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SDS Sheet 0046114

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Safety Data Sheet                                                                 
Date of Issue: 20-May-2015 |Revision Date: 20-May-2015 |Revision Number: 1        
Imperial Supplies Part Number: 0046114                                            

SECTION 1: IDENTIFICATION                                                         

1.1.  Product Identifier
Product Form:                                                                     
Product Name: 4711 PINT LIQUID DE-ICER                                            
CAS No:                                                                           
Synonyms: None                                                                    

1.2.  Intended Use of the Product
Use of the substance/mixture: De-Icer.                                            

1.3.  Name, Address, and Telephone of the Responsible Party
Imperial Supplies LLC                                                             
789 Armed Forces Drive                                                            
P.O. Box 11008                                                                    
Green Bay, WI 53407-1038                                                          

1.4.  Emergency Telephone Number
Emergency     |Chemical Emergency Phone Number: Chemtrec 1-800-424-9300           
number        |                                                                   

SECTION 2: HAZARDS IDENTIFICATION                                                 

2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Acute Toxicity|Category 3    
- Oral        |              
Acute Toxicity|Category 3    
- Dermal      |              
Acute toxicity|Category 3    
- Inhalation  |              
(Dusts/Mists) |              
Specific      |Category 1    
target organ  |              
toxicity      |              
(single       |              
exposure)     |              
Flammable     |Category 2    
Liquids       |              

2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Skull & |Health  |Flame   |        |        |        
                             |Crossbon|Hazard  |        |        |        |        
                             |es      |        |        |        |        |        
Signal Word (GHS-US)         |DANGER                                              
Hazard Statements (GHS-US)   |Toxic if swallowed                                  
                             |Toxic in contact with skin                          
                             |Toxic if inhaled                                    
                             |Causes damage to organs (Central Nervous System,    
                             |Eyes, Gastrointestinal Tract, Respiratory System,   
                             |and Skin) through prolonged or repeated exposure.   
                             |Highly flammable liquid and vapor                   
Precautionary Statements     |Prevention:                                         
(GHS-US)                     |Wash face, hands and any exposed skin thoroughly    
                             |after handling                                      
                             |Do not eat, drink or smoke when using this product  
                             |Wear protective gloves/protective clothing/eye      
                             |protection/face protection                          
                             |Use only outdoors or in a well-ventilated area      
                             |Do not breathe dust/fume/gas/mist/vapors/spray      
                             |Keep away from heat/sparks/open flames/hot surfaces.
                             |- No smoking                                        
                             |Keep container tightly closed                       
                             |Ground/Bond container and receiving equipment       
                             |Use explosion-proof electrial/ventilating/lighting  
                             |Use only non-sparking tools                         
                             |Take precautionary measures against static discharge
                             |Specific treatment (see first aid on this label)    
                             |IF exposed: Call a POISON CENTER or doctor/physician
                             |IF ON SKIN (or hair): Remove/Take off immediately   
                             |all contaminated clothing. Rinse skin with          
                             |IF INHALED: Remove person to fresh air and keep     
                             |comfortable for breathing.                          
                             |Call a POISON CENTER or doctor/physician            
                             |IF SWALLOWED: Immediately call a POISON CENTER or   
                             |Rinse mouth                                         
                             |In case of fire: Use CO2, dry chemical, or foam for 
                             |Store locked up                                     
                             |Store in a well-ventilated place. Keep container    
                             |tightly closed                                      
                             |Keep cool.                                          
                             |Disposal: Dispose of contents/container to an       
                             |approved waste disposal plant                       

2.3.  Other Hazards
Other Hazards Not Contributing to the Classification: None                        

2.4.  Unknown Acute Toxicity (GHS-US)
 Harmful to aquatic life with long lasting effects.                               
0% of the mixture consists of ingredient(s) of unknown toxicity.                  


