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SDS Sheet 0046470

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SECTION 1: IDENTIFICATION                                                       

1.1.  Product Identifier
Product Form:                                                                   
Product Name: 4647 QUART NON-CHLOR BRK CL                                       
CAS No:                                                                         

1.2.  Intended Use of the Product
Use of the substance/mixture: non-chlorinated brake cleaner.                    

1.3.  Name, Address, and Telephone of the Responsible Party
Imperial Supplies LLC                                                           
789 Armed Forces Drive                                                          
P.O. Box 11008                                                                  
Green Bay, WI 53407-1038                                                        

1.4.  Emergency Telephone Number
Emergency     | Chemtrec 1-800-262-8200 ID 1195, 734-721-5930                   
number        |                                                                 

SECTION 2: HAZARDS IDENTIFICATION                                               

2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Skin          |Category 2    
tation        |              
Serious eye   |Category 2A   
damage/eye    |              
irritation    |              
Reproductive  |Category 2    
Toxicity      |              
Specific      |Category 3    
target organ  |              
toxicity      |              
(single       |              
exposure)     |              
Specific      |Category 2    
target organ  |              
toxicity      |              
(repeated     |              
exposure)     |              
Aspiration    |Category 1    
toxicity      |              
Flammable     |Category 1    
Liquids       |              

2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Exclamation Mark |Health Hazard |Flame
Signal Word (GHS-US)         |DANGER                                            
Hazard Statements (GHS-US)   |Causes skin irritation                            
                             |Causes serious eye irritation                     
                             |Suspected of damaging fertility or the unborn
                             |May cause drowsiness or dizziness                 
                             |May cause damage to organs (central nervous
                             |eyes, kidney, liver, respiratory system, and skin)
                             |through prolonged or repeated exposure.           
                             |May be fatal if swallowed and enters airways      
                             |Extremely flammable liquid and vapor              
Precautionary Statements     |Prevention:                                       
(GHS-US)                     |Obtain special instructions before use            
                             |Do not handle until all safety precautions have
                             |read and understood                               
                             |Wear protective gloves/protective clothing/eye    
                             |protection/face protection                        
                             |Wash face, hands and any exposed skin thoroughly  
                             |after handling                                    
                             |Do not breathe dust/fume/gas/mist/vapors/spray    
                             |Use only outdoors or in a well-ventilated area    
                             |Keep away from heat/sparks/open flames/hot
                             |- No smoking                                      
                             |Keep container tightly closed                     
                             |Ground/Bond container and receiving equipment     
                             |Use explosion-proof electrial/ventilating/lighting
                             |Use only non-sparking tools                       
                             |Take precautionary measures against static
                             |If exposed or concerned: Get medical              
                             |Specific treatment (see first aid on this label)  
                             |IF IN EYES: Rinse cautiously with water for
                             |minutes. Remove contact lenses, if present and
                             |to do. Continue rinsing.                          
                             |If eye irritation persists: Get medical           
                             |IF ON SKIN (or hair): Remove/Take off immediately 
                             |all contaminated clothing. Rinse skin with        
                             |Wash contaminated clothing before reuse           
                             |If skin irritation occurs: Get medical            
                             |IF INHALED: Remove person to fresh air and keep   
                             |comfortable for breathing.                        
                             |Call a POISON CENTER or doctor/physician if you
                             |IF SWALLOWED: Immediately call a POISON CENTER or 
                             |Do NOT induce vomiting                            
                             |In case of fire: Use CO2, dry chemical, or foam
                             |Store locked up                                   
                             |Store in a well-ventilated place. Keep container  
                             |tightly closed                                    
                             |Keep cool.                                        
                             |Dispose of contents/container to an approved waste
                             |disposal plant                                    

2.3.  Other Hazards
Other Hazards Not Contributing to the Classification: None                      

2.4.  Unknown Acute Toxicity (GHS-US)
0% of the mixture consists of ingredient(s) of unknown toxicity                 


3.1.  Substance
Name                            |Product identifier   |%       |Classification  
                                |                     |        |(GHS-US)        
                                |                     |        |                
                                |                     |        |                
                                |                     |        |                
                                |                     |        |                
                                |                     |        |                

Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification  
                                |                     |        |(GHS-US)        
ACETONE                         |67-64-1              |70-80   |                
TOLUENE                         |108-88-3             |10-20   |                
HEPTANE                         |64742-49-0           |10-20   |                
                                |                     |        |                
                                |                     |        |                

SECTION 4: FIRST AID MEASURES                                                   

4.1.  Description of First Aid Measures
First-aid Measures General: Avoid contact with eyes,skin, and clothing.Avoid    
breathing, vapors,mist,or gas.                                                  
First-aid Measures After Inhalation: Move to fresh air. If not breathing, give  
artificial respiration. If breathing has stopped,                               
contact emergency medical services immediately.                                 
First-aid Measures After Skin Contact: Wash off immediately with soap and plenty
of water. Remove and wash contaminated                                          
clothing before re-use. Get medical attention immediately if symptoms occur.    
First-aid Measures After Eye Contact: Immediately flush with plenty of water.   
After initial flushing, remove any contact lenses and continue flushing for at  
least 15 minutes. Seek immediate medical attention/advice.                      
First-aid Measures After Ingestion: Do NOT induce vomiting. Call a physician    
immediately. Never give anything by mouth to an                                 
unconscious person. Risk of product entering the lungs on vomiting after        

4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries: Not applicable.                                              
Symptoms/Injuries After Inhalation:                                             
Symptoms/Injuries After Skin Contact:                                           
Symptoms/Injuries After Eye Contact:                                            
Symptoms/Injuries After Ingestion:                                              
Chronic Symptoms:                                                               

4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Notes to physician: Treat symptomatically.                                      

SECTION 5: FIRE-FIGHTING MEASURES                                               

5.1.  Extinguishing Media
Suitable Extinguishing Media: Use extinguishing measures that are appropriate to
local circumstances and the surrounding environment.                            
Unsuitable Extinguishing Media: Decomposition by contact with water may generate
vapors which can be ignited by heat or                                          
open flame.                                                                     

5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: Extremely flammable.                                               
Explosion Hazard:                                                               
Sensitivity to Mechanical Impact: none.                                         
Sensitivity to Static Discharge: none.                                          

5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                    
Firefighting Instructions:                                                      
Protection During Firefighting: As in any fire, wear self-contained breathing   
apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full

SECTION 6: ACCIDENTAL RELEASE MEASURES                                          

6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Absorb with sand ,clay, or other suitable material. Hard      
surfaces may be mopped with                                                     
water. Remove all sources of ignition. Avoid contact with skin, eyes and
Ensure adequate ventilation. Avoid dust formation. Keep people away from and    
upwind of spill/leak. Take precautionary measures against static discharges. All
equipment used when handling the product must be grounded.                      

6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                           
Emergency Procedures:                                                           

6.1.2.      For Emergency Responders
Protective Equipment:                                                           
Emergency Procedures:                                                           

6.2.  Environmental Precautions
Do not flush into surface water or sanitary sewer system. Beware of vapors      
accumulating to form explosive concentrations. Vapors can accumulate in low
Prevent further leakage or spillage if safe to do so. Do not allow material to  
contaminate ground water system.                                                

6.3.  Methods and Material for Containment and Cleaning Up
For Containment: Prevent further leakage or spillage if safe to do so. Contain
collect spillage with non-combustible absorbent material, (e.g. sand, earth,    
diatomaceous earth, vermiculite) and place in container for disposal according
local / national regulations (see Section 13).                                  
Methods for Cleaning Up: Soak up with inert absorbent material. Pick up and     
transfer to properly labeled containers. Clean contaminated surface thoroughly. 
After cleaning, flush away traces with water. Ground and bond containers when   
transferring material. Take precautionary measures against static discharges.   
Prevent product from entering drains. Sweep up and shovel into                  
suitable containers for disposal.                                               

