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SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: 4605-0 GALLON BUG & TAR RMVR CAS No: Synonyms: None 1.2. Intended Use of the Product Use of the substance/mixture: Bug and tar remover. 1.3. Name, Address, and Telephone of the Responsible Party Company Imperial Supplies LLC 789 Armed Forces P.O. Box 11008 Green Bay, WI 53407-1038 Phone: 1.4. Emergency Telephone Number Emergency | Chemtrec 1-800-424-9300 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Skin |Category 2 corrosion/irri| tation | Serious eye |Category 2A damage/eye | irritation | Skin |Category 1 Sensitization | Reproductive |Category 2 Toxicity | Specific |Category 3 target organ | toxicity | (single | exposure) | Specific |Category 2 target organ | toxicity | (repeated | exposure) | Aspiration |Category 1 toxicity | Flammable |Category 3 Liquids | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Exclamation Mark |Health Hazard |Flame | Signal Word (GHS-US) |DANGER Hazard Statements (GHS-US) |Causes skin irritation |Causes serious eye irritation |May cause an allergic skin reaction |Suspected of damaging fertility or the unborn child |May cause respiratory irritation. May cause |drowsiness or dizziness |May cause damage to organs (central nervous system, |eyes, kidney, liver, respiratory system, and skin) |through prolonged or repeated exposure. |May be fatal if swallowed and enters airways |Flammable liquid and vapor Precautionary Statements |Prevention (GHS-US) |Obtain special instructions before use |Do not handle until all safety precautions have been |read and understood |Wash face, hands and any exposed skin thoroughly |after handling |Wear protective gloves/protective clothing/eye |protection/face protection |Contaminated work clothing should not be allowed out |of the workplace |Do not breathe dust/fume/gas/mist/vapors/spray |Use only outdoors or in a well-ventilated area |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking |Keep container tightly closed |Ground/Bond container and receiving equipment |Use explosion-proof electrial/ventilating/lighting |/equipment. |Use only non-sparking tools |Take precautionary measures against static discharge | |Response |If exposed or concerned: Get medical |advice/attention |Specific treatment (see first aid on this label) |IF IN EYES: Rinse cautiously with water for several |minutes. Remove contact lenses, if present and easy |to do. Continue rinsing. |If eye irritation persists: Get medical |advice/attention |IF ON SKIN (or hair): Remove/Take off immediately |all contaminated clothing. Rinse skin with |water/shower |Wash contaminated clothing before reuse |If skin irritation or rash occurs: Get medical |advice/attention |IF INHALED: Remove person to fresh air and keep |comfortable for breathing. |Call a POISON CENTER or doctor/physician if you feel |unwell |IF SWALLOWED: Immediately call a POISON CENTER or |doctor/physician |Do NOT induce vomiting |In case of fire: Use CO2, dry chemical, or foam for |extinction |Storage |Store locked up |Store in a well-ventilated place. Keep container |tightly closed |Keep cool. |Disposal |Dispose of contents/container to an approved waste |disposal plant 2.3. Other Hazards Other Hazards Not Contributing to the Classification: Toxic to aquatic life with long lasting effects 0% of the mixture consists of ingredient(s) of unknown toxicity. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) PETROLEUM DISTILLATES |64741-65-7 |10-20 | D-LIMONENE |5989-27-5 |10-20 | KEROSENE |8008-20-6 |1-10 | TOLUENE |108-88-3 |1-10 | AMMONIA |1336-21-6 |0.1-1 | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Move to fresh air. If breathing is difficult, give oxygen. Artificial respiration and/or oxygen may be necessary. If breathing has stopped, contact emergency medical services immediately. First-aid Measures After Skin Contact: Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If symptoms persist, call a physician. First-aid Measures After Eye Contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. If symptoms persist, call a physician. First-aid Measures After Ingestion: Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician or Poison Control Center immediately. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Irritating to respiratory system. Symptoms/Injuries After Skin Contact: Causes severe skin burns. Symptoms/Injuries After Eye Contact: Causes eye damage. Symptoms/Injuries After Ingestion: May be fatal if swallowed and enters airways. Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Notes to physician: Treat symptomatically. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Water fog.Dry chemical. Carbon dioxide (CO2). Cool containers/tanks with water spray. Unsuitable Extinguishing Media: Keep away from sources of ignition - No smoking. Cool containers / tanks with water spray. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Extremely flammable. Keep product and empty container away from heat and sources of ignition. In the event of fire and/or explosion do not breathe fumes. In the event of fire, cool tanks with water spray. Risk of ignition. Explosion Hazard: Sensitivity to Mechanical Impact: none. Sensitivity to Static Discharge: none. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Avoid dust formation. Remove all sources of ignition. Keep people away from and upwind of spill/leak. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Prevent further leakage or spillage if safe to do so. Do not allow material to contaminate ground water system. Prevent product from entering drains. Do not flush into surface water or sanitary sewer system. Should not be released into the environment. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up: Pick up and transfer to properly labeled containers. Soak up with inert absorbent material. Clean contaminated surface thoroughly. After cleaning, flush away traces with water. Ground and bond containers when transferring material. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Avoid contact with skin, eyes and clothing. Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharges. Hygiene Measures: Remove and wash contaminated clothing before re-use. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Keep container tightly closed in a dry and well-ventilated place. Keep away from open flames, hot surfaces and sources of ignition. Keep in properly labeled containers. Keep out of the reach of children. Store locked up. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH KEROSENE 8008-20-6 TWA: 200 mg/m3 total hydrocarbon vapor application restricted to conditions in which there are negligible aerosol Exposures Skin - potential significant contribution to overall exposure by the cutaneous route - TWA: 100 mg/m3 TOLUENE 108-88-3 TWA: 20 ppm TWA: 200 ppm (vacated) TWA: 100 ppm (vacated) TWA: 375 mg/m3 (vacated) STEL: 150 ppm (vacated) STEL: 560 mg/m3 Ceiling: 300 ppm IDLH: 500 ppm TWA: 100 ppm TWA: 375 mg/m3 STEL: 150 ppm STEL: 560 mg/m3 Other Exposure Guidelines: Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). 8.2. Exposure Controls Appropriate Engineering |Showers, Eyewash stations, Ventilation systems. Controls | Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Safety glasses with side-shields. Skin and Body Protection |Chemical resistant apron. Protective gloves. Respiratory Protection |If exposure limits are exceeded or irritation is |experienced, NIOSH/MSHA approved respiratory |protection should be worn. Positive-pressure |supplied air respirators may be required for high |airborne contaminant concentrations Respiratory |protection must be provided in accordance with |current local regulations. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |No information available Appearance |No information available Odor |No information available Odor Threshold |No information available pH |10 Relative Evaporation Rate |No information available (butylacetate=1) | Melting Point |No information available Freezing Point |No information available Boiling Point |No information available Flash Point |No information available Auto-ignition Temperature |No information available Decomposition Temperature |No information available Flammability (solid, gas) |No information available Vapor Pressure |No information available Relative Vapor Density at 20 Â°C | Relative Density | Specific Gravity |No information available Solubility |Practically insoluble Partition coefficient: |No information available n-octanol/water | Viscosity |No information available Lower Flammable Limit |No information available Upper Flammable Limit |No information available 9.2. Other Information VOC Content(%): 28.5 SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No data available. 10.2 Chemical Stability Stable under recommended storage conditions. 10.3 Possibility of Hazardous Reactions None under normal processing. 10.4 Conditions to Avoid Extremes of temperature and direct sunlight. 10.5 Incompatible Materials Strong acids, alkalis, or oxidizing agents. 10.6 Hazardous Decomposition Products None known based on information supplied. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Irritating to skin. May cause an allergic skin reaction. Serious Eye Damage/Irritation: Irritating to eyes. Respiratory or Skin Sensitization: May cause sensitization by skin contact. Germ Cell Mutagenicity: None known. Carcinogenicity: The table below indicates whether each agency has evaluated a listed ingredient as a carcinogen. Reproductive Toxicity: Product is or contains a chemical which is a known or suspected reproductive hazard. Specific Target Organ Toxicity (Single Exposure): May cause respiratory irritation. May cause drowsiness and dizziness. Specific Target Organ Toxicity (Repeated Exposure): May cause damage to organs through prolonged or repeated exposure. Aspiration Hazard: May be fatal if swallowed and enters airways. Symptoms/Injuries After Inhalation: Vapors may irritate throat and respiratory system. May cause drownsiness and dizziness based on components. May cause irritation of respiratory tract. Avoid breathing vapors or mists. Symptoms/Injuries After Skin Contact: Irritating to skin. Repeated exposure may cause skin dryness or cracking. Prolonged skin contact may defat the skin and produce dermatitis. Avoid contact with skin. Symptoms/Injuries After Eye Contact: Irritating to eyes. Avoid contact with eyes. Symptoms/Injuries After Ingestion: May be harmful or fatal if swallowed. Aspiration into the lungs during swallowing may cause serious lung damage which may be fatal. Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Ecotoxicity: Chemical Name Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphnia and other aquatic invertebrates PETROLEUM DISTILLATES 64741-65-7 30000 mg/L EC50 Pseudokirchneriella subcapitata 72h - - 2 mg/L LC50 Mysidopsis bahia 48h D-LIMONENE 5989-27-5 - 0.619 - 0.796 mg/L LC50 Pimephales promelas 96h flow-through 35 mg/L LC50 Oncorhynchus mykiss 96h - - TOLUENE 108-88-3 433 mg/L EC50 Pseudokirchneriella subcapitata 96h 12.5 mg/L EC50 Pseudokirchneriella subcapitata 72h static 11.0 - 15.0 mg/L LC50 Lepomis macrochirus 96h static 14.1 - 17.16 mg/L LC50 Oncorhynchus mykiss 96h static 15.22 - 19.05 mg/L LC50 Pimephales promelas 96h flow through 5.89 - 7.81 mg/L LC50 Oncorhynchus mykiss 96h flow-through 50.87 - 70.34 mg/L LC50 Poecilia reticulata 96h static 12.6 mg/L LC50 Pimephales promelas 96h static 28.2 mg/L LC50 Poecilia reticulata 96h semi static 5.8 mg/L LC50 Oncorhynchus mykiss 96h semi- static54 mg/L LC50 Oryzias latipes 96h static - 5.46 - 9.83 mg/L EC50 Daphnia magna 48h Static 11.5 mg/L EC50 Daphnia magna 48h AMMONIA 1336-21-6 - 8.2 mg/L LC50 Pimephales promelas 96h - 0.66 mg/L EC50 Daphnia pulex 48h 0.66 mg/L EC50 water flea 48h 12.2. Persistence and Degradability No information available. 12.3. Bioaccumulative Potential No information available. Chemical Name log Pow TOLUENE 108-88-3 2.65 12.4. Mobility in Soil 12.5. Other Adverse Effects No information available. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: It must undergo special treatment, e.g. at suitable disposal site, to comply with local regulations. Additional Information: Contaminated packaging: Do not re-use empty containers. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |CONSUMER COMMODITY ORM-D or LIMITED QUANTITY Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |FLAMMABLE LIQUID, N.O.S. (TOLUENE, CITRUS TERPENES) Hazard Class |3 Identification Number|UN1993 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |FLAMMABLE LIQUID, N.O.S. (TOLUENE, CITRUS TERPENES) Identification Number|UN1993 |<PICTOGRAM PHRASE> Hazard Class |3 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA 313: Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Chemical Name CAS-No Weight %* SARA 313 - Threshold Values % TOLUENE - 108-88-3 108-88-3 1-10 1.0 AMMONIA - 1336-21-6 1336-21-6 0.1-1 1.0 SARA Section 311/312 Hazard Classes |Acute Health Hazard |Yes |Chronic Health Hazard |Yes |Fire Hazard |Yes |Sudden Release of Pressure Hazard no |Reactive Hazard |no Toxic Substances Control Act (TSCA) | |Chemical Name |TSCA | |PETROLEUM DISTILLATES |X | |D-LIMONENE |X | |KEROSENE |X | |TOLUENE |X | |AMMONIA |X | 15.2 US State Regulations California Proposition 65: This product contains the following Proposition 65 chemicals: Chemical Name California Prop. 65 TOLUENE - 108-88-3 Developmental Female Reproductive U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania KEROSENE 8008-20-6 X X X TOLUENE 108-88-3 X X X AMMONIA 1336-21-6 X X X EPA Pesticide Registration Number: Not applicable. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |21-May-2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.