3.1.  Substance
Name                            |Product identifier   |%       |Classification    
                                |                     |        |(GHS-US)          
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  

Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification    
                                |                     |        |(GHS-US)          
METHANOL                        |67-56-1              |90-100  |                  
PROPYLENE GLYCOL                |57-55-6              |1-10    |                  
                                |                     |        |                  
                                |                     |        |                  
*The exact percentage (concentration) of composition has been withheld as a trade 

SECTION 4: FIRST AID MEASURES                                                     

4.1.  Description of First Aid Measures
First-aid Measures General: Avoid contact with eyes,skin, and clothing. Avoid     
breathing, vapors,mist,or gas.                                                    
First-aid Measures After Inhalation: Move to fresh air. If not breathing, give    
artificial respiration. If breathing has stopped, contact emergency medical       
services immediately.                                                             
First-aid Measures After Skin Contact: Wash off immediately with soap and plenty  
of water. Remove and wash contaminated                                            
clothing before re-use. Get medical attention immediately if symptoms occur.      
First-aid Measures After Eye Contact: Immediately flush with plenty of water.     
After initial flushing, remove any contact lenses and continue flushing for at    
least 15 minutes. Seek immediate medical attention/advice.                        
First-aid Measures After Ingestion: Do NOT induce vomiting. Call a physician      
immediately. Never give anything by mouth to an                                   
unconscious person. Risk of product entering the lungs on vomiting after          

4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries: Harmful if ingested. Causes skin irritations and harmful in    
contact with skin. May cause an allergic skin reaction. Causes serious eye damage 
and irritation. May cause respiratory irritation.                                 
Symptoms/Injuries After Inhalation:                                               
Symptoms/Injuries After Skin Contact:                                             
Symptoms/Injuries After Eye Contact:                                              
Symptoms/Injuries After Ingestion:                                                
Chronic Symptoms:                                                                 

4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Notes to physician: Treat symptomatically.                                        

SECTION 5: FIRE-FIGHTING MEASURES                                                 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Water fog. Dry chemical. Carbon dioxide (CO2). Cool 
containers/tanks with water spray.                                                
Unsuitable Extinguishing Media: Keep away from heat and sources of ignition. Do   
not smoke. Cool containers / tanks with water spray.                              

5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: No information available.                                            
Explosion Hazard: Sensitivity to Mechanical Impact             none.              
Sensitivity to Static Discharge                   Yes.                            

5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                      
Firefighting Instructions:                                                        
Protection During Firefighting: As in any fire, wear self-contained breathing     
apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective

SECTION 6: ACCIDENTAL RELEASE MEASURES                                            

6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures:                                                                 
Personal precautions: Evacuate personnel to safe areas. Avoid contact with skin,  
eyes and clothing. Ensure adequate ventilation. Avoid dust formation. Remove all  
sources of ignition. Keep people away from and upwind of spill/leak. Take         
precautionary measures against static discharges. All equipment used when handling
the product must be grounded.                                                     

6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                             
Emergency Procedures:                                                             

6.1.2.      For Emergency Responders
Protective Equipment:                                                             
Emergency Procedures:                                                             

6.2.  Environmental Precautions
Beware of vapors accumulating to form explosive concentrations. Vapors can        
accumulate in low areas. Prevent further leakage or spillage if safe to do so. Do 
not allow material to contaminate ground water system. Prevent product from       
entering drains.                                                                  

6.3.  Methods and Material for Containment and Cleaning Up
For Containment: Absorb with earth, sand or other non-combustible material and    
transfer to containers for later disposal. Prevent further leakage or spillage if 
safe to do so.                                                                    
Methods for Cleaning Up: Pick up and transfer to properly labeled containers. Soak
up with inert absorbent material. Clean contaminated surface thoroughly. After    
cleaning, flush away traces with water.                                           

6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                        

SECTION 7: HANDLING AND STORAGE                                                   

7.1.  Precautions for Safe Handling
Additional Hazards When Processed:                                                
Hygiene Measures: Handle in accordance with good industrial hygiene and safety    
Avoid contact with skin, eyes and clothing. Handle in accordance with good        
industrial hygiene and safety practice. Remove and wash contaminated clothing     
before re-use. Keep away from open flames, hot surfaces and sources of ignition.  
Take precautionary measures against static discharges.                            

