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SDS Sheet 0047110

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SECTION 1: IDENTIFICATION                                                       
 


1.1.  Product Identifier
Product Form:                                                                   
 
Product Name: 4711 PINT LIQUID DE-ICER                                          
 
CAS No:                                                                         
 
Synonyms:                                                                       
 


1.2.  Intended Use of the Product
Use of the substance/mixture: De-Icer.                                          
 


1.3.  Name, Address, and Telephone of the Responsible Party
Company                                                                         
 
Imperial Supplies LLC                                                           
 
789 Armed Forces Drive                                                          
 
P.O. Box 11008                                                                  
 
Green Bay, WI 53407-1038                                                        
 
Phone                                                                           
 


1.4.  Emergency Telephone Number
Emergency     | Chemtrec 1-800-424-9300                                         
 
number        |                                                                 
 

SECTION 2: HAZARDS IDENTIFICATION                                               
 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Acute Toxicity|Category 3    
- Oral        |              
Acute Toxicity|Category 3    
-Dermal       |              
Acute toxicity|Category 3    
- Inhalation  |              
(Dusts/Mists) |              
Specific      |Category 1    
target organ  |              
toxicity      |              
(single       |              
exposure)     |              
Flammable     |Category 2    
Liquids       |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Skull and Crossbones |Health Hazard |Flame
       
Signal Word (GHS-US)         |Danger                                            
       
Hazard Statements (GHS-US)   |Toxic if swallowed                                
 
                             |Toxic in contact with skin                        
 
                             |Toxic if inhaled                                  
 
                             |Causes damage to organs (Central Nervous System,  
 
                             |Eyes, Gastrointestinal Tract, Respiratory System, 
 
                             |and Skin) through prolonged or repeated exposure. 
 
                             |Highly flammable liquid and vapor                 
 
Precautionary Statements     |Prevention:                                       
 
(GHS-US)                     |Wash face, hands and any exposed skin thoroughly  
 
                             |after handling                                    
 
                             |Do not eat, drink or smoke when using this product
 
                             |Wear protective gloves/protective clothing/eye    
 
                             |protection/face protection                        
 
                             |Use only outdoors or in a well-ventilated area    
 
                             |Do not breathe dust/fume/gas/mist/vapors/spray    
 
                             |Keep away from heat/sparks/open flames/hot
surfaces.
                             |- No smoking                                      
 
                             |Keep container tightly closed                     
 
                             |Ground/Bond container and receiving equipment     
 
                             |Use explosion-proof electrial/ventilating/lighting
 
                             |/equipment.                                       
 
                             |Use only non-sparking tools                       
 
                             |Take precautionary measures against static
discharge
                             |                                                  
 
                             |                                                  
 
                             |Response:                                         
 
                             |Specific treatment (see first aid on this label)  
 
                             |IF exposed: Call a POISON CENTER or
doctor/physician
                             |                                                  
 
                             |IF ON SKIN (or hair): Remove/Take off immediately 
 
                             |all contaminated clothing. Rinse skin with        
 
                             |water/shower                                      
 
                             |IF INHALED: Remove person to fresh air and keep   
 
                             |comfortable for breathing.                        
 
                             |Call a POISON CENTER or doctor/physician          
 
                             |IF SWALLOWED: Immediately call a POISON CENTER or 
 
                             |doctor/physician Rinse mouth                      
 
                             |In case of fire: Use CO2, dry chemical, or foam
for 
                             |extinction                                        
 
                             |                                                  
 
                             |Storage:                                          
 
                             |Store locked up                                   
 
                             |Store in a well-ventilated place. Keep container  
 
                             |tightly closed                                    
 
                             |Keep cool.                                        
 
                             |                                                  
 
                             |Disposal:                                         
 
                             |Dispose of contents/container to an approved waste
 
                             |disposal plant                                    
 


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification:  . Harmful to aquatic life
 
with long lasting effects. 0% of the mixture consists of ingredient(s) of
unknown 
toxicity.                                                                       
 


2.4.  Unknown Acute Toxicity (GHS-US)
                                                                                
 

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                               
 


3.1.  Substance
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%*      |Classification  
 
                                |                     |        |(GHS-US)        
 
METHANOL                        |67-56-1              |90-100  |                
 
PROPYLENE GLYCOL                |57-55-6              |1-10    |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


*The exact percentage (concentration) of composition has been withheld as a
trade secret.

