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SDS Sheet 0047350

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Safety Data Sheet                                                                 
Date of Issue: 26-May-2015 |Revision Date: 26-May-2015 |Revision Number: 1        
Imperial Supplies Part Number: 0047350                                            

SECTION 1: IDENTIFICATION                                                         


1.1.  Product Identifier
Product Form:                                                                     
Product Name: 4335 PINT DEGREASER                                                 
CAS No:                                                                           
Synonyms: None                                                                    


1.2.  Intended Use of the Product
Use of the substance/mixture: Degreaser.                                          


1.3.  Name, Address, and Telephone of the Responsible Party
Company:                                                                          
Imperial Supplies LLC                                                             
789 Armed Forces Drive                                                            
P.O. Box 11008                                                                    
Green Bay, WI 53407-1038                                                          
Phone:                                                                            


1.4.  Emergency Telephone Number
Emergency     | Chemtrec 1-800-424-9300                                           
number        |                                                                   

SECTION 2: HAZARDS IDENTIFICATION                                                 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Skin          |Category 2    
corrosion/irri|              
tation        |              
Serious eye   |Category 2A   
damage/eye    |              
irritation    |              
Skin          |Category 1    
Sensitization |              
Flammable     |Category 4    
Liquids       |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Exclamati|       |        |        |        |        
                             |on Mark  |       |        |        |        |        
Signal Word (GHS-US)         |WARNING                                             
Hazard Statements (GHS-US)   |Causes skin irritation                              
                             |Causes serious eye irritation                       
                             |May cause an allergic skin reaction                 
                             |Combustible liquid                                  
Precautionary Statements     |Precautionary Statements - Prevention               
(GHS-US)                     |Wash face, hands and any exposed skin thoroughly    
                             |after handling                                      
                             |Wear protective gloves/protective clothing/eye      
                             |protection/face protection                          
                             |Avoid breathing dust/fume/gas/mist/vapors/spray     
                             |Contaminated work clothing should not be allowed out
                             |of the workplace                                    
                             |Keep away from heat/sparks/open flames/hot surfaces.
                             |- No smoking                                        
                             |Precautionary Statements - Response                 
                             |Specific treatment (see first aid on this label)    
                             |IF IN EYES: Rinse cautiously with water for several 
                             |minutes. Remove contact lenses, if present and easy 
                             |to do. Continue rinsing.                            
                             |If eye irritation persists: Get medical             
                             |advice/attention                                    
                             |IF ON SKIN: Wash with plenty of soap and water.     
                             |Take off contaminated clothing and wash before reuse
                             |                                                    
                             |If skin irritation or rash occurs: Get medical      
                             |advice/attention                                    
                             |In case of fire: Use CO2, dry chemical, or foam for 
                             |extinction                                          
                             |Precautionary Statements - Storage                  
                             |Store in a well-ventilated place. Keep cool         
                             |Precautionary Statements - Disposal                 
                             |Dispose of contents/container to an approved waste  
                             |disposal plant                                      


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification: Harmful to aquatic life with
long lasting effects. Harmful to aquatic life. No information available.          


2.4.  Unknown Acute Toxicity (GHS-US)
                                                                                  

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                                 


3.1.  Substance
Name                            |Product identifier   |%       |Classification    
                                |                     |        |(GHS-US)          
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification    
                                |                     |        |(GHS-US)          
ETHOXYLATED ALCOHOL             |68439-46-3           |1-10    |                  
SODIUM METASILICATE PENTAHYDRATE|6834-92-0            |1-10    |                  
D-LIMONENE                      |5989-27-5            |0.1-1   |                  
                                |                     |        |                  
                                |                     |        |                  


SECTION 4: FIRST AID MEASURES                                                     


4.1.  Description of First Aid Measures
First-aid Measures General:                                                       
First-aid Measures After Inhalation:  Move to fresh air. If breathing is          
difficult, give oxygen. Artificial respiration and/or oxygen  may be necessary. If
breathing has stopped, contact emergency medical services  immediately.           
First-aid Measures After Skin Contact: Wash off immediately with soap and plenty  
of water while removing all contaminated  clothes and shoes. If symptoms persist, 
call a physician.                                                                 
First-aid Measures After Eye Contact: Rinse immediately with plenty of water, also
under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. If  
symptoms persist, call a physician.                                               
First-aid Measures After Ingestion: Rinse mouth. Do NOT induce vomiting. Never    
give anything by mouth to an unconscious  person. Drink plenty of water. Call a   
physician or Poison Control Center immediately.                                   


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries: Causes skin and eye irritation.                                
Symptoms/Injuries After Inhalation:                                               
Symptoms/Injuries After Skin Contact:                                             
Symptoms/Injuries After Eye Contact:                                              
Symptoms/Injuries After Ingestion:                                                
Chronic Symptoms:                                                                 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
Notes to physician: Treat symptomatically.                                        

SECTION 5: FIRE-FIGHTING MEASURES                                                 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Use extinguishing measures that are appropriate to  
local circumstances and the surrounding environment.                              
Unsuitable Extinguishing Media: Decomposition by contact with water may generate  
vapors which can be ignited by heat or  open flame.                               