7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures: Keep container tightly closed in a dry and well-ventilated    
place. Keep away from open flames, hot surfaces and sources of ignition. Keep in  
properly labeled containers. Keep out of the reach of children. Store locked up.  
Storage Conditions:                                                               

7.3.  Specific End Use(s)

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                  

8.1.  Control Parameters
Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965   
F.2d 962 (11th Cir., 1992).                                                       

8.2.  Exposure Controls
Appropriate Engineering      |Showers, Eyewash stations, Ventilation systems.     
Controls                     |                                                    
Personal Protective Equipment|                                                    
Materials for Protective     |                                                    
Clothing                     |                                                    
Hand Protection              |                                                    
Eye Protection               |Safety glasses with side-shields.                   
Skin and Body Protection     |Chemical resistant apron. Protective gloves.        
Respiratory Protection       |If exposure limits are exceeded or irritation is    
                             |experienced, NIOSH/MSHA approved respiratory        
                             |protection should be worn. Positive-pressure        
                             |supplied air respirators may be required for high   
                             |airborne contaminant concentrations. Respiratory    
                             |protection must be provided in accordance with      
                             |current local regulations.                          
Thermal Hazard Protection    |                                                    

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                       

9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |Liquid                                       
Appearance                          |Clear                                        
Odor                                |Solvent                                      
Odor Threshold                      |No information available                     
pH                                  |No information available                     
Relative Evaporation Rate           |No information available                     
(butylacetate=1)                    |                                             
Melting Point                       |No information available                     
Freezing Point                      |No information available                     
Boiling Point                       |No information available                     
Flash Point                         |12 °C / 54 °F (Based on lowest flashpoint of 
                                    |the products                                 
Auto-ignition Temperature           |No information available                     
Decomposition Temperature           |No information available                     
Flammability (solid, gas)           |No information available                     
Vapor Pressure                      |No information available                     
Relative Vapor Density at 20 °C     |No information available                     
Relative Density                    |                                             
Specific Gravity                    |0.809                                        
Solubility                          |Water solubility: Practically insoluble      
Partition coefficient:              |No information available                     
n-octanol/water                     |                                             
Viscosity                           |No information available                     
Lower Flammable Limit               |                                             
Upper Flammable Limit               |                                             

9.2.  Other Information
VOC Content(%): 97.5                                                              

SECTION 10: STABILITY AND REACTIVITY                                              

10.1      Reactivity
No data available.                                                                

10.2      Chemical Stability
Stable under recommended storage conditions.                                      

10.3      Possibility of Hazardous Reactions
None under normal processing.                                                     

10.4      Conditions to Avoid
Extremes of temperature and direct sunlight.                                      

10.5      Incompatible Materials
Strong acids, alkalis, or oxidizing agents.                                       

10.6      Hazardous Decomposition Products
None known based on information supplied.                                         

SECTION 11: TOXICOLOGICAL INFORMATION                                             

11.1. Information on Toxicological Effects
Acute Toxicity: Unknown Acute Toxicity 0% of the mixture consists of ingredient(s)
of unknown toxicity                                                               
The following values are calculated based on chapter 3.1 of the GHS document .    
ATEmix (oral) 102 mg/kg                                                           
ATEmix (dermal) 308 mg/kg                                                         
ATEmix (inhalation-dust/mist) 0.5 mg/l                                            
Skin Corrosion/Irritation:                                                        
Serious Eye Damage/Irritation:                                                    
Respiratory or Skin Sensitization: None known                                     
Germ Cell Mutagenicity: None known.                                               
Carcinogenicity: There are no known carcinogenic chemicals in this product.       
Reproductive Toxicity: This product does not contain any known or suspected       
reproductive hazards.                                                             
Specific Target Organ Toxicity (Single Exposure): May cause drowsiness and        
dizziness. May cause drowsiness and dizziness.                                    
Specific Target Organ Toxicity (Repeated Exposure): Causes damage to organs       
through prolonged or repeated exposure if swallowed. Causes damage to organs      
through prolonged or repeated exposure if inhaled.                                
Aspiration Hazard: May be fatal if swallowed and enters airways.                  
Symptoms/Injuries After Inhalation: Toxic by inhalation. Avoid breathing vapors or
Symptoms/Injuries After Skin Contact: Toxic in contact with skin. Avoid contact   
with skin and clothing.                                                           
Symptoms/Injuries After Eye Contact: Avoid contact with eyes.                     
Symptoms/Injuries After Ingestion: Toxic if swallowed.                            
Harmful if swallowed. May be fatal if swallowed and enters airways.               
Chronic Symptoms: Intentional misuse by deliberately concentrating and inhaling   
contents may be harmful or fatal. Chronic hydrocarbon abuse has been associated   
with irregular heart rhythms and potential cardiac arrest. Prolonged skin contact 
may defat the skin and produce dermatitis.                                        