SECTION 4: FIRST AID MEASURES                                                   
 


4.1.  Description of First Aid Measures
First-aid Measures General: Avoid contact with eyes,skin, and clothing.Avoid    
 
breathing, vapors,mist,or gas.                                                  
 
First-aid Measures After Inhalation: Move to fresh air. If not breathing, give  
 
artificial respiration. If breathing has stopped,                               
 
contact emergency medical services immediately.                                 
 
First-aid Measures After Skin Contact: Wash off immediately with soap and plenty
 
of water. Remove and wash contaminated                                          
 
clothing before re-use. Get medical attention immediately if symptoms occur.    
 
First-aid Measures After Eye Contact: Immediately flush with plenty of water.   
 
After initial flushing, remove any contact lenses and continue flushing for at  
 
least 15 minutes. Seek immediate medical attention/advice.                      
 
First-aid Measures After Ingestion: Do NOT induce vomiting. Call a physician    
 
immediately. Never give anything by mouth to an                                 
 
unconscious person. Risk of product entering the lungs on vomiting after        
 
ingestion.                                                                      
 


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries: Harmful if ingested.Causes skin irritations and harmful in   
 
contact with skin. May cause an allergic skin reaction. Causes serious eye
damage 
and irritation. May cause respiratory irritation.                               
 
Symptoms/Injuries After Inhalation: May cause respiratory irritation.           
 
Symptoms/Injuries After Skin Contact: Causes skin irritations and harmful in    
 
contact with skin. May cause an allergic skin reaction.                         
 
Symptoms/Injuries After Eye Contact: Causes serious eye damage and irritation.  
 
Symptoms/Injuries After Ingestion: Harmful if ingested.                         
 
Chronic Symptoms:                                                               
 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
Notes to physician: Treat symptomatically.                                      
 

SECTION 5: FIRE-FIGHTING MEASURES                                               
 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Water fog.Dry chemical. Carbon dioxide (CO2). Cool
 
containers/tanks with water spray.                                              
 
Unsuitable Extinguishing Media: Keep away from heat and sources of ignition. Do 
 
not smoke. Cool containers / tanks with water spray.                            
 


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: No information available                                           
 
Explosion Hazard:                                                               
 
Sensitivity to Mechanical Impact none.                                          
 
Sensitivity to Static Discharge Yes.                                            
 
Reactivity:                                                                     
 


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                    
 
Firefighting Instructions:                                                      
 
Protection During Firefighting: As in any fire, wear self-contained breathing   
 
apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective
gear.                                                                           
 

SECTION 6: ACCIDENTAL RELEASE MEASURES                                          
 


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Evacuate personnel to safe areas. Avoid contact with skin,
eyes 
and clothing. Ensure adequate ventilation. Avoid dust formation. Remove all     
 
sources of ignition. Keep people away from and upwind of spill/leak. Take       
 
precautionary measures against static discharges. All equipment used when
handling
the product must be grounded.                                                   
 


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.1.2.      For Emergency Responders
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.2.  Environmental Precautions
Beware of vapors accumulating to form explosive concentrations. Vapors can      
 
accumulate in low areas. Prevent further leakage or spillage if safe to do so.
Do 
not allow material to contaminate ground water system. Prevent product from     
 
entering drains.                                                                
 


6.3.  Methods and Material for Containment and Cleaning Up
For Containment: Absorb with earth, sand or other non-combustible material and  
 
transfer to containers for later disposal. Prevent further leakage or spillage
if 
safe to do so.                                                                  
 
Methods for Cleaning Up: Pick up and transfer to properly labeled containers.
Soak
up with inert absorbent material. Clean contaminated surface thoroughly. After  
 
cleaning, flush away traces with water.                                         
 


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                      
 


SECTION 7: HANDLING AND STORAGE                                                 
 


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Avoid contact with skin, eyes and clothing.  
 
Handle in accordance with good industrial                                       
 
hygiene and safety practice. Remove and wash contaminated clothing before
re-use. 
Keep away from open flames, hot surfaces and sources of ignition. Take          
 
precautionary measures against static discharges.                               
 