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: No information available.                                            
Explosion Hazard: Sensitivity to Mechanical Impact none.                          
Sensitivity to Static Discharge none.                                             
Reactivity:                                                                       


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                      
Firefighting Instructions:                                                        
Protection During Firefighting: As in any fire, wear self-contained breathing     
apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full           
protective gear.                                                                  

SECTION 6: ACCIDENTAL RELEASE MEASURES                                            


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Evacuate personnel to safe areas. Absorb with sand ,clay, or    
other suitable material. Hard surfaces may be mopped with water. Avoid contact    
with skin, eyes and clothing. Ensure  adequate ventilation. Avoid dust formation. 
Keep people away from and upwind of spill/leak.                                   


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                             
Emergency Procedures:                                                             


6.1.2.      For Emergency Responders
Protective Equipment:                                                             
Emergency Procedures:                                                             


6.2.  Environmental Precautions
Prevent further leakage or spillage if safe to do so. Do not allow material to    
contaminate  ground water system. Prevent product from entering drains.           


6.3.  Methods and Material for Containment and Cleaning Up
For Containment: Absorb with earth, sand or other non-combustible material and    
transfer to containers for  later disposal. Prevent further leakage or spillage if
safe to do so.                                                                    
Methods for Cleaning Up: Pick up and transfer to properly labeled containers. Soak
up with inert absorbent material. Clean contaminated surface thoroughly. After    
cleaning, flush away traces with water.                                           


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                        


SECTION 7: HANDLING AND STORAGE                                                   


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Avoid contact with skin, eyes and clothing.    
Handle in accordance with good industrial  hygiene and safety practice. Remove and
wash contaminated clothing before re-use.                                         
Hygiene Measures: Handle in accordance with good industrial hygiene and safety    
practice.                                                                         


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                               
Storage Conditions: Keep container tightly closed in a dry and well-ventilated    
place. Keep in properly labeled  containers. Keep out of the reach of children.   
Store locked up.                                                                  
Incompatible products: Strong acids, alkalis, or oxidizing agents.                
Aerosol Level: 1.                                                                 


7.3.  Specific End Use(s)
                                                                                  

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                  


8.1.  Control Parameters
Exposure Guidelines: This product does not contain any hazardous materials with   
occupational exposure limits established by the region specific regulatory bodies.


8.2.  Exposure Controls
Appropriate Engineering      |Showers Eyewash stations Ventilation systems.       
Controls                     |                                                    
Personal Protective Equipment|                                                    
Materials for Protective     |                                                    
Clothing                     |                                                    
Hand Protection              |                                                    
Eye Protection               |Safety glasses with side-shields.                   
Skin and Body Protection     |Chemical resistant apron. Protective gloves.        
Respiratory Protection       |If exposure limits are exceeded or irritation is    
                             |experienced, NIOSH/MSHA approved  respiratory       
                             |protection should be worn. Positive-pressure        
                             |supplied air respirators may be  required for high  
                             |airborne contaminant concentrations. Respiratory    
                             |protection must be  provided in accordance with     
                             |current local regulations.                          
Thermal Hazard Protection    |                                                    

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                       


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |Liquid                                       
Appearance                          |Slightly Hazy                                
Odor                                |Fragrance                                    
Odor Threshold                      |No information available                     
pH                                  |No information available                     
Relative Evaporation Rate           |No information available                     
(butylacetate=1)                    |                                             
Melting Point                       |No information available                     
Freezing Point                      |No information available                     
Boiling Point                       |No information available                     
Flash Point                         |No information available                     
Auto-ignition Temperature           |No information available                     
Decomposition Temperature           |No information available                     
Flammability (solid, gas)           |No information available                     
Vapor Pressure                      |No information available                     
Relative Vapor Density at 20 °C     |No information available                     
Relative Density                    |                                             
Specific Gravity                    |1.01                                         
Solubility                          |Water solubility: Practically insoluble      
Partition coefficient:              |No information available                     
n-octanol/water                     |                                             
Viscosity                           |No information available                     
Lower Flammable Limit               |No information available                     
Upper Flammable Limit               |No information available                     