6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                      

SECTION 7: HANDLING AND STORAGE                                                 

7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Avoid contact with skin, eyes and clothing.  
Handle in accordance with good industrial                                       
hygiene and safety practice. Remove and wash contaminated clothing before
Keep away from open flames, hot surfaces and sources of ignition. Take          
precautionary measures against static discharges. Do not breathe vapors or spray
Hygiene Measures: Handle in accordance with good industrial hygiene and safety  

7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                             
Storage Conditions: Keep container tightly closed in a dry and well-ventilated  
place. Keep away from open                                                      
flames, hot surfaces and sources of ignition. Keep in properly labeled
Keep out                                                                        
of the reach of children. Store locked up.                                      
Incompatible products: Strong acids, alkalis, or oxidizing agents.              

7.3.  Specific End Use(s)


8.1.  Control Parameters
Exposure Guidelines                                                             
Chemical Name                ACGIH TLV                     OSHA PEL             
NIOSH IDLH                                                                      
ACETONE                           STEL: 750 ppm              TWA: 1000 ppm      
IDLH: 2500 ppm                                                                  
67-64-1                              TWA: 500 ppm             TWA: 2400 mg/m3   
TWA: 250 ppm                                                                    
(vacated) TWA: 750 ppm                     TWA: 590 mg/m3                       
(vacated) TWA: 1800 mg/m3                                                       
(vacated) STEL: 2400 mg/m3                                                      
The acetone STEL does not                                                       
apply to the cellulose acetate                                                  
fiber industry. It is in effect for all                                         
other sectors                                                                   
(vacated) STEL: 1000 ppm                                                        
TOLUENE                         TWA: 20 ppm                  TWA: 200 ppm       
IDLH: 500 ppm                                                                   
vacated) TWA: 100 ppm                    TWA: 100 ppm                           
(vacated) TWA: 375 mg/m3              TWA: 375 mg/m3                            
(vacated) STEL: 150 ppm                   STEL: 150 ppm                         
(vacated) STEL: 560 mg/m3              STEL: 560 mg/m3                          
HEPTANE                         TLV: 400 ppm                 TWA: 500 ppm       
64742-49-0                       STEL: 500 ppm                                  

8.2.  Exposure Controls
Appropriate Engineering      |Showers                                           
Controls                     |Eyewash stations                                  
                             |Ventilation systems.                              
Personal Protective Equipment|                                                  
Materials for Protective     |                                                  
Clothing                     |                                                  
Hand Protection              |                                                  
Eye Protection               |Safety glasses with side-shields.                 
Skin and Body Protection     |Chemical resistant apron. Protective gloves.      
Respiratory Protection       |If exposure limits are exceeded or irritation is  
                             |experienced, NIOSH/MSH approved respiratory       
                             |protection should be worn. Positive-pressure      
                             |supplied air respirators may be required for high 
                             |airborne contaminant concentrations. Respiratory  
                             |protection must be provided in accordance with    
                             |current local regulations.                        
Thermal Hazard Protection    |                                                  

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                     

9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |Liquid                                     
Appearance                          |Clear                                      
Odor                                |Solvent                                    
Odor Threshold                      |No information available                   
pH                                  |No information available                   
Relative Evaporation Rate           |No information available                   
(butylacetate=1)                    |                                           
Melting Point                       |No information available                   
Freezing Point                      |No information available                   
Boiling Point                       |No information available                   
Flash Point                         |-20 °C / -4 °F                             
Auto-ignition Temperature           |No information available                   
Decomposition Temperature           |No information available                   
Flammability (solid, gas)           |No information available                   
Vapor Pressure                      |No information available                   
Relative Vapor Density at 20 °C     |                                           
Relative Density                    |                                           
Specific Gravity                    |0.787                                      
Solubility                          |Practically insoluble                      
Partition coefficient:              |No information available                   
n-octanol/water                     |                                           
Viscosity                           |No information available                   
Lower Flammable Limit               |No information available                   
Upper Flammable Limit               |No information available                   