Hygiene Measures: Handle in accordance with good industrial hygiene and safety  
 
practice.                                                                       
 


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures: Keep container tightly closed in a dry and well-ventilated  
 
place. Keep away from open flames, hot surfaces and sources of ignition. Keep in
 
properly labeled containers. Keep out of the reach of children. Store locked up.
 
Incompatible products: Strong acids, alkalis, or oxidizing agents.              
 
Storage Conditions: Keep container tightly closed in a dry and well-ventilated  
 
place. Keep away from open flames, hot surfaces and sources of ignition. Keep in
 
properly labeled containers. Keep out of the reach of children. Store locked up.
 
Incompatible products: Strong acids, alkalis, or oxidizing agents.              
 


7.3.  Specific End Use(s)
                                                                                
 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                
 


8.1.  Control Parameters
Exposure Guidelines                                                             
 
Chemical Name                                                                   
 
ACGIH TLV                                                                       
 
OSHA PEL                                                                        
 
NIOSH IDLH                                                                      
 
                                                                                
 
METHANOL                                                                        
 
67-56-1                                                                         
 
STEL: 250 ppm                                                                   
 
TWA: 200 ppm                                                                    
 
Skin - potential significant                                                    
 
contribution to overall exposure                                                
 
by the cutaneous route                                                          
 
TWA: 200 ppm                                                                    
 
TWA: 260 mg/m3                                                                  
 
(vacated) TWA: 200 ppm                                                          
 
(vacated) TWA: 260 mg/m3                                                        
 
(vacated) STEL: 250 ppm                                                         
 
(vacated) STEL: 325 mg/m3                                                       
 
(vacated) S*                                                                    
 
IDLH: 6000 ppm                                                                  
 
TWA: 200 ppm                                                                    
 
TWA: 260 mg/m3                                                                  
 
STEL: 250 ppm                                                                   
 
STEL: 325 mg/m3                                                                 
 
                                                                                
 
ACGIH: (American Conference of Governmental Industrial Hygienists)              
 
OSHA: (Occupational Safety & Health Administration)                             
 
NIOSH IDLH: Immediately Dangerous to Life or Health                             
 
                                                                                
 
Other Exposure Guidelines: Vacated limits revoked by the Court of Appeals
decision
in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992).                             
 


8.2.  Exposure Controls
Appropriate Engineering      |Showers. Eyewash stations. Ventilation systems.   
 
Controls                     |                                                  
 
Personal Protective Equipment|                                                  
 
Materials for Protective     |                                                  
 
Clothing                     |                                                  
 
Hand Protection              |                                                  
 
Eye Protection               |Safety glasses with side-shields.                 
 
Skin and Body Protection     |Chemical resistant apron. Protective gloves.      
 
Respiratory Protection       |If exposure limits are exceeded or irritation is  
 
                             |experienced, NIOSH/MSHA approved respiratory      
 
                             |protection should be worn. Positive-pressure      
 
                             |supplied air respirators may be required for high 
 
                             |airborne contaminant concentrations. Respiratory  
 
                             |protection must be provided in accordance with    
 
                             |current local regulations.                        
 
Thermal Hazard Protection    |                                                  
 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                     
 


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |Liquid                                     
 
Appearance                          |Clear                                      
 
Odor                                |Solvent                                    
 
Odor Threshold                      |No information available                   
 
pH                                  |No information available                   
 
Relative Evaporation Rate           |No information available                   
 
(butylacetate=1)                    |                                           
 
Melting Point                       |No information available                   
 
Freezing Point                      |No information available                   
 
Boiling Point                       |No information available                   
 
Flash Point                         |12 °C / 54 °F    Based on lowest flashpoint
 
                                    |of the products constituent.               
 
