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MATERIAL SAFETY DATA SHEET SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 4700-0 GALLON PENETRATING OIL IDENTIFICATION NUMBER: 0147-107 DATE PRINTED: 08/06/09 PRODUCT USE/CLASS: PENETRATING OIL SUPPLIER/DISTRIBUTOR MANUFACTURED BY: IMPERIAL SUPPLIES LLC IMPERIAL SUPPLIES LLC 789 ARMED FORCES DRIVE 789 ARMED FORCES DRIVE GREEN BAY, WI 54304 GREEN BAY, WI 54304 INFORMATION#: 800-558-2808 INFORMATION#: 800-558-2808 EMERGENCY#: 800-255-3924 EMERGENCY#: 800-255-3924 CHEM-TEL CHEM-TEL PREPARER: CUSTOMER SERVICE, PHONE: PREPARE DATE: 08/06/09 SECTION 2 - COMPOSITION / INFORMATION ON INGREDIENTS ITEM CHEMICAL NAME CAS NUMBER WT/WT% LESS THAN 01 HYDROTREATED, SEVERE, LT. 64742-52-5 70-80 NAPHTHENIC DIST. 02 HYDROTREATED MIDDLE DISTILLATES 64742-67-7 10-20 03 CYCLOHEXANONE 108-94-1 1-10 04 DISTILLATES, PETROLEUM, 64742-52-5 1-10 HYDROTREATED NAP EXPOSURE LIMITS: ACGIH OSHA COMPANY ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN 01 5 MG/M3 10 MG/M3 MIS 5 MG/M3 N.E. N.E. NO MIST MIST 02 5 MG/M3 N.E. 5 MG/M3 N.E. N.E. NO MIST MIST 03 25 PPM N.E. 25 PPM 50 PPM SKIN N.E. YES SKIN SKIN 04 5 MG/M3 10 MG/M3 5 MG/M3 N.E. N.E. YES SKIN (See Section 16 for abbreviation legend) SECTION 3 - HAZARDS IDENTIFICATION *** EMERGENCY OVERVIEW *** Vapors irritating to eyes and respiratory tract. High vapor concentrations may cause drowsiness. EFFECTS OF OVEREXPOSURE - EYE CONTACT: Liquid, aerosols and vapors of this product are irritating and can cause pain, tearing, reddening and swelling accompanied by a stinging sensation and/or a feeling like that of fine dust in the eyes. EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash). EFFECTS OF OVEREXPOSURE - INHALATION: Headaches, dizziness, nausea, decreased blood pressure, changes in heart rate and cyanosis may result from over-exposure to vapor or skin exposure. Prolonged inhalation may be harmful. EFFECTS OF OVEREXPOSURE - INGESTION: This material may be harmful or fatal if swallowed. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Overexposure may cause nervous system damage. PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT INGESTION SKIN ABSORPTION EYE CONTACT INHALATION SECTION 4 - FIRST AID MEASURES FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water. Get medical attention, if irritation persists. FIRST AID - SKIN CONTACT: Immediately flush skin with plenty of water. Remove clothing. Get medical attention immediately. Wash clothing separately before reuse. FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. FIRST AID - INGESTION: Get medical attention immediately. If swallowed, do NOT induce vomiting. Give victim a glass of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. SECTION 5 - FIRE FIGHTING MEASURES FLASH POINT: LOWER EXPLOSIVE LIMIT: 0.7%. 111 F UPPER EXPLOSIVE LIMIT: 9.4% AUTO IGNITION TEMPERATURE: N.D. EXTINGUISHING MEDIA: ALCOHOL FOAM CO2 DRY CHEMICAL FOAM UNUSUAL FIRE AND EXPLOSION HAZARDS: "Empty" containers retain product residue (liquid and/or vapor) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE,SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Empty drums should be completely drained, properly bunged and promptly returned to a drum reconditioner, or properly disposed of. SPECIAL FIREFIGHTING PROCEDURES: Containers can build up pressure if exposed to heat (fire). As in any fire, wear self-contained breathing apparatus pressure-demand (MSHA/NIOSH approved or equivalent) and full protective gear. SECTION 6 - ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Absorb spill with inert material (e.g. dry sand or earth)then place in a chemical waste container. Avoid runoff into storm sewers and ditches with lead to waterways. SECTION 7 - HANDLING AND STORAGE AEROSOL LEVEL: N/A HANDLING: Wash thoroughly after handling. STORAGE: Keep from freezing. SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: Good general ventilation should be sufficient to control airborne levels. Local exhaust ventilation may be necessary to control any air contaminants to within their TLVs during the use of this product. RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. SKIN PROTECTION: No Information. EYE PROTECTION: Wear safety glasses with side shields (or goggles) and a face shield OTHER PROTECTIVE EQUIPMENT: STANDARD INDUSTRIAL CLOTHING STANDARDS SHOULD BE FOLLOWED. HYGIENIC PRACTICES: Wash hands before eating. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Follow all MSDS/label precautions even after container is emptied because they may retain product residues. Avoid prolonged or repeated contact with skin. Avoid breathing vapors from heated material. Avoid contact with eyes, skin, and clothing. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES BOILING RANGE: 309-563 F VAPOR DENSITY: Is heavier than air ODOR: PETROLUEM ODOR THRESHOLD: ND APPEARANCE: AMBER LIQUID EVAPORATION Is faster than RATE: Butyl Acetate SOLUBILITY IN NIL H20: FREEZE POINT: ND SPECIFIC 0.8561 GRAVITY: VAPOR PRESSURE: ND pH @ 0.0%: NA PHYSICAL STATE LIQUID VISCOSITY: ND COEFFICIENT OF WATER/OIL DISTRIBUTION: N.D. VOLATILE ORGANIC COMPOUNDS (VOCS): 0.95 lbs/gal, 114 grams/lts VOC, % (wt): 13.37% (See Section 16 for abbreviation legend) SECTION 10 - STABILITY AND REACTIVITY CONDITIONS TO AVOID: ALL SOURCES OF IGNITION, WELDING ARCS, AND OPEN FLAMES. INCOMPATIBILITY: STRONG ACIDS, ALKALIS, OXIDIZERS, AND AMINES. HAZARDOUS DECOMPOSITION PRODUCTS: OXIDES OF CARBON, OXIDES OF NITROGEN, AND MAY PRODUCE FORMS OF CHLORIDE, CHLORINE, AND PHOSGENE. HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. STABILITY: This product is stable under normal storage conditions. SECTION 11 - TOXICOLOGICAL PROPERTIES PRODUCT LD50: 5000 mg/kg PRODUCT LC50: 4600 ppm COMPONENT TOXICOLOGICAL INFORMATION: CHEMICAL NAME LD50 LC50 HYDROTREATED, SEVERE, LT. NE NE NAPHTHENIC DI HYDROTREATED MIDDLE DISTILLATES >5000 MG/KG/RAT 4600 MG/M3/4H/RAT CYCLOHEXANONE 162000 MG/KG/RAT >8000 GM/M3/4H/RAT DISTILLATES,PETROLEUM, ND ND HYDROTREATED SECTION 12 - ECOLOGICAL INFORMATION ECOLOGICAL INFORMATION: No Information. SECTION 13 - DISPOSAL CONSIDERATIONS DISPOSAL METHOD: DISPOSE IN ACCORDANCE WITH ALL FEDERAL, STATE, AND LOCAL REGULATIONS. SECTION 14 - TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME: CONSUMER COMMODITY DOT TECHNICAL NAME: DOT TECHNICAL NAME: ORM-D DOT HAZARD CLASS: ORM-D HAZARD SUBCLASS: DOT UN/NA NUMBER: PACKING GROUP: RESP. GUIDE PAGE: DOT EXEMPTIONS: DOT SPECIAL INSTRUCTIONS: IMDG SHIPPING INFORMATION UN1993 IMDG PROPER SHIPPING NAME: FLAMMABLE LIQUID, N.O.S. IMDG TECHNICAL NAME: CYCLOHEXANONE IMDG HAZARD CLASS: 3 HAZARD SUBCLASS: PACKING GROUP: III FLASH POINT, C:44 IMDG EXEMPTIONS: LIMITED QUANTITY IATA SPECIAL INSTRUCTIONS: SECTION 15 - REGULATORY INFORMATION U.S. FEDERAL REGULATIONS: AS FOLLOWS - OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200) CERCLA -SARA HAZARD CATEGORY: This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: IMMEDIATE HEALTH HAZARD CHRONIC HEALTH HAZARD FIRE HAZARD SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: CHEMICAL NAME CAS NUMBER WT/WT% IS LESS THAN No SARA Section 313 components exist in this product. TOXIC SUBSTANCES CONTROL ACT: This product contains the following chemical substances subject to the reporting requirements Of TSCA 12(B) if exported from the United States: CHEMICAL NAME CAS NUMBER No information is available U.S. STATE REGULATIONS: AS FOLLOWS - NEW JERSEY RIGHT-TO-KNOW: The following materials are non-hazardous, but are among the top five components in this product: CHEMICAL NAME CAS NUMBER No non-hazardous materials are among the top five ingredients. PENNSYLVANIA RIGHT TOKNOW: The following nonhazardous ingredients are present in the product at greater than 3%: CHEMICAL NAME CAS NUMBER No non-hazardous ingredients are present at greater than 3%. CALIFORNIA PROPOSITION 65: WARNING: The chemicals (s) noted below and contained in this product, are known To the state of California to cause cancer, birth defects or other reproductive harm: CHEMICAL NAME CAS NUMBER No Proposition 65 chemicals exist in this product. INTERNATIONAL REGULATIONS: AS FOLLOWS - CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings. CANADIAN WHMIS CLASS: No information available SECTION 16 - OTHER INFORMATION HMIS RATINGS - HEALTH:2 FLAMMABILITY: 1 REACTIVITY: 0 PREVIOUS MSDS REVISION DATE: 07/29/09 REASON FOR REVISION: UPDATE LEGEND: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined *** THIS MSDS IS NOT FOR REPRODUCTION OR REPRODUCTION OR DISTRIBUTION *** The information contained on this MSDS has been checked and should be accurate. However, it is the responsibility of the user to comply with all Federal, State, and Local laws and regulations. <END OF MSDS>
The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'MSDS' shall be created or inferred by any statement in this 'MSDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'MSDS'. The user is responsible for full compliance.