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Safety Data Sheet | | Date of Issue: 11/17/15 |Revision Date: 11/17/15 |Revision Number: 4.00 Imperial Supplies Part Number: 0046740 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: 3M One-Step Rust Converter, PN 3513 CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: 1.3. Name, Address, and Telephone of the Responsible Party Company 3M - Automotive Aftermarket 3M Center St. Paul, MN 55144-1000, USA Phone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency Telephone Number Emergency |1-800-364-3577 or (651) 737-6501 (24 hours) number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 2 Liquid | Acute Toxicity|Category 4 (oral) | Serious Eye |Category 2A Damage/Irritat| ion | Skin |Category 2 Corrosion/Irri| tation | Skin |Category 1 Sensitizer | Reproductive |Category 1B Toxicity | Reproductive |Lactation Toxicity | Carcinogenicit|Category 2 y | Specific |Category 1 Target Organ | Toxicity | (single | exposure): | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Exclamat|Health | | | | |ion mark|hazard | | | Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Highly flammable liquid and vapor. |Harmful if swallowed. |Causes serious eye irritation. |Causes skin irritation. |May cause an allergic skin reaction. |May damage fertility or the unborn child. |May cause harm to breast-fed children. |Suspected of causing cancer. |Causes damage to organs: sensory organs. |Causes damage to organs through prolonged or |repeated exposure: liver. Precautionary Statements |Prevention: (GHS-US) |Obtain special instructions before use. |Do not handle until all safety precautions have been |read and understood. |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking. |Ground/bond container and receiving equipment. |Use only non-sparking tools. |Take precautionary measures against static |discharge. |Keep container tightly closed. |Use explosion-proof electrical/ventilating/lighting |equipment. |Do not breathe dust/fume/gas/mist/vapors/spray. |Avoid contact during pregnancy/while nursing. |Wear protective gloves and eye/face protection. |Do not eat, drink or smoke when using this product. |Wash thoroughly after handling. |Contaminated work clothing must not be allowed out |of the workplace. | |Response: |IF ON SKIN (or hair): Take off immediately all |contaminated clothing. Rinse skin with water/shower. | |IF IN EYES: Rinse cautiously with water for several |minutes. Remove contact lenses, if present and easy |to do. |Continue rinsing. |If eye irritation persists: Get medical |advice/attention. |IF ON SKIN: Wash with plenty of soap and water. |If skin irritation or rash occurs: Get medical |advice/attention. |Take off contaminated clothing and wash it before |reuse. |IF exposed: Call a POISON CENTER or |doctor/physician. |Rinse mouth. |IF SWALLOWED: Call a POISON CENTER or |doctor/physician if you feel unwell. |Specific treatment (see Notes to Physician on this |label). |In case of fire: Use a fire fighting agent suitable |for flammable liquids such as dry chemical or carbon |dioxide to Extinguish. | |Storage: |Store in a well-ventilated place. Keep cool. |Store locked up. | |Disposal: |Dispose of contents/container in accordance with |applicable local/regional/national/international |regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Water |7732-18-5 |40 - 70 | | |Trade | | |Secret *| Vinyl Acrylic Polymer (NJTSRN: |Trade Secret* |15 - 40 | 8387P) | |Trade | | |Secret *| Isopropyl Alcohol |67-63-0 |3 - 7 | | |Trade | | |Secret *| Methyl Alcohol |67-56-1 |3 - 7 | | |Trade | | |Secret *| Tannic Acid |1401-55-4 |3 - 7 | | |Trade | | |Secret *| Bis(2-Ethylhexyl)Phthalate |117-81-7 |1 - 5 | | |Trade | | |Secret *| Synthetic Amorphous Silica, |112945-52-5 |1 - 5 | Fumed, Crystalline Free | |Trade | | |Secret *| 5-Decyne-4,7-diol, |126-86-3 |< 1 | 2,4,7,9-tetramethyl- | |Trade | | |Secret *| NJTS or NJTSRN: New Jersey Trade Secret Registry Number. *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. First-aid Measures After Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. First-aid Measures After Eye Contact: Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue rinsing. Immediately get medical attention. First-aid Measures After Ingestion: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Symptoms/Injuries After Skin Contact: Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. May cause additional health effects (see below). Symptoms/Injuries After Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Symptoms/Injuries After Ingestion: Harmful if swallowed. Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Notes to Physician: This product contains methanol. If there is a reasonable suspicion of methanol poisoning, intravenous (IV) administration with either fomepizole (preferred) or ethanol (if fomepizole is unavailable) should be considered as part of the medical management. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. Unsuitable Extinguishing Media: 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Closed containers exposed to heat from fire may build pressure and explode. Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Seal the container. Dispose of collected material as soon as possible. Methods for Cleaning Up: 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: For industrial or professional use only. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Avoid contact during pregnancy/while nursing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Keep away from reactive metals (eg. Aluminum, zinc etc.) to avoid the formation of hydrogen gas that could create an explosion hazard. Wear low static or properly grounded shoes. Use personal protective equipment (gloves, respirators, etc.) as required. To minimize the risk of ignition, determine applicable electrical classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable vapor accumulation. Ground/bond container and receiving equipment if there is potential for static electricity accumulation during transfer. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store away from heat. Store away from acids. Store away from oxidizing agents. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Occupational exposure limits: If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments SILICA, AMORPHOUS 112945-52-5 OSHA TWA concentration:0.8 mg/m3;TWA:20 millions of particles/cu. ft. Bis(2-Ethylhexyl)Phthalate 117-81-7 ACGIH TWA:5 mg/m3 A3: Confirmed animal carcin. Bis(2-Ethylhexyl)Phthalate 117-81-7 OSHA TWA:5 mg/m3 Methyl Alcohol 67-56-1 ACGIH TWA:200 ppm;STEL:250 ppm Skin Notation Methyl Alcohol 67-56-1 OSHA TWA:260 mg/m3(200 ppm) Isopropyl Alcohol 67-63-0 ACGIH TWA:200 ppm;STEL:400 ppm A4: Not class. as human carcin Isopropyl Alcohol 67-63-0 OSHA TWA:980 mg/m3(400 ppm) ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling. 8.2. Exposure Controls Appropriate Engineering |Use general dilution ventilation and/or local Controls |exhaust ventilation to control airborne exposures to |below relevant Exposure Limits and/or control |dust/fume/gas/mist/vapors/spray. If ventilation is |not adequate, use respiratory protection equipment. |Use explosion-proof ventilation equipment. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Select and use gloves and/or protective clothing |approved to relevant local standards to prevent skin |contact based on the results of an exposure |assessment. Selection should be based on use factors |such as exposure levels, concentration of the |substance or mixture, frequency and duration, |physical challenges such as temperature extremes, |and other use conditions. Consult with your glove |and/or protective clothing manufacturer for |selection of appropriate compatible |gloves/protective clothing. Note: Nitrile gloves may |be worn over polymer laminate gloves to improve |dexterity. Gloves made from the following |material(s) are recommended: Polymer laminate. If |this product is used in a manner that presents a |higher potential for exposure (eg. spraying, high |splash potential etc.), then use of protective |coveralls may be necessary. Select and use body |protection to prevent contact based on the results |of an exposure assessment. The following protective |clothing material(s) are recommended: Apron - |polymer laminate. Eye Protection |Select and use eye/face protection to prevent |contact based on the results of an exposure |assessment. The following eye/face protection(s) are |recommended: Full Face Shield. Indirect Vented |Goggles. Skin and Body Protection | Respiratory Protection |An exposure assessment may be needed to decide if a |respirator is required. If a respirator is needed, |use respirators as part of a full respiratory |protection program. Based on the results of the |exposure assessment, select from the following |respirator type(s) to reduce inhalation exposure: |Half facepiece or full facepiece air-purifying |respirator suitable for mercury vapor and |particulates. For questions about suitability for a |specific application, consult with your respirator |manufacturer. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid Appearance | Odor |Aromatic odor Odor Threshold |No Data Available Ph |2 - 4 Relative Evaporation Rate (butyl |No Data Available acetate=1) | Melting Point | Freezing Point | Boiling Point |318 - 390 �F Flash Point |50 Deg. F [Test Method: Closed Cup] |10 Deg. C Auto-ignition Temperature | Decomposition Temperature |No Data Available Flammability (solid, gas) |Not Applicable Vapor Pressure |< 0.1 kPa Relative Vapor Density at 20 �C | Relative Density | Specific Gravity |1.077 [Ref Std: WATER=1] Solubility |Complete Partition coefficient: | n-octanol/water | Viscosity |275 - 375 centipoise [Test Method: |Brookfield] [Details: Spindle #2 @ 50 rpm] Lower Flammable Limit |No Data Available Upper Flammable Limit |No Data Available 9.2. Other Information Volatile Organic Compounds: 105 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds: 8.6 % weight [Test Method: calculated per CARB title 2] Percent volatile: 63 % weight VOC Less H2O & Exempt Solvents: 245 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2 Chemical Stability Stable. 10.3 Possibility of Hazardous Reactions Hazardous polymerization will not occur. 10.4 Conditions to Avoid Heat. Sparks and/or flames. 10.5 Incompatible Materials Strong oxidizing agents. Aluminum. Zinc. 10.6 Hazardous Decomposition Products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity: Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Reproductive Toxicity: Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Contains a chemical or chemicals which may interfere with lactation or be harmful to breastfed children. Specific Target Organ Toxicity (Single Exposure): May cause blindness. Specific Target Organ Toxicity (Repeated Exposure): Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and jaundice. Aspiration Hazard: For the component/components, either no data are currently available or the data are not sufficient for classification. Symptoms/Injuries After Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Symptoms/Injuries After Skin Contact: Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. May cause additional health effects (see below). Symptoms/Injuries After Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Symptoms/Injuries After Ingestion: Harmful if swallowed. Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. 12.2. Persistence and Degradability 12.3. Bioaccumulative Potential 12.4. Mobility in Soil 12.5. Other Adverse Effects SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate uncured product in a permitted waste incineration facility. As a disposal alternative, utilize an acceptable permitted waste disposal facility. If no other disposal options are available, waste product that has been completely cured or polymerized may be placed in a landfill properly designed for industrial waste. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name | Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name | Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name | Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations Contact 3M for more information. SARA Section 311/312 Hazard Classes |Fire Hazard - Yes |Pressure Hazard - No |Reactivity Hazard - No |Immediate Hazard - Yes |Delayed Hazard - Yes Toxic Substances Control Act (TSCA) |The components of this product are in |compliance with the chemical notification |requirements of TSCA. 15.2 US State Regulations Contact 3M for more information. Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Methyl Alcohol 67-56-1 Trade Secret 3 - 7 Bis(2-Ethylhexyl)Phthalate 117-81-7 Trade Secret 1 - 5 SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |11/17/15 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.