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SDS Sheet 0046400

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SECTION 1: IDENTIFICATION                                                       
 


1.1.  Product Identifier
Product Form:                                                                   
 
Product Name: 4640-0 GALLON GLASS CLEANER                                       
 
CAS No:                                                                         
 
Synonyms: None                                                                  
 


1.2.  Intended Use of the Product
Use of the substance/mixture: No information available.                         
 


1.3.  Name, Address, and Telephone of the Responsible Party
Company                                                                         
 
Imperial Supplies LLC                                                           
 
789 Armed Forces Drive                                                          
 
P.O. Box 11008                                                                  
 
Green Bay, WI 53407-1038                                                        
 
Phone                                                                           
 


1.4.  Emergency Telephone Number
Emergency     | Chemtrec 1-800-424-9300                                         
 
number        |                                                                 
 

SECTION 2: HAZARDS IDENTIFICATION                                               
 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Skin          |Category 1    
corrosion/irri|              
tation        |              
Serious eye   |Category 1    
damage/eye    |              
irritation    |              
              |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Corrosion 
        
Signal Word (GHS-US)         |DANGER                                            
 
Hazard Statements (GHS-US)   |Causes severe skin burns and eye damage           
 
Precautionary Statements     |Prevention:                                       
 
(GHS-US)                     |Do not breathe dust/fume/gas/mist/vapors/spray    
 
                             |Wash face, hands and any exposed skin thoroughly  
 
                             |after handling                                    
 
                             |Wear protective gloves/protective clothing/eye    
 
                             |protection/face protection                        
 
                             |Response:                                         
 
                             |Immediately call a POISON CENTER or               
 
                             |doctor/physician.                                 
 
                             |Specific treatment (see first aid on this label)  
 
                             |IF IN EYES: Rinse cautiously with water for
several 
                             |minutes. Remove contact lenses, if present and
easy 
                             |to do. Continue rinsing.                          
 
                             |Immediately call a POISON CENTER or               
 
                             |doctor/physician.                                 
 
                             |IF ON SKIN (or hair): Remove/Take off immediately 
 
                             |all contaminated clothing. Rinse skin with        
 
                             |water/shower                                      
 
                             |Wash contaminated clothing before reuse           
 
                             |IF INHALED: Remove person to fresh air and keep   
 
                             |comfortable for breathing.                        
 
                             |Immediately call a POISON CENTER or               
 
                             |doctor/physician.                                 
 
                             |IF SWALLOWED: Rinse mouth. Do NOT induce vomiting 
 
                             |Storage:                                          
 
                             |Store locked up                                   
 
                             |Disposal:                                         
 
                             |Dispose of contents/container to an approved waste
 
                             |disposal plant                                    
 


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification: None                      
 


2.4.  Unknown Acute Toxicity (GHS-US)
0.002% of the mixture consists of ingredient(s) of unknown toxicity             
 

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                               
 


3.1.  Substance
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
2-BUTOXYETHANOL                 |111-76-2             |1-10    |                
 
AMMONIA                         |1336-21-6            |0.1-1   |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


SECTION 4: FIRST AID MEASURES                                                   
 


4.1.  Description of First Aid Measures
First-aid Measures General:                                                     
 
First-aid Measures After Inhalation: Move to fresh air. If breathing is
difficult,
give oxygen. Artificial respiration and/or oxygen                               
 
may be necessary. If breathing has stopped, contact emergency medical services  
 
immediately.                                                                    
 
First-aid Measures After Skin Contact: Wash off immediately with soap and plenty
 
of water while removing all contaminated                                        
 
clothes and shoes. If symptoms persist, call a physician.                       
 
First-aid Measures After Eye Contact: Rinse immediately with plenty of water,
also
under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. If
 
symptoms persist, call a physician.                                             
 
First-aid Measures After Ingestion: Rinse mouth. Do NOT induce vomiting. Never  
 
give anything by mouth to an unconscious                                        
 
person. Drink plenty of water. Call a physician or Poison Control Center        
 
immediately.                                                                    
 


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries:                                                              
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact: Causes severe skin burns.                 
 
Symptoms/Injuries After Eye Contact: Causes  eye irritaton.                     
 
Symptoms/Injuries After Ingestion: Harmful if swallowed.                        
 
Chronic Symptoms:  Notes to physician: Treat symptomatically.                   
 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
Notes to physician: Treat symptomatically.                                      
 

SECTION 5: FIRE-FIGHTING MEASURES                                               
 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Use extinguishing measures that are appropriate to
 
local circumstances and the surrounding environment.                            
 
Unsuitable Extinguishing Media: Decomposition by contact with water may generate
 
vapors which can be ignited by heat or open flame.                              
 


