SDS Sheet 0043240All SDS Go Back Print
SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: GOJOÂ® NATURAL* ORANGE Pumice Hand Cleaner CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Skin-care. 1.3. Name, Address, and Telephone of the Responsible Party Company: GOJO Industries, Inc. One GOJO Plaza, Suite 500 Akron OH 44311 Phone: 1 (330) 255-6000 1.4. Emergency Telephone Number Emergency |1-800-424-9300 CHEMTREC number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Eye irritation|Category 2A | | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Exclamation Mark Signal Word (GHS-US) |Warning Hazard Statements (GHS-US) |H319 Causes serious eye irritation. Precautionary Statements |Prevention: (GHS-US) |P264 Wash skin thoroughly after handling. |P280 Wear eye protection/ face protection. |Response: |P305 + P351 + P338 IF IN EYES: Rinse cautiously with |water for several minutes. Remove contact lenses, if |present and easy to do. Continue rinsing. |P337 + P313 If eye irritation persists: Get medical |advice/ attention. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None known. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) 1-Methyl 4-(1-Methylethenyl) |5989-27-5 |>= 5 - <| Cyclohexene | |10 | Alcohols, C12-15, ethoxylated |68551-13-3 |>= 1 - <| propoxylated | |5 | | | | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: In the case of accident or if you feel unwell, seek medical advice immediately. When symptoms persist or in all cases of doubt seek medical advice. First-aid Measures After Inhalation: If inhaled, remove to fresh air. Get medical attention if symptoms occur. First-aid Measures After Skin Contact: Wash with water and soap as a precaution. Get medical attention if symptoms occur. First-aid Measures After Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lens, if worn. Get medical attention. First-aid Measures After Ingestion: If swallowed, DO NOT induce vomiting. Get medical attention if symptoms occur. Rinse mouth thoroughly with water. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Causes serious eye irritation. Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Protection of first-aiders: First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists. Notes to physician: Treat symptomatically and supportively. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Water spray Alcohol-resistant foam Dry chemical Carbon dioxide (CO2) Unsuitable Extinguishing Media: None known. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Exposure to combustion products may be a hazard to health. Explosion Hazard: Hazardous combustion products: Carbon oxides Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area. Protection During Firefighting: In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Use personal protective equipment. Emergency Procedures: Follow safe handling advice and personal protective equipment recommendations. 6.2. Environmental Precautions Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Soak up with inert absorbent material. For large spills, provide diking or other appropriate containment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container. Methods for Cleaning Up: Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Avoid inhalation of vapor or mist. Do not swallow. Do not get in eyes. Avoid prolonged or repeated contact with skin. Handle in accordance with good industrial hygiene and safety practice. Take care to prevent spills, waste and minimize release to the environment. Hygiene Measures: Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section. Storage Conditions: Keep in properly labeled containers. Store in accordance with the particular national regulations. Materials to avoid: Do not store with the following product types: Strong oxidizing agents. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Ingredients with workplace control parameters Contains no substances with occupational exposure limit values. Hazardous components without workplace control parameters Ingredients CAS-No. 1-Methyl 4-(1-Methylethenyl) Cyclohexene 5989-27-5 Alcohols, C12-15, ethoxylated propoxylated 68551-13-3 8.2. Exposure Controls Appropriate Engineering |Ensure adequate ventilation, especially in confined Controls |areas. Minimize workplace exposure concentrations. |Dust formation may be relevant in the processing of |this product. In addition to substance-specific |OELs, general limitations of concentrations of |particulates in the air at workplaces have to be |considered in workplace risk assessment. Relevant |limits include: OSHA PEL for Particulates Not |Otherwise Regulated of 15 mg/m3 - total dust, 5 |mg/m3 - respirable fraction; and ACGIH TWA for |Particles (insoluble or poorly soluble) Not |Otherwise Specified of 3 mg/m3 - respirable |particles, 10 mg/m3 - inhalable particles. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Material: Impervious gloves. |Remarks: Choose gloves to protect hands against |chemicals depending on the concentration specific to |place of work. Breakthrough time is not determined |for the product. Change gloves often! For special |applications, we recommend clarifying the resistance |to chemicals of the aforementioned protective gloves |with the glove manufacturer. Wash hands before |breaks and at the end of workday. Eye Protection |Wear the following personal protective equipment: |Safety goggles. Skin and Body Protection |Select appropriate protective clothing based on |chemical resistance data and an assessment of the |local exposure potential. Skin contact must be |avoided by using impervious protective clothing |(gloves, aprons, boots, etc). Respiratory Protection |General and local exhaust ventilation is recommended |to maintain vapor exposures below recommended |limits. Where concentrations are above recommended |limits or are unknown, appropriate respiratory |protection should be worn. Follow OSHA respirator |regulations (29 CFR 1910.134) and use NIOSH/MSHA |approved respirators. Protection provided by air |purifying respirators against exposure to any |hazardous chemical is limited. Use a positive |pressure air supplied respirator if there is any |potential for uncontrolled release, exposure levels |are unknown, or any other circumstance where air |purifying respirators may not provide adequate |protection. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State | Appearance |Liquid Odor |Citrus Odor Threshold |No data available pH |5.0 - 8.0 Relative Evaporation Rate |No data available (butylacetate=1) | Melting Point |No data available Freezing Point |No data available Boiling Point |95 Â°C Flash Point |> 100 Â°C Auto-ignition Temperature |No data available Decomposition Temperature |The substance or mixture is not classified |self-reactive. Flammability (solid, gas) |Not applicable Vapor Pressure |No data available Relative Vapor Density at 20 Â°C |No data available Relative Density | Specific Gravity | Solubility |Soluble Partition coefficient: |Not applicable n-octanol/water | Viscosity |Viscosity, kinematic: 10,000 - 50,000 mm2/s |(20 Â°C) Lower Flammable Limit |No data available Upper Flammable Limit |No data available 9.2. Other Information |SECTION 10: STABILITY AND REACTIVITY | 10.1 Reactivity Not classified as a reactivity hazard. 10.2 Chemical Stability Stable under normal conditions. 10.3 Possibility of Hazardous Reactions Can react with strong oxidizing agents. 10.4 Conditions to Avoid None known. 10.5 Incompatible Materials Oxidizing agents 10.6 Hazardous Decomposition Products No hazardous decomposition products are known. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Not classified based on available information. Skin Corrosion/Irritation: Not classified based on available information. Serious Eye Damage/Irritation: Causes serious eye irritation. Respiratory or Skin Sensitization: Skin sensitization: Not classified based on available information. Respiratory sensitization: Not classified based on available information. Germ Cell Mutagenicity: Not classified based on available information. Carcinogenicity: Not classified based on available information. Reproductive Toxicity: Not classified based on available information. Specific Target Organ Toxicity (Single Exposure): Not classified based on available information. Specific Target Organ Toxicity (Repeated Exposure): Not classified based on available information. Aspiration Hazard: Not classified based on available information. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity 1-Methyl 4-(1-Methylethenyl) Cyclohexene: Toxicity to fish: LC50 (Pimephales promelas (fathead minnow)): 0.72 mg/l Exposure time: 96 h Toxicity to daphnia and other: EC50 (Daphnia magna (Water flea)): 0.36 mg/l aquatic invertebrates Exposure time: 48 h Toxicity to algae: ErC50 (Desmodesmus subspicatus (green algae)): 150 mg/l Exposure time: 72 h Test substance: Water Accommodated Fraction Remarks: Based on data from similar materials M-Factor (Acute aquatic tox-: 1 icity) Alcohols, C12-15, ethoxylated propoxylated: Toxicity to fish: LC50 (Scophthalmus maximus (turbot)): 3.1 mg/l Exposure time: 96 h Remarks: Based on data from similar materials Toxicity to daphnia and other: EC50 (Daphnia magna (Water flea)): 0.14 mg/l aquatic invertebrates Exposure time: 48 h Remarks: Based on data from similar materials Toxicity to algae: EC50 (Pseudokirchneriella subcapitata (green algae)): 0.75 mg/l Exposure time: 72 h Remarks: Based on data from similar materials M-Factor (Acute aquatic tox-: 1 icity) Toxicity to bacteria: EC50 (Pseudomonas putida): > 10,000 mg/l Exposure time: 16.9 h Remarks: Based on data from similar materials 12.2. Persistence and Degradability 1-Methyl 4-(1-Methylethenyl) Cyclohexene: Biodegradability: Result: Readily biodegradable. Biodegradation: 80 % Exposure time: 28 d Remarks: Based on data from similar materials Alcohols, C12-15, ethoxylated propoxylated: Biodegradability: Result: Readily biodegradable. Biodegradation: 80 - 88 % Exposure time: 28 d Remarks: Based on data from similar materials 12.3. Bioaccumulative Potential 1-Methyl 4-(1-Methylethenyl) Cyclohexene: Partition coefficient: n-: log Pow: 4.38 octanol/water 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects No data available. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Waste from residues: Dispose of in accordance with local regulations. Contaminated packaging: Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name | Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. |(1-Methyl 4-(1-Methylethenyl) Cyclohexene) Hazard Class |9 Identification Number|UN 3082 Label Codes |9 |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) |F-A | EmS-No. (Spillage) |S-F | 14.3 In Accordance with IATA Proper Shipping Name |Environmentally hazardous substance, liquid, n.o.s. |(1-Methyl 4-(1-Methylethenyl) Cyclohexene) Identification Number|UN 3082 |<PICTOGRAM PHRASE> Hazard Class |9 | Label Codes |Miscellaneous | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA Section 311/312 Hazard Classes |Acute Health Hazard Toxic Substances Control Act (TSCA) |All chemical substances in this product are |either listed on the TSCA Inventory or are in |compliance with a TSCA Inventory exemption. 15.2 US State Regulations <COMPONENT> Pennsylvania Right To Know Water 7732-18-5 70 - 90 % Pumice 1332-09-8 5 - 10 % 1-Methyl 4-(1-Methylethenyl) Cyclohexene 5989-27-5 5 - 10 % New Jersey Right To Know Water 7732-18-5 70 - 90 % Pumice 1332-09-8 5 - 10 % 1-Methyl 4-(1-Methylethenyl) Cyclohexene 5989-27-5 5 - 10 % Alcohols, C12-15, ethoxylated propoxylated 68551-13-3 1 - 5 % California Prop 65: This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |03/02/2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.