Auto-ignition Temperature           |No information available                   
 
Decomposition Temperature           |No information available                   
 
Flammability (solid, gas)           |No information available                   
 
Vapor Pressure                      |No information available                   
 
Relative Vapor Density at 20 °C     |No information available                   
 
Relative Density                    |                                           
 
Specific Gravity                    |0.809                                      
 
Solubility                          |Practically insoluble                      
 
Partition coefficient:              |No information available                   
 
n-octanol/water                     |                                           
 
Viscosity                           |No information available                   
 
Lower Flammable Limit               |No information available                   
 
Upper Flammable Limit               |No information available                   
 


9.2.  Other Information
VOC Content(%):      97.5                                                       
 

SECTION 10: STABILITY AND REACTIVITY                                            
 


10.1      Reactivity
No data available                                                               
 


10.2      Chemical Stability
Stable under recommended storage conditions.                                    
 


10.3      Possibility of Hazardous Reactions
None under normal processing.                                                   
 


10.4      Conditions to Avoid
Extremes of temperature and direct sunlight.                                    
 


10.5      Incompatible Materials
Strong acids, alkalis, or oxidizing agents.                                     
 


10.6      Hazardous Decomposition Products
None known based on information supplied.                                       
 

SECTION 11: TOXICOLOGICAL INFORMATION                                           
 


11.1. Information on Toxicological Effects
Acute Toxicity: Harmful if swallowed. May be fatal if swallowed and enters      
 
airways.                                                                        
 
Skin Corrosion/Irritation:                                                      
 
Serious Eye Damage/Irritation:                                                  
 
Respiratory or Skin Sensitization: None known.                                  
 
Germ Cell Mutagenicity: None known.                                             
 
Carcinogenicity: There are no known carcinogenic chemicals in this product.     
 
Reproductive Toxicity: This product does not contain any known or suspected     
 
reproductive hazards.                                                           
 
Specific Target Organ Toxicity (Single Exposure): may cause drowsiness and      
 
dizziness. May cause drowsiness and dizziness                                   
 
Specific Target Organ Toxicity (Repeated Exposure): Causes damage to organs     
 
through prolonged or repeated exposure if swallowed. Causes damage to organs    
 
through prolonged or repeated exposure if inhaled.                              
 
Aspiration Hazard: May be fatal if swallowed and enters airways.                
 
Symptoms/Injuries After Inhalation: Toxic by inhalation. Avoid breathing vapors
or
mists.                                                                          
 
Symptoms/Injuries After Skin Contact: Toxic in contact with skin. Avoid contact 
 
with skin and clothing.                                                         
 
Symptoms/Injuries After Eye Contact: Avoid contact with eyes.                   
 
Symptoms/Injuries After Ingestion: Toxic if swallowed.                          
 
Chronic Symptoms: Intentional misuse by deliberately concentrating and inhaling 
 
contents may be harmful or fatal. Chronic hydrocarbon abuse has been associated 
 
with irregular heart rhythms and potential cardiac arrest. Prolonged skin
contact 
may defat the skin and produce dermatitis.                                      
 

SECTION 12: ECOLOGICAL INFORMATION                                              
 


12.1. Toxicity
Chemical Name                                                                   
 
Toxicity to algae                                                               
 
Toxicity to fish                                                                
 
Toxicity to                                                                     
 
Microorganisms                                                                  
 
Toxicity to daphnia and other aquatic invertebrates                             
 
                                                                                
 
METHANOL                                                                        
 
67-56-1                                                                         
 
-                                                                               
 
13500 - 17600 mg/L LC50 Lepomis macrochirus 96h flow-through 18 - 20 mL/L LC50  
 
Oncorhynchus mykiss 96h static 19500  -20700 mg/L LC50 Oncorhynchus mykiss 96h  
 
flow through 28200 mg/L LC50                                                    
 
Pimephales promelas 96h flow-through 100 mg/L LC50 Pimephales promelas 96h
Static 
-                                                                               
 
-                                                                               
 
                                                                                
 
PROPYLENE GLYCOL                                                                
 
57-55-6                                                                         
 
19000 mg/L EC50                                                                 
 
Pseudokirchneriella                                                             
 
subcapitata 96h                                                                 
 
41 - 47 mL/L LC50                                                               
 
Oncorhynchus mykiss 96h static 51400 mg/L LC50 Pimephales promelas 96h static   
 
51600 mg/L LC50 Oncorhynchus mykiss 96h static 710 mg/L LC50 Pimephales promelas
 
96h                                                                             
 
-                                                                               
 
1000 mg/L EC50 Daphnia magna 48h Static                                         
 
                                                                                
 


12.2. Persistence and Degradability
No information available.                                                       
 


12.3. Bioaccumulative Potential
No information available.                                                       
 
Chemical Name                                                                   
 
log Pow                                                                         
 
                                                                                
 
METHANOL                                                                        
 
67-56-1                                                                         
 
-0.77                                                                           
 
                                                                                
 


12.4. Mobility in Soil
                                                                                
 


12.5. Other Adverse Effects
No information available                                                        
 

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: This material, as supplied, is a hazardous waste
 
according to federal regulations (40 CFR 261).                                  
 