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: No information available.                                          
 
Explosion Hazard:                                                               
 
Sensitivity to Mechanical Impact: none.                                         
 
Sensitivity to Static Discharge: none.                                          
 
Reactivity:                                                                     
 


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                    
 
Firefighting Instructions:                                                      
 
Protection During Firefighting: As in any fire, wear self-contained breathing   
 
apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective
gear.                                                                           
 

SECTION 6: ACCIDENTAL RELEASE MEASURES                                          
 


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Avoid contact with the skin and the eyes. Ensure adequate     
 
ventilation. Avoid dust formation. Keep people away from and upwind of
spill/leak.


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.1.2.      For Emergency Responders
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.2.  Environmental Precautions
Prevent further leakage or spillage if safe to do so. Do not allow material to  
 
contaminate ground water system. Prevent product from entering drains. Do not   
 
flush into surface water or sanitary sewer system.                              
 


6.3.  Methods and Material for Containment and Cleaning Up
For Containment: Absorb or cover with dry earth, sand or other non-combustible  
 
material and transfer to containers. Prevent further leakage or spillage if safe
 
to do so.                                                                       
 
Methods for Cleaning Up: Pick up and transfer to properly labeled containers.
Soak
up with inert absorbent material. Clean contaminated surface thoroughly. After  
 
cleaning, flush away traces with water.                                         
 


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                      
 


SECTION 7: HANDLING AND STORAGE                                                 
 


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Avoid contact with skin, eyes and clothing.  
 
Handle in accordance with good industrial hygiene and safety practice. Remove
and 
wash contaminated clothing before re-use.                                       
 
Hygiene Measures: Handle in accordance with good industrial hygiene and safety  
 
practice.                                                                       
 


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                             
 
Storage Conditions: Keep container tightly closed in a dry and well-ventilated  
 
place. Keep in properly labeled containers. Keep out of the reach of children.  
 
Store locked up.                                                                
 
Incompatible products: None known based on information supplied.                
 
Aerosol Level: 1                                                                
 


7.3.  Specific End Use(s)
                                                                                
 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                
 


8.1.  Control Parameters
Exposure Guidelines                                                             
 
Chemical Name                                                                   
 
ACGIH TLV                                                                       
 
OSHA PEL                                                                        
 
NIOSH IDLH                                                                      
 
                                                                                
 
2-BUTOXYETHANOL                                                                 
 
111-76-2                                                                        
 
TWA: 20 ppm                                                                     
 
TWA: 50 ppm                                                                     
 
TWA: 240 mg/m3                                                                  
 
(vacated) TWA: 25 ppm                                                           
 
(vacated) TWA: 120 mg/m3                                                        
 
(vacated) S*                                                                    
 
S*                                                                              
 
IDLH: 700 ppm                                                                   
 
TWA: 5 ppm                                                                      
 
TWA: 24 mg/m3                                                                   
 
                                                                                
 
Other Exposure Guidelines: Vacated limits revoked by the Court of Appeals
decision
in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992).                             
 


8.2.  Exposure Controls
Appropriate Engineering      |Showers                                           
 
Controls                     |Eyewash stations                                  
 
                             |Ventilation systems.                              
 
Personal Protective Equipment|                                                  
 
Materials for Protective     |                                                  
 
Clothing                     |                                                  
 
Hand Protection              |                                                  
 
Eye Protection               |Safety glasses with side-shields.                 
 
Skin and Body Protection     |Chemical resistant apron. Protective gloves.      
 
Respiratory Protection       |If exposure limits are exceeded or irritation is  
 
                             |experienced, NIOSH/MSHA approved respiratory      
 
                             |protection should be worn. Positive-pressure      
 
                             |supplied air respirators may be required for high 
 
                             |airborne contaminant concentrations. Respiratory  
 
                             |protection must be provided in accordance with    
 
                             |current local regulations.                        
 
Thermal Hazard Protection    |                                                  
 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                     
 


