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SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: 4602-0 GALLON CC PEN LUBE CAS No: Synonyms: None 1.2. Intended Use of the Product Use of the substance/mixture: Penetrating lubricant. 1.3. Name, Address, and Telephone of the Responsible Party Company Imperial Supplies LLC 789 Armed Forces Drive P.O. Box 11008 Green Bay, WI 53407-1038 Phone 1.4. Emergency Telephone Number Emergency | Chemtrec 1-800-424-9300 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Specific |Category 3 target organ | toxicity | (single | exposure) | Aspiration |Category 1 toxicity | Flammable |Category 3 Liquids | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Exclamation Mark |Health Hazard |Flame Signal Word (GHS-US) |DANGER Hazard Statements (GHS-US) |May cause respiratory irritation. May cause |drowsiness or dizziness |May be fatal if swallowed and enters airways |Flammable liquid and vapor Precautionary Statements |Prevention (GHS-US) |Avoid breathing dust/fume/gas/mist/vapors/spray |Use only outdoors or in a well-ventilated area |Wear protective gloves/protective clothing/eye |protection/face protection |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking |Keep container tightly closed |Ground/Bond container and receiving equipment |Use explosion-proof electrial/ventilating/lighting |/equipment. |Use only non-sparking tools |Take precautionary measures against static discharge | |Response |IF ON SKIN (or hair): Remove/Take off immediately |all contaminated clothing. Rinse skin with |water/shower |IF INHALED: Remove person to fresh air and keep |comfortable for breathing. |Call a POISON CENTER or doctor/physician if you feel |unwell |IF SWALLOWED: Immediately call a POISON CENTER or |doctor/physician |Do NOT induce vomiting |In case of fire: Use CO2, dry chemical, or foam for |extinction |Storage |Store locked up |Store in a well-ventilated place. Keep container |tightly closed |Keep cool. |Disposal |Dispose of contents/container to an approved waste |disposal plant 2.3. Other Hazards Other Hazards Not Contributing to the Classification: Toxic to aquatic life with long lasting effects 0% of the mixture consists of ingredient(s) of unknown toxicity 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |%* |Classification | | |(GHS-US) HYDROTREATED LIGHT DISTALLATES |64742-47-8 |20-30 | NAPHTHENIC OIL, SEVERLY HYDROT |64742-52-5 |10-20 | PETROLEUM DISTILLATES |64742-47-8 |10-20 | | | | *The exact percentage | | | (concentration) of composition | | | has been withheld as a trade | | | secret. | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Avoid contact with eyes,skin, and clothing.Avoid breathing, vapors,mist,or gas. First-aid Measures After Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing has stopped, contact emergency medical services immediately. First-aid Measures After Skin Contact: Wash off immediately with soap and plenty of water. Remove and wash contaminated clothing before re-use. Get medical attention immediately if symptoms occur. First-aid Measures After Eye Contact: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Seek immediate medical attention/advice. First-aid Measures After Ingestion: Do NOT induce vomiting. Call a physician immediately. Never give anything by mouth to an unconscious person. Risk of product entering the lungs on vomiting after ingestion. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: May cause respiratory irritation. Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Ingestion causing lung damage. Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Main Symptoms May cause respiratory irritation. ingestion causing lung damage. Notes to physician: Treat symptomatically. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Water fog.Dry chemical. Carbon dioxide (CO2). Cool containers/tanks with water spray. Unsuitable Extinguishing Media: Keep away from heat and sources of ignition. Do not smoke. Cool containers / tanks with water spray. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Flammable. Risk of ignition. In the event of fire and/or explosion do not breathe fumes. In the event of fire, cool tanks with water spray. Explosion Hazard: Sensitivity to Mechanical: Impact none. Sensitivity to Static Discharge: none. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Evacuate personnel to safe areas. Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Avoid dust formation. Remove all sources of ignition. Keep people away from and upwind of spill/leak. All equipment used when handling the product must be grounded. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. Prevent further leakage or spillage if safe to do so. Do not allow material to contaminate ground water system. Prevent product from entering drains. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up: Pick up and transfer to properly labeled containers. Soak up with inert absorbent material. Clean contaminated surface thoroughly. After cleaning, flush away traces with water. Take precautionary measures against static discharges. Ground and bond containers when transferring material. Prevent product from entering drains. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Avoid contact with skin, eyes and clothing. Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharges. Hygiene Measures: Handle in accordance with good industrial hygiene and safety practice. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Keep container tightly closed in a dry and well-ventilated place. Keep away from open flames, hot surfaces and sources of ignition. Keep in properly labeled containers. Keep out of the reach of children. Store locked up. Incompatible products: Strong acids, alkalis, or oxidizing agents. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH HYDROTREATED LIGHT DISTALLATES 64742-47-8 TWA: 200 PPM 8 hours - - Other Exposure Guidelines: Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). 8.2. Exposure Controls Appropriate Engineering |Showers, Eyewash stations, Ventilation systems. Controls | Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Safety glasses with side-shields. Skin and Body Protection |Chemical resistant apron. Protective gloves. Respiratory Protection |If exposure limits are exceeded or irritation is |experienced, NIOSH/MSHA approved respiratory |protection should be worn. Positive-pressure |supplied air respirators may be required for high |airborne contaminant concentrations. Respiratory |protection must be provided in accordance with |current local regulations. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid Appearance |Cloudy Odor |Solvent Odor Threshold |No information available pH |No information available Relative Evaporation Rate |No information available (butylacetate=1) | Melting Point |No information available Freezing Point |No information available Boiling Point |No information available Flash Point |38.9 Â°C / 102 Â°F Based on propellant Auto-ignition Temperature |No information available Decomposition Temperature |No information available Flammability (solid, gas) |No information available Vapor Pressure |No information available Relative Vapor Density at 20 Â°C | Relative Density | Specific Gravity |.866 Solubility |Practically insoluble Partition coefficient: |No information available n-octanol/water | Viscosity |No information available Lower Flammable Limit |No information available Upper Flammable Limit |No information available 9.2. Other Information VOC Content(%): 17.6 SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No data available. 10.2 Chemical Stability Stable under recommended storage conditions. 10.3 Possibility of Hazardous Reactions None under normal processing. 10.4 Conditions to Avoid Extremes of temperature and direct sunlight. 10.5 Incompatible Materials Strong acids, alkalis, or oxidizing agents. 10.6 Hazardous Decomposition Products None known based on information supplied. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Avoid contact with skin. May cause mild irritation. Serious Eye Damage/Irritation: Avoid contact with eyes. Respiratory or Skin Sensitization: None known. Irritation: Irritating to respiratory system. Germ Cell Mutagenicity: None known. Carcinogenicity: There are no known carcinogenic chemicals in this product. Reproductive Toxicity: This product does not contain any known or suspected reproductive hazards. Specific Target Organ Toxicity (Single Exposure): May cause respiratory irritation. May cause drowsiness and dizziness. Specific Target Organ Toxicity (Repeated Exposure): None under normal use conditions. Aspiration Hazard: May be fatal if swallowed and enters airways. Symptoms/Injuries After Inhalation: Avoid breathing vapors or mists. Vapors may irritate throat and respiratory system. May cause drownsiness and dizziness based on components. May cause irritation of respiratory tract. Inhalation of high vapor concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting. Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: May be fatal if swallowed. Toxic if swallowed.Aspiration into the lungs during swallowing may cause serious lung damage which may be fatal. Chronic Symptoms: Chronic hydrocarbon abuse has been associated with irregular heart rhythms and potential cardiac arrest. Prolonged skin contact may defat the skin and produce dermatitis. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Chemical Name Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphnia and other aquatic invertebrates HYDROTREATED LIGHT DISTALLATES 64742-47-8 - 2.2 mg/L LC50 Lepomis macrochirus 96h static 2.4 mg/L LC50 Oncorhynchus mykiss 96h static 45 mg/L LC50 Pimephales promelas 96h flow-through - - NAPHTHENIC OIL, SEVERLY HYDROT 64742-52-5 - 5000 mg/L LC50 Oncorhynchus mykiss 96h - 1000 mg/L EC50 Daphnia magna 48h PETROLEUM DISTILLATES 64742-47-8 - 2.2 mg/L LC50 Lepomis macrochirus 96h static 2.4 mg/L LC50 Oncorhynchus mykiss 96h static 45 mg/L LC50 Pimephales promelas 96h flow-through - - 12.2. Persistence and Degradability No information available. 12.3. Bioaccumulative Potential No information available. 12.4. Mobility in Soil 12.5. Other Adverse Effects No information available. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Additional Information: Do not re-use empty containers. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |NOT REGULATED FOR SHIPMENT Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |PETROLEUM DISTILLATES, N.O.S Hazard Class |3 Identification Number|UN1268 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |PETROLEUM DISTILLATES, N.O.S Identification Number|UN1268 |<PICTOGRAM PHRASE> Hazard Class |3 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA 313: Section 313 of Title III of the Superfund Amendments and Re-authorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. Clean Water Act: This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). CERCLA: This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Re-authorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material. SARA Section 311/312 Hazard Classes |Acute Health Hazard |Yes |Chronic Health Hazard |Yes |Fire Hazard |Yes |Sudden Release of Pressure Hazard no |Reactive Hazard |no Toxic Substances Control Act (TSCA) |HYDROTREATED X |LIGHT DISTALLATES | |NAPHTHENIC OIL, X |SEVERLY HYDROT | |PETROLEUM X |DISTILLATES 15.2 US State Regulations California Proposition 65: This product does not contain any known Proposition 65 chemicals. U.S. State Right-to-Know Regulations EPA Pesticide Registration Number: Not applicable. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |20-May-2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.