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SDS Sheet 0042130

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SECTION 1: IDENTIFICATION                                                       
 


1.1.  Product Identifier
Product Form:                                                                   
 
Product Name: Simple Green® Hand Cleaner Gel                                    
 
CAS No:                                                                         
 
Synonyms:                                                                       
 


1.2.  Intended Use of the Product
Use of the substance/mixture:                                                   
 


1.3.  Name, Address, and Telephone of the Responsible Party
Company:                                                                        
 
Sunshine Makers, Inc.                                                           
 
15922 Pacific Coast Highway                                                     
 
Huntington Beach, CA 92649 USA                                                  
 
Telephone: 800-228-0709 ? 562-795-6000                                          
 


1.4.  Emergency Telephone Number
Emergency     | Chem-Tel 24-Hour Emergency Service: 800-255-3924                
 
number        |                                                                 
 

SECTION 2: HAZARDS IDENTIFICATION                                               
 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Ex. Compressed|H280          
gas           |              
              |              
              |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |None
        
Signal Word (GHS-US)         |Warning                                           
 
Hazard Statements (GHS-US)   |H320 - Causes eye irritation.                     
 
Precautionary Statements     |P264 - Wash hands thoroughly after handling.      
 
(GHS-US)                     |P305 + P351 + P338 - IF IN EYS: Rinse cautiously  
 
                             |with water for several minutes. Remove contact    
 
                             |lenses, if present and easy to do. Continue
rinsing.
                             |                                                  
 
                             |P337 + P313 - If eye irritation persists: Get     
 
                             |medical advice/attention.                         
 


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification: None Known                
 


2.4.  Unknown Acute Toxicity (GHS-US)
                                                                                
 

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                               
 


3.1.  Substance
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
Water                           |7732-18-5            |> 87.5% |                
 
Pumice                          |1332-09-8            |< 2%    |                
 
Acrylates/C10-30 Alkyl Acrylate |proprietary          |< 1%    |                
 
Crosspolymer                    |                     |        |                
 
Diisopropanolamine              |110-97-4             |< 1%    |                
 
Sodium Citrate                  |68-04-2              |< 1%    |                
 
Ethoxylated alcohol             |68439-46-3           |< 1%    |                
 
Acetylated Lanolin Alcohol      |61788-49-6           |< 1%    |                
 
Sodium Carbonate                |497-19-8             |< 1%    |                
 
Citric Acid                     |77-92-9              |< 1%    |                
 
Tetrasodium                     |51981-21-6           |< 1%    |                
 
N,N-bis(carboxymethyl)-L-glutama|                     |        |                
 
te                              |                     |        |                
 
Fragrance                       |Proprietary          |< 1%    |                
 
Colorant                        |Proprietary          |< 1%    |                
 
Benzyl Alcohol                  |100-51-6             |< 0.5%  |                
 
Dehydroacetic acid              |520-45-6             |< 0.5%  |                
 


SECTION 4: FIRST AID MEASURES                                                   
 


4.1.  Description of First Aid Measures
First-aid Measures General:                                                     
 
First-aid Measures After Inhalation: Not expected to cause respiratory
irritation.
If adverse effect occurs, move to fresh air.                                    
 
First-aid Measures After Skin Contact: Not expected to cause skin irritation. If
 
adverse effect occurs, rinse skin with water.                                   
 
First-aid Measures After Eye Contact: Causes eye irritation. IF IN EYS: Rinse   
 
cautiously with water for several minutes. Remove contact lenses, if present and
 
easy to do. Continue rinsing. If eye irritation persists: Get medical           
 
advice/attention.                                                               
 
First-aid Measures After Ingestion: May cause upset stomach. Drink plenty of
water
to dilute. See section 11.                                                      
 


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries:                                                              
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact:                                           
 
Symptoms/Injuries After Eye Contact:                                            
 
Symptoms/Injuries After Ingestion:                                              
 
Chronic Symptoms:                                                               
 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
Treat symptomatically                                                           
 

SECTION 5: FIRE-FIGHTING MEASURES                                               
 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Use Dry chemical, CO2, water spray or "alcohol"   
 
foam. Avoid high volume jet water.                                              
 
Unsuitable Extinguishing Media: Use Dry chemical, CO2, water spray or "alcohol" 
 
foam. Avoid high volume jet water.                                              
 


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard:                                                                    
 
Explosion Hazard:                                                               
 
Reactivity:                                                                     
 


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                    
 
Firefighting Instructions: In event of fire, fire created carbon oxides may be  
 
formed.                                                                         
 
Protection During Firefighting: Wear positive pressure self-contained breathing 
 
apparatus; Wear full protective clothing.                                       
 

SECTION 6: ACCIDENTAL RELEASE MEASURES                                          
 


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: For non-emergency and emergency personnel: See section 8 -    
 
personal protection. Avoid eye contact. Wear safety goggles.                    
 


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.1.2.      For Emergency Responders
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.2.  Environmental Precautions
Do not allow into open waterways and ground water systems.                      
 


6.3.  Methods and Material for Containment and Cleaning Up
For Containment:                                                                
 
Methods for Cleaning Up: Dike or soak up with inert absorbent material. See     
 
section 13 for disposal considerations.                                         
 


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                      
 


SECTION 7: HANDLING AND STORAGE                                                 
 


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Ensure adequate ventilation. Keep out of
reach 
of children. Keep away from heat, sparks, open flame and direct sunlight. Do not
 
pierce any part of the container. Do not mix or contaminate with any other      
 
chemical. Do not eat, drink or smoke while using this product.                  
 