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |Liquid                                     
 
Appearance                          |Clear                                      
 
Odor                                |Ammonia                                    
 
Odor Threshold                      |No information available                   
 
pH                                  |12.9                                       
 
Relative Evaporation Rate           |No information available                   
 
(butylacetate=1)                    |                                           
 
Melting Point                       |No information available                   
 
Freezing Point                      |No information available                   
 
Boiling Point                       |No information available                   
 
Flash Point                         |No information available                   
 
Auto-ignition Temperature           |No information available                   
 
Decomposition Temperature           |No information available                   
 
Flammability (solid, gas)           |No information available                   
 
Vapor Pressure                      |No information available                   
 
Relative Vapor Density at 20 °C     |                                           
 
Relative Density                    |                                           
 
Specific Gravity                    |1.002                                      
 
Solubility                          |Practically insoluble                      
 
Partition coefficient:              |No information available                   
 
n-octanol/water                     |                                           
 
Viscosity                           |No information available                   
 
Lower Flammable Limit               |No information available                   
 
Upper Flammable Limit               |No information available                   
 


9.2.  Other Information
VOC Content(%): 2.8                                                             
 

SECTION 10: STABILITY AND REACTIVITY                                            
 


10.1      Reactivity
No data available.                                                              
 


10.2      Chemical Stability
Stable under recommended storage conditions.                                    
 


10.3      Possibility of Hazardous Reactions
None under normal processing.                                                   
 


10.4      Conditions to Avoid
Extremes of temperature and direct sunlight.                                    
 


10.5      Incompatible Materials
None known based on information supplied.                                       
 


10.6      Hazardous Decomposition Products
None known based on information supplied.                                       
 

SECTION 11: TOXICOLOGICAL INFORMATION                                           
 


11.1. Information on Toxicological Effects
Acute Toxicity:                                                                 
 
Skin Corrosion/Irritation: Contact causes severe skin irritation and possible   
 
burns. Avoid contact with skin.                                                 
 
Serious Eye Damage/Irritation: May cause irreversible damage to eyes. Avoid     
 
contact with eyes. Risk of serious damage to eyes.                              
 
Respiratory or Skin Sensitization: Avoid breathing vapors or mists. None known. 
 
Germ Cell Mutagenicity: None known.                                             
 
Carcinogenicity: The table below indicates whether each agency has evaluated a  
 
listed ingredient as a carcinogen.                                              
 
Reproductive Toxicity: This product does not contain any known or suspected     
 
reproductive hazards.                                                           
 
Specific Target Organ Toxicity (Single Exposure): None under normal use         
 
conditions.                                                                     
 
Specific Target Organ Toxicity (Repeated Exposure): None under normal use       
 
conditions.                                                                     
 
Aspiration Hazard: Not applicable.                                              
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact: Causes burns. Causes severe burns.        
 
Symptoms/Injuries After Eye Contact: Risk of serious damage to eyes. Causes eye 
 
damage.                                                                         
 
Symptoms/Injuries After Ingestion: May be fatal if swallowed and enters airways.
 
Chronic Symptoms: May cause adverse liver effects.                              
 

SECTION 12: ECOLOGICAL INFORMATION                                              
 


12.1. Toxicity
Chemical Name                                                                   
 
Toxicity to algae                                                               
 
Toxicity to fish                                                                
 
Toxicity to                                                                     
 
microorganisms                                                                  
 
Toxicity to daphnia and other aquatic invertebrates                             
 
                                                                                
 
2-BUTOXYETHANOL                                                                 
 
111-76-2                                                                        
 
-                                                                               
 
1490 mg/L LC50 Lepomis macrochirus 96h static 2950 mg/L LC50 Lepomis macrochirus
 
96h                                                                             
 
-                                                                               
 
1000 mg/L EC50 Daphnia magna 48h                                                
 
                                                                                
 
AMMONIA                                                                         
 
1336-21-6                                                                       
 
-                                                                               
 
8.2 mg/L LC50 Pimephales promelas 96h                                           
 
-                                                                               
 
0.66 mg/L EC50 Daphnia pulex 48h 0.66 mg/L EC50 water flea 48h                  
 
                                                                                
 


12.2. Persistence and Degradability
No information available.                                                       
 


12.3. Bioaccumulative Potential
No information available.                                                       
 
Chemical Name                                                                   
 
log Pow                                                                         
 
                                                                                
 
2-BUTOXYETHANOL   111-76-2                                                      
 
0.81                                                                            
 
                                                                                
 


12.4. Mobility in Soil
                                                                                
 


12.5. Other Adverse Effects
No information available.                                                       
 

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: This material, as supplied, is a hazardous waste
 
according to federal regulations (40 CFR 261).                                  
 
Additional Information: Do not re-use empty containers.                         
 

