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SDS Sheet 0046114Printer Friendly View
Safety Data Sheet Date of Issue: 20-May-2015 |Revision Date: 20-May-2015 |Revision Number: 1 Imperial Supplies Part Number: 0046114 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: 4711 PINT LIQUID DE-ICER CAS No: Synonyms: None 1.2. Intended Use of the Product Use of the substance/mixture: De-Icer. 1.3. Name, Address, and Telephone of the Responsible Party Company Imperial Supplies LLC 789 Armed Forces Drive P.O. Box 11008 Green Bay, WI 53407-1038 1.4. Emergency Telephone Number Emergency |Chemical Emergency Phone Number: Chemtrec 1-800-424-9300 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Acute Toxicity|Category 3 - Oral | Acute Toxicity|Category 3 - Dermal | Acute toxicity|Category 3 - Inhalation | (Dusts/Mists) | Specific |Category 1 target organ | toxicity | (single | exposure) | Flammable |Category 2 Liquids | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Skull & |Health |Flame | | | |Crossbon|Hazard | | | | |es | | | | | Signal Word (GHS-US) |DANGER Hazard Statements (GHS-US) |Toxic if swallowed |Toxic in contact with skin |Toxic if inhaled |Causes damage to organs (Central Nervous System, |Eyes, Gastrointestinal Tract, Respiratory System, |and Skin) through prolonged or repeated exposure. |Highly flammable liquid and vapor Precautionary Statements |Prevention: (GHS-US) |Wash face, hands and any exposed skin thoroughly |after handling |Do not eat, drink or smoke when using this product |Wear protective gloves/protective clothing/eye |protection/face protection |Use only outdoors or in a well-ventilated area |Do not breathe dust/fume/gas/mist/vapors/spray |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking |Keep container tightly closed |Ground/Bond container and receiving equipment |Use explosion-proof electrial/ventilating/lighting |/equipment. |Use only non-sparking tools |Take precautionary measures against static discharge | |Response: |Specific treatment (see first aid on this label) |IF exposed: Call a POISON CENTER or doctor/physician | |IF ON SKIN (or hair): Remove/Take off immediately |all contaminated clothing. Rinse skin with |water/shower |IF INHALED: Remove person to fresh air and keep |comfortable for breathing. |Call a POISON CENTER or doctor/physician |IF SWALLOWED: Immediately call a POISON CENTER or |doctor/physician |Rinse mouth |In case of fire: Use CO2, dry chemical, or foam for |extinction |Storage: |Store locked up |Store in a well-ventilated place. Keep container |tightly closed |Keep cool. |Disposal: Dispose of contents/container to an |approved waste disposal plant 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None 2.4. Unknown Acute Toxicity (GHS-US) Harmful to aquatic life with long lasting effects. 0% of the mixture consists of ingredient(s) of unknown toxicity. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) METHANOL |67-56-1 |90-100 | PROPYLENE GLYCOL |57-55-6 |1-10 | | | | | | | *The exact percentage (concentration) of composition has been withheld as a trade secret. SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Avoid contact with eyes,skin, and clothing. Avoid breathing, vapors,mist,or gas. First-aid Measures After Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing has stopped, contact emergency medical services immediately. First-aid Measures After Skin Contact: Wash off immediately with soap and plenty of water. Remove and wash contaminated clothing before re-use. Get medical attention immediately if symptoms occur. First-aid Measures After Eye Contact: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Seek immediate medical attention/advice. First-aid Measures After Ingestion: Do NOT induce vomiting. Call a physician immediately. Never give anything by mouth to an unconscious person. Risk of product entering the lungs on vomiting after ingestion. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Harmful if ingested. Causes skin irritations and harmful in contact with skin. May cause an allergic skin reaction. Causes serious eye damage and irritation. May cause respiratory irritation. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Notes to physician: Treat symptomatically. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Water fog. Dry chemical. Carbon dioxide (CO2). Cool containers/tanks with water spray. Unsuitable Extinguishing Media: Keep away from heat and sources of ignition. Do not smoke. Cool containers / tanks with water spray. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: No information available. Explosion Hazard: Sensitivity to Mechanical Impact none. Sensitivity to Static Discharge Yes. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Personal precautions: Evacuate personnel to safe areas. Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Avoid dust formation. Remove all sources of ignition. Keep people away from and upwind of spill/leak. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. Prevent further leakage or spillage if safe to do so. Do not allow material to contaminate ground water system. Prevent product from entering drains. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up: Pick up and transfer to properly labeled containers. Soak up with inert absorbent material. Clean contaminated surface thoroughly. After cleaning, flush away traces with water. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Hygiene Measures: Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharges. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Keep container tightly closed in a dry and well-ventilated place. Keep away from open flames, hot surfaces and sources of ignition. Keep in properly labeled containers. Keep out of the reach of children. Store locked up. Storage Conditions: 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). 8.2. Exposure Controls Appropriate Engineering |Showers, Eyewash stations, Ventilation systems. Controls | Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Safety glasses with side-shields. Skin and Body Protection |Chemical resistant apron. Protective gloves. Respiratory Protection |If exposure limits are exceeded or irritation is |experienced, NIOSH/MSHA approved respiratory |protection should be worn. Positive-pressure |supplied air respirators may be required for high |airborne contaminant concentrations. Respiratory |protection must be provided in accordance with |current local regulations. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid Appearance |Clear Odor |Solvent Odor Threshold |No information available pH |No information available Relative Evaporation Rate |No information available (butylacetate=1) | Melting Point |No information available Freezing Point |No information available Boiling Point |No information available Flash Point |12 Â°C / 54 Â°F (Based on lowest flashpoint of |the products |Constituent). Auto-ignition Temperature |No information available Decomposition Temperature |No information available Flammability (solid, gas) |No information available Vapor Pressure |No information available Relative Vapor Density at 20 Â°C |No information available Relative Density | Specific Gravity |0.809 Solubility |Water solubility: Practically insoluble Partition coefficient: |No information available n-octanol/water | Viscosity |No information available Lower Flammable Limit | Upper Flammable Limit | 9.2. Other Information VOC Content(%): 97.5 SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No data available. 10.2 Chemical Stability Stable under recommended storage conditions. 10.3 Possibility of Hazardous Reactions None under normal processing. 10.4 Conditions to Avoid Extremes of temperature and direct sunlight. 10.5 Incompatible Materials Strong acids, alkalis, or oxidizing agents. 10.6 Hazardous Decomposition Products None known based on information supplied. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Unknown Acute Toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 102 mg/kg ATEmix (dermal) 308 mg/kg ATEmix (inhalation-dust/mist) 0.5 mg/l Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: None known Germ Cell Mutagenicity: None known. Carcinogenicity: There are no known carcinogenic chemicals in this product. Reproductive Toxicity: This product does not contain any known or suspected reproductive hazards. Specific Target Organ Toxicity (Single Exposure): May cause drowsiness and dizziness. May cause drowsiness and dizziness. Specific Target Organ Toxicity (Repeated Exposure): Causes damage to organs through prolonged or repeated exposure if swallowed. Causes damage to organs through prolonged or repeated exposure if inhaled. Aspiration Hazard: May be fatal if swallowed and enters airways. Symptoms/Injuries After Inhalation: Toxic by inhalation. Avoid breathing vapors or mists. Symptoms/Injuries After Skin Contact: Toxic in contact with skin. Avoid contact with skin and clothing. Symptoms/Injuries After Eye Contact: Avoid contact with eyes. Symptoms/Injuries After Ingestion: Toxic if swallowed. Harmful if swallowed. May be fatal if swallowed and enters airways. Chronic Symptoms: Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Chronic hydrocarbon abuse has been associated with irregular heart rhythms and potential cardiac arrest. Prolonged skin contact may defat the skin and produce dermatitis. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity 12.2. Persistence and Degradability No information available. 12.3. Bioaccumulative Potential No information available. METHANOL log Pow 67-56-1 -0.77 12.4. Mobility in Soil 12.5. Other Adverse Effects No information available. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Additional Information: Contaminated packaging: Do not re-use empty containers. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |CONSUMER COMMODITY ORM-D or LIMITED QUANTITY Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |METHANOL SOLUTION Hazard Class |3 (6.1) Identification Number|UN1230 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |METHANOL SOLUTION Identification Number|UN1230 |<PICTOGRAM PHRASE> Hazard Class |3 (6.1) | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA 313: Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Chemical Name CAS-No Weight %* SARA 313 - Threshold Values % METHANOL - 67-56-1 67-56-1 90-100 1.0 Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302): Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQs RQ METHANOL 67-56-1 5000 lb RQ 5000 lb final RQ RQ 2270 kg final RQ SARA Section 311/312 Hazard Classes |Acute Health Hazard |Yes |Chronic Health Hazard |Yes |Fire Hazard |Yes |Sudden Release of Pressure Hazard |no |Reactive Hazard |no Toxic Substances Control Act (TSCA) | 15.2 US State Regulations <COMPONENT> California Proposition 65: This product contains the following Proposition 65 chemicals: Chemical Name California Prop. 65 METHANOL - 67-56-1 Carcinogen U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania METHANOL 67-56-1 X X X PROPYLENE GLYCOL 57-55-6 X X Canada: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class B2 Flammable liquid D1A Very toxic materials D2B Toxic materials SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |20-May-2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.