggles) and a face shield. Skin and Body |Skin Protection: Impervious gloves should be used. Protection |Other Protective Equipment: Standard industrial |clothing standards should be followed. Respiratory |A respiratory protection program that meets OSHA Protection |1910.134 and ANSI Z88.2 requirements must be followed |whenever workplace conditions warrant a respirator's |use. Ventilation/Other | Hygiene Measures: Wash hands before eating. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Follow all MSDS/label precautions even after container is emptied because they may retain product residues. Avoid prolonged or repeated contact with skin. Avoid contact with eyes, skin, and clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance |CLEAR |Odor |MILD Odor Threshold |ND |Physical State |LIQUID Color | |Viscosity |ND pH |12.0 |Percent Volatile, | | |wt. % | Flash Point |NONE |Auto-ignition |ND | |Temperature | Decomposition | |Boiling Point/ Range|340 - 340 F Temp | | | Melting | |Freezing Point |ND Point/Range | | | Flammability | |Explosion Limits | Specific Gravity |0.9929 |Water Solubility |COMPLETE Solubility | |Evaporation Rate |Is faster than Butyl | | |Acetate Vapor Pressure |ND |Vapor Density |Is heavier than air VOC content, wt. |0.32 lbs/gal,| | % | | | |39 grams/ltr,| | | | | |(Wt): 3.90% | | | | | Notes 10. STABILITY AND REACTIVITY Chemical Stability |This product is stable under normal storage |conditions. Incompatible Products |May react with oxygen and strong oxidizing |agents such as chlorates, nitrates, peroxides, |etc. Conditions to avoid |Avoid open flames and high temperatures. Avoid |contact with strong oxidizing agents. All |sources of ignition, welding arcs, and open |flames. Avoid contact with strong acids. Hazardous Decomposition |Oxides of carbon, nitrogen. Avoid strong Products |mineral acids. Carbon Monoxide, carbon dioxide, |smoke, fumes. Aldehydes. Ketones. Organic |acids. Hazardous Polymerization |Will not occur under normal conditions. Notes 11. TOXICOLOGY INFORMATION Acute Toxicity: PRODUCT LD50: 10652 mg/kg PRODUCT LC50: 2900 ppm Product | Information | Inhalation | Eye Contact | Skin Contact | Ingestion | Chemical Name |LD50 Oral |LD50 Dermal |LC50 Inhalation 2-BUTOXYETHANOL |470 MG/KG/RAT |470 MG/KG/RAT |2900 MG/M3/7H/RAT | | | Chronic Toxicity| Chemical Name |ACGIH |IARC |NTP |OSHA | | | | | | | | Target Organ Effects 12. ECOLOGICAL INFORMATION Ecotoxicity: Product is expected to be readily biodegradable. Expected to be moderately toxic to aquatic organisms on an acute basis. The Environmental impact of this product has been fully investigated Chemical Name|Toxicity to |Toxicity to |Tox, to |Daphnia Magna |Algea |Fish |Microorganisms|(water flea) | | | | | | | | | | | | Notes: Product is expected to be readily biodegradable. Expected to be moderately toxic to aquatic organisms on an acute basis. 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods: Dispose in accordance with all federal, state, and local regulations. Contaminated Packaging US EPA Waste number Notes 14. TRANSPORTATION INFORMATION DOT UN-Number | Proper Shipping name|NOT REGULATED Hazard Class | Packing Group | Description | Emergency Response | Guide Number | TDG UN-Number | Proper Shipping name| Hazard Class | Packing Group | Description | MEX | UN-Number | Proper Shipping name| Hazard Class | Packing Group | Description | ICAO UN-Number | Proper Shipping name| Hazard Class | Packing Group | Description | IATA UN-Number | Proper Shipping name|NOT REGULATED Hazard Class | Packing Group | ERG Code | Description | IMDG/IMO UN-Number | Proper Shipping name|NOT REGULATED Hazard Class | Packing Group | EmS No. | Description | RID UN-Number | Proper Shipping | name | Hazard Class | Packing Group | Classification Code| Description | ADR/RID-Labels | ADR UN-Number | Proper Shipping | name | Hazard Class | Packing Group | Classification Code| Description | ADR/RID-Labels | ADN UN-Number Proper Shipping name Hazard Class Packing Group Classification Code Special Provisions Description Hazard Labels Limited Quantity 15. REGULATORY INFORMATION International Inventories TSCA: TOXIC SUBSTANCES CONTROL ACT: This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: CHEMICAL NAME CAS NUMBER No information is available. DSL EINECS ENCS IECSC PICCS AICS U.S. Federal Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). SARA 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: CHEMICAL NAME CAS NUMBER WT/WT % IS LESS THAN 2-BUTOXYETHANOL 111-76-2 1-10 SARA 311/312 Hazard Categories Acute Health Hazard: Yes Chronic Health Hazard: Yes Fire Hazard: Yes Sudden Release of Pressure Hazard: No Reactive Hazard: No Clean Water Act CERCLA: This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories. U.S. State Regulations: NEW JERSEY RIGHT-TO-KNOW: The following materials are non-hazardous, but are among the top five components in this product: CHEMICAL NAME CAS NUMBER WATER 7732-18-5 PENNSYLVANIA RIGHT-TO-KNOW: The following non-hazardous ingredients are present in the product at greater than 3%: CHEMICAL NAME CAS NUMBER WATER 7732-18-5 CALIFORNIA PROPOSITION 65: WARNING: The chemical(s) noted below and contained in this product, are known to the state of California to cause cancer, birth defects or other reproductive harm: CHEMICAL NAME CAS NUMBER No Proposition 65 chemicals exist in this product. U.S. State Right-to-Know Regulations International Regulations Canada: CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings. CANADIAN WHMIS CLASS: No information available. 16. OTHER INFORMATION Prepared By: Revision Date: 08/27/10 Company: AMERICAN JETWAY CORPORATION Revision number Telephone number: 1-800-424-9300 Notes Other Information Disclaimer information: The information contained on this MSDS has been checked and should be accurate. However, it is the responsibility of the user to comply with all Federal, State, and Local laws and regulations. END OF MATERIAL SAFETY DATA SHEET
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.