SECTION 14: TRANSPORT INFORMATION                                               
 


14.1 In Accordance with DOT
Proper Shipping Name |NOT REGULATED FOR SHIPMENT                                
 
Hazard Class         |                       |<PICTOGRAM PHRASE>                
 
Identification Number|                       |                                  
 
Label Codes          |                       |                                  
 
ERG Number           |                                                          
 


14.2 In Accordance with IMDG
Proper Shipping Name |NOT REGULATED FOR SHIPMENT                                
 
Hazard Class         |                                                          
 
Identification Number|                                                          
 
Label Codes          |                      |<PICTOGRAM PHRASE>                 
 
ntification Of The   |                      |                                   
 
Substance/m          |                      |                                   
 
EmS-No. (Fire)       |                      |                                   
 
EmS-No. (Spillage)   |                      |                                   
 


14.3 In Accordance with IATA
Proper Shipping Name |NOT REGULATED FOR SHIPMENT                                
 
Identification Number|                       |<PICTOGRAM PHRASE>                
  
Hazard Class         |                       |                                  
  
Label Codes          |                       |                                  
  
ntification Of The   |                       |                                  
  
Substance/m          |                       |                                  
  
ERG Code (IATA)      |                                                          
 

SECTION 15: REGULATORY INFORMATION                                              
 

15.1      US Federal Regulations
<COMPONENT>                                                                     
 
SARA 313: Section 313 of Title III of the Superfund Amendments and
Reauthorization
Act of 1986 (SARA). This product contains a chemical or chemicals which are     
 
subject to the reporting requirements of the Act and Title 40 of the Code of    
 
Federal Regulations, Part 372:                                                  
 
Chemical Name                                                                   
 
CAS-No                                                                          
 
Weight %*                                                                       
 
SARA 313 - Threshold  Values %                                                  
 
                                                                                
 
2-BUTOXYETHANOL -                                                               
 
111-76-2                                                                        
 
111-76-2                                                                        
 
1-10                                                                            
 
1.0                                                                             
 
                                                                                
 
AMMONIA - 1336-21-6                                                             
 
1336-21-6                                                                       
 
0.1-1                                                                           
 
1.0                                                                             
 
                                                                                
 
                                                                                
 
Clean Water Act: This product contains the following substances which are       
 
regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR  
 
122.42):                                                                        
 
Chemical Name                                                                   
 
CWA - Reportable                                                                
 
Quantities                                                                      
 
CWA - Toxic Pollutants                                                          
 
CWA - Priority Pollutants                                                       
 
CWA - Hazardous                                                                 
 
Substances                                                                      
 
                                                                                
 
AMMONIA                                                                         
 
1336-21-6                                                                       
 
1000 lb                                                                         
 
                                                                                
 
                                                                                
 
X                                                                               
 
                                                                                
 
                                                                                
 
CERCLA: This material, as supplied, contains one or more substances regulated as
a
hazardous substance under the Comprehensive Environmental Response Compensation 
 
and Liability Act (CERCLA) (40 CFR 302):                                        
 
Chemical Name                                                                   
 
Hazardous Substances RQs                                                        
 
Extremely Hazardous Substances RQs                                              
 
RQ                                                                              
 
                                                                                
 
AMMONIA                                                                         
 
1336-21-6                                                                       
 
1000 lb                                                                         
 
                                                                                
 
RQ 1000 lb final RQ                                                             
 
RQ 454 kg final RQ                                                              
 
                                                                                
 
SARA Section 311/312 Hazard Classes |Acute Health Hazard: Yes                   
 
                                    |Chronic Health Hazard: Yes                 
 
                                    |Fire Hazard: no                            
 
                                    |Sudden Release of Pressure Hazard: no      
 
                                    |Reactive Hazard: no                        
 
Toxic Substances Control Act (TSCA) |Chemical Name                              
 
                                    |TSCA                                       
 
                                    |                                           
 
                                    |2-BUTOXYETHANOL                            
 
                                    |X                                          
 
                                    |                                           
 
                                    |AMMONIA                                    
 
                                    |X                                          
 
                                    |                                           
 

15.2      US State Regulations
<COMPONENT>                                                                     
 
California Proposition 65: This product does not contain any known Proposition
65 
chemicals.                                                                      
 
U.S. State Right-to-Know Regulations:                                           
 
Chemical Name                                                                   
 
New Jersey                                                                      
 
Massachusetts                                                                   
 
Pennsylvania                                                                    
 
                                                                                
 
2-BUTOXYETHANOL                                                                 
 
111-76-2                                                                        
 
X                                                                               
 
X                                                                               
 
X                                                                               
 
                                                                                
 
AMMONIA                                                                         
 
1336-21-6                                                                       
 
X                                                                               
 
X                                                                               
 
X                                                                               
 
                                                                                
 
EPA Pesticide Registration Number: Not applicable.                              
 
                                                                                
 

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION   
 

Revision date   |20-May-2015                                                    
 
Other           |This document has been prepared in accordance with the SDS     
 
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR  
 
                |1910.1200.                                                     
 
GHS Full Text Phrases:                                                          
 
----|                               |                                           
 
--  |                               |                                           
 
----|                               |                                           
 
--  |                               |                                           
 
----|                               |                                           
 
--  |                               |                                           
 
----|                               |                                           
 
--  |                               |                                           
 
----|                               |                                           
 
--  |                               |                                           
 


Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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