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Safety Data Sheet | | Date of Issue: |Revision Date: June 3, 2016|Revision Number: Imperial Supplies Part Number: 0046580 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: CLEAR-DIESEL FUEL AND TANK CLEANER CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Diesel fuel additive 1.3. Name, Address, and Telephone of the Responsible Party Company Power Service Products, Inc. P.O. Box 108 Weatherford, TX 76086 Phone: 800/643-9089 or 817-599-9486 Supplier: Imperial Supplies LLC 1.4. Emergency Telephone Number Emergency | 1-800-424-9300, 001-703-527-3887 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Health Hazard Criteria |Category Acute Toxicity, Oral: |NC Acute Toxicity, Dermal: |3 Acute Toxicity, Inhalation, Vapors: |3 Skin Corrosion/Irritation: |2 Serious Eye Damage/Eye Irritation: |2 Respiratory Sensitization: |NC Skin Sensitization: |NC Germ Cell Mutagenicity: |NC Carcinogenicity: |NC Reproductive Toxicity: |NC Specific Target Organ Toxicity, |3 Single Exposure: | Specific Target Organ Toxicity, |NC Repeated or Prolonged Exposure: | Aspiration Hazard: |1 Physical Properties Criteria|Category Explosives: |NC Flammable Gases: |NC Flammable Aerosols: |NC Oxidizing Gases: |NC Gases Under Pressure: |NC Flammable Liquids: |3 Flammable Solids: |NC Self-Reactive Chemicals: |NC Pyrophoric Liquids: |NC Pyrophoric Solids: |NC Self-Heating Chemicals: |NC Chemicals Which, in Contact |NC with Water, Emit Flammable | Gases: | Oxidizing Liquids: |NC Oxidizing Solids: |NC Organic Peroxides: |NC Corrosive to Metals: |NC 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Skulls |Health |Exclamat|Flame | | |and |hazard |ion mark| | | |crossbon| | | | | |es | | | | | Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Toxic if inhaled. |Toxic in contact with skin. |May be fatal if swallowed and enters airways. |Causes skin and serious eye irritation. |May cause respiratory irritation. |Flammable liquid and vapor. Precautionary Statements |Keep away from flames and hot surfaces. No smoking. (GHS-US) |Do not breathe vapors. |Keep container tightly closed. |Ground/Bond container and receiving equipment. |Use explosion-proof pumps when pumping. |Use non-sparking tools. |Take precautionary measures against static |discharge. |Use only outdoors or in a well-ventilated area. |Avoid breathing vapors. |Wash hands thoroughly after handling. |Do not eat, drink or smoke when using this product. |Wear protective gloves/clothing and eye protection. |Store locked up and in a well ventilated place. Keep |cool. |KEEP OUT OF REACH OF CHILDREN. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Hydroxy alkoxylate |trade secret |35 - 95 | Petroleum Distillates |trade secret |20 - 50 | 2,6-Di-tert butylphenol |trade secret |0.1 - | | |1.0 | Amines |trade secret |0.1 - | | |0.5 | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: As a precaution, exposure to liquids, vapors, mists and fumes should be minimized. First-aid Measures After Inhalation: Remove person to fresh air and keep comfortable for breathing. Call a doctor if person feels unwell. First-aid Measures After Skin Contact: Wash with plenty of water. If skin irritation occurs: Get medical advice/attention if person feels unwell. Take off contaminated clothing and wash it before use. First-aid Measures After Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid Measures After Ingestion: If swallowed, immediately call a doctor. Do NOT induce vomiting. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use water fog, alcohol foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Unsuitable Extinguishing Media: 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Explosion Hazard: Vapors are heavier than air and may travel along the ground to a distant ignition source and flash back. See Section 10 for Stability and Reactivity. NOTE: EMPTY CONTAINERS CONTAIN COMBUSTIBLE VAPORS THAT CAN CAUSE FLASH FIRES OR EXPLOSIONS. CONTAINERS ARE SINGLE-TRIP CONTAINERS AND SHOULD NOT BE USED FOR ANY REASON AFTER BEING EMPTIED. DO NOT USE CUTTING TORCH EQUIPMENT OR ANY OTHER FLAME OR OTHER SOURCES OF IGNITION ON ANY EMPTY CONTAINER. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: Use standard protective equipment including self-contained breathing apparatus (SCBA). SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas. Eliminate all sources of ignition in the vicinity of the spill or released vapor. See Section 2 for Hazards Identification. See Section 4 for First Aid Measures. See Section 5 for Fire Fighting Information. See Section 8 for Personal Protective Equipment. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions 6.3. Methods and Material for Containment and Cleaning Up For Containment: Eliminate potential sources of ignition. Stop leak if it can be done without risk. Dike and contain spill. Do not touch or walk through spilled material. Prevent entry into waterways, sewer, basements or confined areas. Remove with vacuum trucks or pump to storage/salvage vessels. Soak up residue with an absorbent such as clay, sand or or pump to storage/salvage vessels. Soak up residue with an absorbent such as clay, sand or vapors. Local, state and federal laws and/or regulations may apply to releases and disposal of this material, as well as those materials and items employed in the clean-up releases. The user/responder will need to determine which local, state and federal laws and/or regulations are applicable. The National Response Center can be reached at 1-800-424-8802. Methods for Cleaning Up: 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: PRECAUTIONS FOR SAFE HANDLING: Avoid contact with eyes and skin. Use only with adequate ventilation. Use proper bonding and/or grounding procedures. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). Keep away from ignition sources such as heat, sparks, and flames. No smoking. Minimize exposure of product to air. Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Practice good housekeeping. NOTE: These precautions are for room temperature handling. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: DO NOT USE OR STORE near heat, sparks, or flame. USE AND STORE ONLY IN A WELL-VENTILATED AREA. Handle containers with care. Keep container tightly closed when not in use. Store locked up. STORAGE TEMPERATURE: -20Â°F to 100Â°F (-29Â°C to 38Â°C) EMPTY CONTAINER WARNING: EMPTY CONTAINERS MAY CONTAIN COMBUSTIBLE VAPORS AND CAN BE DANGEROUS. SEE SECTION 5 FOR FIRE AND EXPLOSION HAZARD DATA. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters EXPOSURE GUIDELINES: CAS # OSHA ACGIH NIOSH PEL TLV STEL REL STEL IDLH Note Petroleum Distillates n/a 500 ppm not est. not est. not est. not est. not est. n/a Hydroxy Alkoxylate Proprietary 50 ppm 20 ppm not est. 5 ppm not est. not est. skin Ethylbenzene 100-41-4 100 ppm 20 ppm not est. 100 ppm 125 ppm 800 ppm (LEL) n/a 8.2. Exposure Controls Appropriate Engineering |The level of protection and types of controls Controls |necessary will vary depending upon potential |exposure conditions. Local exhaust ventilation is |recommended to control exposure. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Eye protection such as safety glasses or chemical |goggles is recommended if contact is likely. Skin and Body Protection |Protective chemical/oil resistant clothing and |gloves are recommended. Wear additional protective |clothing as appropriate. Respiratory Protection |Wear a NIOSH/MSHA approved respirator as necessary. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State | Appearance |Liquid, straw yellow Odor |Faint aromatic Odor Threshold |Not available pH |6-7 Relative Evaporation Rate (butyl |Not available acetate=1) | Melting Point |Not available Freezing Point | Boiling Point |303Â°F; 151Â°C Flash Point |118Â°F; 47.8Â°C Auto-ignition Temperature |Not available Decomposition Temperature |Not available Flammability (solid, gas) |Not available Vapor Pressure |0.4 mmHg Relative Vapor Density at 20 Â°C |Not available Relative Density | Specific Gravity |0.91 Solubility |Not available Partition coefficient: |Not available n-octanol/water | Viscosity |Not available Lower Flammable Limit |Not available Upper Flammable Limit |Not available 9.2. Other Information Pour Point : <-157Â°F; -<-105Â°C SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity See Incompatible Materials below. 10.2 Chemical Stability This material is considered stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. 10.3 Possibility of Hazardous Reactions Hazardous polymerization will not occur. 10.4 Conditions to Avoid Flames, high energy ignition sources, and elevated temperatures. 10.5 Incompatible Materials May react with oxygen; strong acids, strong oxidizing agents, such as; chlorates, nitrates, peroxides, etc.; alkalis, nitric acid; sulfuric acid; sulfur oxides; reducing agents. 10.6 Hazardous Decomposition Products Carbon oxides, products of incomplete combustion. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Breathing of high vapor concentrations may cause dizziness, light-headedness, headache, nausea and loss of coordination. Continued inhalation may result in unconsciousness. The vapor or fumes from this material may cause respiratory irritation. Breathing this material at elevated concentrations causes central nervous system effects. Central nervous system effects may include headache, dizziness, nausea, vomiting, weakness, loss of coordination, blurred vision, drowsiness, confusion or disorientation. At extreme exposures, central nervous system effects may include respiratory depression, tremors, or convulsions, loss of consciousness, coma or death. Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: No information available. Germ Cell Mutagenicity: No information available. Carcinogenicity: Component List Cumene IARC, NTP Ethylbenzene IARC Naphthalene IARC, NTP Reproductive Toxicity: No information available. Specific Target Organ Toxicity (Single Exposure): Respiratory tract irritation. Specific Target Organ Toxicity (Repeated Exposure): No information available. Aspiration Hazard: Aspiration hazard identified. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: DELAYED AND IMMEDIATE EFFECTS AND CHRONIC EFFECTS FROM SHORT- AND LONG-TERM EXPOSURE: Repeated skin exposure to a component of this product may cause irritation, even a burn; may cause a more severe response on covered skin, such as under clothing or gloves. Inhalation exposure to a component of this product has caused fetotoxicity in the presence of maternal toxicity in animals. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity This material is expected to be toxic to aquatic organisms. 12.2. Persistence and Degradability No information not available. 12.3. Bioaccumulative Potential No information not available. 12.4. Mobility in Soil No information not available. 12.5. Other Adverse Effects No information not available. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: RCRA Information: Disposal of unused product may be subject to RCRA hazardous waste regulations (40 CFR Part 261). Disposal of the used product may also be regulated as hazardous waste due to resulting mixture characteristics, mixture components or product use. Such changes to the product may result in different and/or additional hazardous waste codes. Potential RCRA waste code based on the product as shipped: D001 IGNITABILITY. State or local laws may impose additional regulatory requirements regarding disposal. Waste characterizations and compliance with applicable laws are the responsibility solely of the waste generator. Additional Information: EMPTY CONTAINER WARNING: EMPTY CONTAINERS MAY CONTAIN COMBUSTIBLE VAPORS AND CAN BE DANGEROUS. SEE SECTION 5 FOR FIRE AND EXPLOSION HAZARD DATA. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |The following part numbers are not regulated by DOT: |9216-06, 9216-09, 9225-06, 9225-09, 9280-06, 19216-06, |19216-09, 19225-06, 19280-06 Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name | Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name | Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations Section 313: Specific chemical information is being withheld as a Trade Secret. The following chemicals subject to the reporting requirements of EPCRA Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (40 CFR Part 372) may be present in this product at a concentration that does not exceed the specified upper weight percentage. CAS Number Chemical Name Max % n/a Glycol Ether Category 70 100-41-4 Ethlybenzene 7.0 State or local laws may impose additional regulatory requirements for components of this material. It is the responsibility solely of the Employer to maintain compliance with State and Local reporting. SARA Section 311/312 Hazard Classes |Section 302 Extremely Hazardous Substances: |None. |Sections 311/ 312 Hazard Class: |Acute Health Effects: Yes |Chronic Health Effects: Yes |Fire Hazard: Yes |Sudden Release of Pressure Hazard: No |Reactivity Hazard: No Toxic Substances Control Act (TSCA) |All chemical substances found in this product |comply with the Toxic Substances Control Act |inventory reporting requirements. 15.2 US State Regulations This product contains a chemical known to the state of California to cause cancer and/or birth defects or other reproductive harm: ethylbenzene, toluene, cumene, naphthalene. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |June 3, 2016 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.