SECTION 12: ECOLOGICAL INFORMATION                                                

12.1. Toxicity

12.2. Persistence and Degradability
No information available.                                                         

12.3. Bioaccumulative Potential
No information available.                                                         
METHANOL                               log Pow                                    
67-56-1                                     -0.77                                 

12.4. Mobility in Soil

12.5. Other Adverse Effects
No information available.                                                         

13.1. Waste treatment methods
Waste Disposal Recommendations: This material, as supplied, is a hazardous waste  
according to federal regulations (40 CFR                                          
Additional Information:                                                           
Contaminated packaging: Do not re-use empty containers.                           

SECTION 14: TRANSPORT INFORMATION                                                 

14.1 In Accordance with DOT
Proper Shipping Name |CONSUMER COMMODITY ORM-D or LIMITED QUANTITY                
Hazard Class         |                       |<PICTOGRAM PHRASE>                  
Identification Number|                       |                                    
Label Codes          |                       |                                    
ERG Number           |                                                            

14.2 In Accordance with IMDG
Proper Shipping Name |METHANOL SOLUTION                                           
Hazard Class         |3 (6.1)                                                     
Identification Number|UN1230                                                      
Label Codes          |                      |<PICTOGRAM PHRASE>                   
ntification Of The   |                      |                                     
Substance/m          |                      |                                     
EmS-No. (Fire)       |                      |                                     
EmS-No. (Spillage)   |                      |                                     

14.3 In Accordance with IATA
Proper Shipping Name |METHANOL SOLUTION                                           
Identification Number|UN1230                 |<PICTOGRAM PHRASE>                   
Hazard Class         |3 (6.1)                |                                     
Label Codes          |                       |                                     
ntification Of The   |                       |                                     
Substance/m          |                       |                                     
ERG Code (IATA)      |                                                            

SECTION 15: REGULATORY INFORMATION                                                

15.1      US Federal Regulations
SARA 313: Section 313 of Title III of the Superfund Amendments and Reauthorization
Act of 1986 (SARA). This product contains a chemical or chemicals which are       
subject to the reporting requirements of the Act and Title 40 of the Code of      
Federal Regulations, Part 372:                                                    
Chemical Name                                                                     
Weight %*                                                                         
SARA 313 - Threshold                                                              
Values %                                                                          
METHANOL - 67-56-1                                                                
Clean Water Act                                                                   
This product contains the following substances which are regulated pollutants     
pursuant to the Clean Water Act (40 CFR 122.21                                    
and 40 CFR 122.42)                                                                
This material, as supplied, contains one or more substances regulated as a        
hazardous substance under the Comprehensive                                       
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302):      
Chemical Name                                                                     
Hazardous Substances RQs                                                          
Extremely Hazardous Substances                                                    
5000 lb                                                                           
RQ 5000 lb final RQ                                                               
RQ 2270 kg final RQ                                                               
SARA Section 311/312 Hazard Classes |Acute Health Hazard                          
                                    |Chronic Health Hazard                        
                                    |Fire Hazard                                  
                                    |Sudden Release of Pressure Hazard            
                                    |Reactive Hazard                              
Toxic Substances Control Act (TSCA) |                                             

15.2      US State Regulations
California Proposition 65: This product contains the following Proposition 65     
Chemical Name                                                                     
California Prop. 65                                                               
METHANOL - 67-56-1                                                                
U.S. State Right-to-Know Regulations                                              
Chemical Name                                                                     
New Jersey                                                                        
PROPYLENE GLYCOL                                                                  
Canada: This product has been classified in accordance with the hazard criteria of
the Controlled Products Regulations (CPR) and                                     
the MSDS contains all the information required by the CPR.                        
WHMIS Hazard Class                                                                
B2 Flammable liquid                                                               
D1A Very toxic materials                                                          
D2B Toxic materials                                                               


Revision date   |20-May-2015                                                      
Other           |This document has been prepared in accordance with the SDS       
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR    
GHS Full Text Phrases:                                                            
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Grainger disclaimer.

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.