9.2.  Other Information
VOC Content(%): 0.49                                                              

SECTION 10: STABILITY AND REACTIVITY                                              


10.1      Reactivity
No data available.                                                                


10.2      Chemical Stability
Stable under recommended storage conditions.                                      


10.3      Possibility of Hazardous Reactions
None under normal processing.                                                     


10.4      Conditions to Avoid
Extremes of temperature and direct sunlight.                                      


10.5      Incompatible Materials
Strong acids, alkalis, or oxidizing agents.                                       


10.6      Hazardous Decomposition Products
None known based on information supplied.                                         

SECTION 11: TOXICOLOGICAL INFORMATION                                             


11.1. Information on Toxicological Effects
Acute Toxicity:                                                                   
Skin Corrosion/Irritation: Irritating to skin. May cause an allergic skin         
reaction.                                                                         
Serious Eye Damage/Irritation: Irritating to eyes.                                
Respiratory or Skin Sensitization: May cause sensitization by skin contact.       
Germ Cell Mutagenicity: None known.                                               
Carcinogenicity: There are no known carcinogenic chemicals in this product.       
Reproductive Toxicity: This product does not contain any known or suspected       
reproductive hazards.                                                             
Specific Target Organ Toxicity (Single Exposure): None under normal use           
conditions.                                                                       
Specific Target Organ Toxicity (Repeated Exposure): None under normal use         
conditions.                                                                       
Aspiration Hazard: Not applicable.                                                
Symptoms/Injuries After Inhalation: Avoid breathing vapors or mists.              
Symptoms/Injuries After Skin Contact: Irritating to skin. Repeated exposure may   
cause skin dryness or cracking. Prolonged skin  contact may defat the skin and    
produce dermatitis. May cause sensitization by skin contact.  Avoid contact with  
skin.                                                                             
Symptoms/Injuries After Eye Contact: Irritating to eyes. Avoid contact with eyes. 
Symptoms/Injuries After Ingestion: May be harmful or fatal if swallowed.          
Chronic Symptoms:                                                                 

SECTION 12: ECOLOGICAL INFORMATION                                                


12.1. Toxicity
                                                                                  


12.2. Persistence and Degradability
No information available.                                                         


12.3. Bioaccumulative Potential
No information available.                                                         


12.4. Mobility in Soil
                                                                                  


12.5. Other Adverse Effects
No information available.                                                         

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: This material, as supplied, is a hazardous waste  
according to federal regulations (40 CFR 261).                                    
Additional Information: Contaminated packaging: Do not re-use empty containers.   

SECTION 14: TRANSPORT INFORMATION                                                 


14.1 In Accordance with DOT
Proper Shipping Name |CONSUMER COMMODITY ORM-D  Or  LIMITED QUANTITY              
Hazard Class         |                       |<PICTOGRAM PHRASE>                  
Identification Number|                       |                                    
Label Codes          |                       |                                    
ERG Number           |                                                            


14.2 In Accordance with IMDG
Proper Shipping Name |CORROSIVE LIQUID, N.O.S.(SODIUM METASILICATE)               
Hazard Class         |8                                                           
Identification Number|UN1760                                                      
Label Codes          |                      |<PICTOGRAM PHRASE>                   
ntification Of The   |                      |                                     
Substance/m          |                      |                                     
EmS-No. (Fire)       |                      |                                     
EmS-No. (Spillage)   |                      |                                     


14.3 In Accordance with IATA
Proper Shipping Name |CORROSIVE LIQUID, N.O.S.(SODIUM METASILICATE)               
Identification Number|UN1760                 |<PICTOGRAM PHRASE>                   
Hazard Class         |8                      |                                     
Label Codes          |                       |                                     
ntification Of The   |                       |                                     
Substance/m          |                       |                                     
ERG Code (IATA)      |                                                            

SECTION 15: REGULATORY INFORMATION                                                

15.1      US Federal Regulations
<COMPONENT>                                                                       
SARA 313: Section 313 of Title III of the Superfund Amendments and Reauthorization
Act of 1986 (SARA). This product does not contain any  chemicals which are subject
to the reporting requirements of the Act and Title 40 of the Code of Federal      
Regulations, Part 372.                                                            
                                                                                  
Clean Water Act: This product does not contain any substances regulated as        
pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40  CFR 122.42).    
                                                                                  
CERCLA: This material, as supplied, does not contain any substances regulated as  
hazardous substances under the Comprehensive  Environmental Response Compensation 
and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and           
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting          
requirements at the local, regional, or state level  pertaining to releases of    
this material.                                                                    
SARA Section 311/312 Hazard Classes |Acute Health Hazard Yes                      
                                    |Chronic Health Hazard Yes                    
                                    |Fire Hazard Yes                              
                                    |Sudden Release of Pressure Hazard no         
                                    |Reactive Hazard no                           
Toxic Substances Control Act (TSCA) |Chemical Name                                
                                    |TSCA                                         
                                    |ETHOXYLATED                                  
                                    |ALCOHOL                                      
                                    |X                                            
                                    |                                             
                                    |SODIUM                                       
                                    |METASILICATE                                 
                                    |PENTAHYDRATE                                X
                                    |                                             
                                    |                                             
                                    |D-LIMONENE                                   
                                    |X                                            

15.2      US State Regulations
<COMPONENT>                                                                       
California Proposition 65: This product does not contain any known Proposition 65 
chemicals.                                                                        
U.S. State Right-to-Know Regulations: EPA Pesticide Registration Number Not       
applicable.                                                                       
                                                                                  

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION     

Revision date   |05/26/2015                                                       
Other           |This document has been prepared in accordance with the SDS       
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR    
                |1910.1200.                                                       
GHS Full Text Phrases:                                                            
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Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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