9.2.  Other Information
VOC Content(%): 20.5                                                            

SECTION 10: STABILITY AND REACTIVITY                                            

10.1      Reactivity
No data available                                                               

10.2      Chemical Stability
Stable under recommended storage conditions.                                    

10.3      Possibility of Hazardous Reactions
None under normal processing.                                                   

10.4      Conditions to Avoid
Extremes of temperature and direct sunlight.                                    

10.5      Incompatible Materials
Strong acids, alkalis, or oxidizing agents.                                     

10.6      Hazardous Decomposition Products
None known based on information supplied.                                       

SECTION 11: TOXICOLOGICAL INFORMATION                                           

11.1. Information on Toxicological Effects
Acute Toxicity:                                                                 
Skin Corrosion/Irritation: Irritating to skin. Repeated exposure may cause skin 
dryness or cracking. Prolonged skin contact may defat the skin and produce      
dermatitis. Avoid contact with skin.                                            
Serious Eye Damage/Irritation: Irritating to eyes. Avoid contact with eyes.     
Respiratory or Skin Sensitization:Vapors may irritate throat and respiratory    
system. May cause drownsiness and dizziness based on components. May cause      
irritation of respiratory tract.                                                
Germ Cell Mutagenicity: None known.                                             
Carcinogenicity: The table below indicates whether each agency has evaluated a  
listed ingredient as a carcinogen.                                              
Chemical Name                                                                   
Group 3                                                                         
Reproductive Toxicity: Product is or contains a chemical which is a known or    
suspected reproductive hazard.                                                  
Specific Target Organ Toxicity (Single Exposure): May cause respiratory         
irritation. May cause drowsiness and dizziness.                                 
Specific Target Organ Toxicity (Repeated Exposure): May cause damage to organs  
through prolonged or repeated exposure.                                         
Aspiration Hazard: May be fatal if swallowed and enters airways.                
Symptoms/Injuries After Inhalation: Irritating to eyes, respiratory system and  
Symptoms/Injuries After Skin Contact: Irritating to skin.                       
Symptoms/Injuries After Eye Contact: Irritating to eyes.                        
Symptoms/Injuries After Ingestion:                                              
Chronic Symptoms: Intentional misuse by deliberately concentrating and inhaling 
contents may be harmful or fatal. Chronic hydrocarbon abuse has been associated 
with irregular heart rhythms and potential cardiac arrest. Prolonged skin
may defat the skin and produce dermatitis. May cause adverse liver effects.     

SECTION 12: ECOLOGICAL INFORMATION                                              

12.1. Toxicity
Chemical Name                                                                   
Toxicity to algae                                                               
Toxicity to fish                                                                
Toxicity to                                                                     
Toxicity to daphnia and other aquatic   invertebrates                           
4.74 - 6.33 mL/L LC50                                                           
Oncorhynchus mykiss 96h 6210 - 8120 mg/L LC50 Pimephales promelas 96h static
mg/L LC50 Lepomis macrochirus 96h                                               
10294 - 17704 mg/L EC50 Daphnia magna 48h Static 12600 - 12700 mg/L EC50 Daphnia
magna 48h                                                                       
433 mg/L EC50 Pseudokirchneriella subcapitata 96h 12.5 mg/L EC50                
subcapitata 72h static                                                          
11.0 - 15.0 mg/L LC50 Lepomis macrochirus 96h static 14.1 - 17.16 mg/L LC50     
Oncorhynchus mykiss                                                             
96h static 15.22 - 19.05 mg/L LC50 Pimephales promelas 96h flow-through         
5.89 - 7.81 mg/L LC50                                                           
Oncorhynchus mykiss 96h flow-through 50.87 - 70.34                              
mg/L LC50 Poecilia reticulata 96h static 12.6 mg/L LC50 Pimephales promelas 96h 
static 28.2                                                                     
mg/L LC50 Poecilia                                                              
reticulata 96h semi-static 5.8 mg/L LC50 Oncorhynchus                           
mykiss 96h semi-static 54 mg/L LC50 Oryzias latipes 96h static                  
5.46 - 9.83 mg/L EC50  Daphnia magna 48h Static 11.5 mg/L EC50 Daphnia magna 48h

12.2. Persistence and Degradability
No information available.                                                       

12.3. Bioaccumulative Potential
No information available.                                                       
Chemical Name                                                    log Pow        
ACETONE                                                               -0.24     
TOLUENE                                                                2.65     

12.4. Mobility in Soil

12.5. Other Adverse Effects
No information available                                                        

13.1. Waste treatment methods
Waste Disposal Recommendations: This material, as supplied, is a hazardous waste
according to federal regulations (40 CFR                                        
Additional Information: Do not re-use empty containers.                         