Additional Information: Contaminated packaging: Do not re-use empty containers. 
 

SECTION 14: TRANSPORT INFORMATION                                               
 


14.1 In Accordance with DOT
Proper Shipping Name |CONSUMER COMMODITY ORM-D                                  
 
                     |or                                                        
 
                     |LIMITED QUANTITY                                          
 
Hazard Class         |                       |<PICTOGRAM PHRASE>                
 
Identification Number|                       |                                  
 
Label Codes          |                       |                                  
 
ERG Number           |                                                          
 


14.2 In Accordance with IMDG
Proper Shipping Name |METHANOL SOLUTION                                         
 
Hazard Class         |3 (6.1)                                                   
 
Identification Number|UN1230                                                    
 
Label Codes          |                      |<PICTOGRAM PHRASE>                 
 
ntification Of The   |                      |                                   
 
Substance/m          |                      |                                   
 
EmS-No. (Fire)       |                      |                                   
 
EmS-No. (Spillage)   |                      |                                   
 


14.3 In Accordance with IATA
Proper Shipping Name |METHANOL SOLUTION                                         
 
Identification Number|UN1230                 |<PICTOGRAM PHRASE>                
  
Hazard Class         |3 (6.1)                |                                  
  
Label Codes          |                       |                                  
  
ntification Of The   |                       |                                  
  
Substance/m          |                       |                                  
  
ERG Code (IATA)      |                                                          
 

SECTION 15: REGULATORY INFORMATION                                              
 

15.1      US Federal Regulations
SARA 313                                                                        
 
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 
 
1986 (SARA). This product contains a chemical                                   
 
or chemicals which are subject to the reporting requirements of the Act and
Title 
40 of the Code of Federal Regulations, Part 372:                                
 
Chemical Name                                                                   
 
CAS-No                                                                          
 
Weight %*                                                                       
 
SARA 313 - Threshold                                                            
 
Values %                                                                        
 
                                                                                
 
METHANOL - 67-56-1                                                              
 
67-56-1                                                                         
 
90-100                                                                          
 
1.0                                                                             
 
                                                                                
 
SARA Section 311/312 Hazard Classes |Acute Health Hazard                        
 
                                    |Yes                                        
 
                                    |Chronic Health Hazard                      
 
                                    |Yes                                        
 
                                    |Fire Hazard                                
 
                                    |Yes                                        
 
                                    |Sudden Release of Pressure Hazard        no
 
                                    |Reactive Hazard                            
 
                                    |no                                         
 
Toxic Substances Control Act (TSCA) |Chemical Name                 TSCA         
 
                                    |METHANOL                           X       
 
                                    |PROPYLENE                           X      
 
                                    |GLYCOL                                     
 
                                    |                                           
 

15.2      US State Regulations
<COMPONENT>                                                                     
 
California Proposition 65                                                       
 
This product contains the following Proposition 65 chemicals:                   
 
Chemical Name                                                                   
 
California Prop. 65                                                             
 
                                                                                
 
METHANOL - 67-56-1                                                              
 
Carcinogen                                                                      
 
                                                                                
 
                                                                                
 
U.S. State Right-to-Know Regulations                                            
 
Chemical Name                                                                   
 
New Jersey                                                                      
 
Massachusetts                                                                   
 
Pennsylvania                                                                    
 
                                                                                
 
METHANOL                                                                        
 
67-56-1                                                                         
 
X                                                                               
 
X                                                                               
 
X                                                                               
 
                                                                                
 
PROPYLENE GLYCOL                                                                
 
57-55-6                                                                         
 
X                                                                               
 
                                                                                
 
                                                                                
 
                                                                                
 

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION   
 

Revision date   |20-May-2015                                                    
 
Other           |This document has been prepared in accordance with the SDS     
 
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR  
 
                |1910.1200.                                                     
 
GHS Full Text Phrases:                                                          
 
----|                               |                                           
 
--  |                               |                                           
 
----|                               |                                           
 
--  |                               |                                           
 
----|                               |                                           
 
--  |                               |                                           
 
----|                               |                                           
 
--  |                               |                                           
 
----|                               |                                           
 
--  |                               |                                           
 


Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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