SECTION 14: TRANSPORT INFORMATION                                               

14.1 In Accordance with DOT
Proper Shipping Name |FLAMMABLE LIQUIDS, N.O.S. (ACETONE, TOLUENE)              
Hazard Class         |3                      |<PICTOGRAM PHRASE>                
Identification Number|UN1993                 |                                  
Label Codes          |                       |                                  
ERG Number           |                                                          

14.2 In Accordance with IMDG
Proper Shipping Name |FLAMMABLE LIQUIDS, N.O.S. (ACETONE, TOLUENE)              
Hazard Class         |3                                                         
Identification Number|UN1993                                                    
Label Codes          |                      |<PICTOGRAM PHRASE>                 
ntification Of The   |                      |                                   
Substance/m          |                      |                                   
EmS-No. (Fire)       |                      |                                   
EmS-No. (Spillage)   |                      |                                   

14.3 In Accordance with IATA
Proper Shipping Name |FLAMMABLE LIQUIDS, N.O.S. (ACETONE, TOLUENE)              
Identification Number|UN1993                 |<PICTOGRAM PHRASE>                
Hazard Class         |3                      |                                  
Label Codes          |                       |                                  
ntification Of The   |                       |                                  
Substance/m          |                       |                                  
ERG Code (IATA)      |                                                          

SECTION 15: REGULATORY INFORMATION                                              

15.1      US Federal Regulations
SARA 313: Section 313 of Title III of the Superfund Amendments and
Act of 1986 (SARA). This product contains a chemical or chemicals which are     
subject to the reporting requirements of the Act and Title 40 of the Code of    
Federal Regulations, Part 372:                                                  
Chemical Name                                                                   
Weight %*                                                                       
SARA 313 - Threshold                                                            
Values %                                                                        
TOLUENE - 108-88-3                                                              
Clean Water Act: This product contains the following substances which are       
regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR  
Chemical Name                                                                   
CWA - Reportable                                                                
CWA - Toxic Pollutants                                                          
CWA - Priority Pollutants                                                       
CWA - Hazardous                                                                 
1000 lb                                                                         
CERCLA: This material, as supplied, contains one or more substances regulated as
hazardous substance under the Comprehensive Environmental Response Compensation 
and Liability Act (CERCLA) (40 CFR 302):                                        
Chemical Name                                                                   
Hazardous Substances RQs                                                        
Extremely Hazardous Substances RQs                                              
5000 lb                                                                         
RQ 5000 lb final RQ                                                             
RQ 2270 kg final RQ                                                             
1000 lb 1 lb                                                                    
RQ 1000 lb final RQ                                                             
RQ 454 kg final RQ RQ 1 lb final RQ                                             
RQ 0.454 kg final RQ                                                            
SARA Section 311/312 Hazard Classes |Acute Health Hazard:                       
                                    |Chronic Health Hazard:                     
                                    |Fire Hazard:                               
                                    |Sudden Release of Pressure Hazard:  no     
                                    |Reactive Hazard:                           
Toxic Substances Control Act (TSCA) |Chemical Name                              

15.2      US State Regulations
California Proposition 65: This product contains the following Proposition 65   
Chemical Name                                                                   
California Prop. 65                                                             
TOLUENE - 108-88-3                                                              
Developmental Female Reproductive                                               
U.S. State Right-to-Know Regulations                                            
Chemical Name                                                                   
New Jersey                                                                      


Revision date   |19-May-2015                                                    
Other           |This document has been prepared in accordance with the SDS     
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR  
GHS Full Text Phrases:                                                          
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Grainger disclaimer.

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.