Hygiene Measures: Wash thoroughly after handling and before eating or drinking. 
 


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                             
 
Storage Conditions: Conditions for Safe Storage including Incompatibilities:
Keep 
container tightly closed. Keep in cool dry area. Avoid prolonged exposure to    
 
sunlight. Do not store at temperatures above 109oF (42.7oC). If separation
occurs,
mix the product for reconstitution.                                             
 


7.3.  Specific End Use(s)
                                                                                
 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                
 


8.1.  Control Parameters
No components listed with TWA or STEL values under OSHA or ACGIH.               
 


8.2.  Exposure Controls
Appropriate Engineering      |                                                  
 
Controls                     |                                                  
 
Personal Protective Equipment|                                                  
 
Materials for Protective     |                                                  
 
Clothing                     |                                                  
 
Hand Protection              |                                                  
 
Eye Protection               |Use protective glasses or safety goggles if       
 
                             |splashing or spray-back is likely.                
 
Skin and Body Protection     |Use protective gloves (any material) when used for
 
                             |prolonged periods or dermally sensitive.          
 
Respiratory Protection       |Use in well ventilated areas or local exhaust     
 
                             |ventilations when cleaning small spaces.          
 
Thermal Hazard Protection    |                                                  
 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                     
 


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |                                           
 
Appearance                          |Viscous Green Gel                          
 
Odor                                |Sassafras (sweet herbal)                   
 
Odor Threshold                      |Not determined                             
 
pH                                  |9.8 - 10.8                                 
 
Relative Evaporation Rate           |Not determined                             
 
(butylacetate=1)                    |                                           
 
Melting Point                       |                                           
 
Freezing Point                      |0degC (32degF)                             
 
Boiling Point                       |101degC (213.8degF)                        
 
Flash Point                         |> 212degF                                  
 
Auto-ignition Temperature           |109degF                                    
 
Decomposition Temperature           |Non-flammable                              
 
Flammability (solid, gas)           |Not determined                             
 
Vapor Pressure                      |Not determined                             
 
Relative Vapor Density at 20 °C     |Not determined                             
 
Relative Density                    |7.923 - 8.757 lb/gal                       
 
Specific Gravity                    |0.95 - 1.05                                
 
Solubility                          |100% in water                              
 
Partition coefficient:              |Not determined                             
 
n-octanol/water                     |                                           
 
Viscosity                           |7500 - 12000 cps                           
 
Lower Flammable Limit               |Not applicable                             
 
Upper Flammable Limit               |Not applicable                             
 


9.2.  Other Information
VOCs: **Water & fragrance exemption in calculation                              
 
SCAQMD 304-91 / EPA 24:            Not tested                                   
 
CARB Method 310**:                     0.8 g/L 0.033 lb/gal 0.08%               
 
SCAQMD Method 313:                   Not tested                                 
 
VOC Composite Partial Pressure: Not determined                                  
 

SECTION 10: STABILITY AND REACTIVITY                                            
 


10.1      Reactivity
Non-reactive.                                                                   
 


10.2      Chemical Stability
Stable under normal conditions 70oF (21oC) and 14.7 psig (760 mmHg).            
 


10.3      Possibility of Hazardous Reactions
None known.                                                                     
 


10.4      Conditions to Avoid
Excessive heat or cold.                                                         
 


10.5      Incompatible Materials
Do not mix with oxidizers, acids, bathroom cleaners, or disinfecting agents.    
 


10.6      Hazardous Decomposition Products
Normal products of combustion - CO, CO2.                                        
 

SECTION 11: TOXICOLOGICAL INFORMATION                                           
 


11.1. Information on Toxicological Effects
Acute Toxicity:                                                                 
 
Skin Corrosion/Irritation: Non-irritant per Dermal Irritection® assay modeling.
No
animal testing performed.                                                       
 
Serious Eye Damage/Irritation: Irritant per Ocular Irritection® assay modeling.
No
animal testing performed.                                                       
 
Respiratory or Skin Sensitization:                                              
 
Germ Cell Mutagenicity: Mixture does not classify under this category.          
 
Carcinogenicity: No ingredients trigger or classify under this category under
NTP,
IARC or OSHA.                                                                   
 
Reproductive Toxicity: Mixture does not classify under this category.           
 
Specific Target Organ Toxicity (Single Exposure): Mixture does not classify
under 
this category.                                                                  
 
Specific Target Organ Toxicity (Repeated Exposure): Mixture does not classify   
 
under this category.                                                            
 
Aspiration Hazard: Mixture does not classify under this category.               
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact:                                           
 
Symptoms/Injuries After Eye Contact:                                            
 
Symptoms/Injuries After Ingestion:                                              
 
Chronic Symptoms:                                                               
 

SECTION 12: ECOLOGICAL INFORMATION                                              
 


12.1. Toxicity
Volume of ingredients used does not trigger toxicity classifications under the  
 
Globally Harmonized System of Classification and Labelling of Chemicals.        
 


12.2. Persistence and Degradability
No data available.                                                              
 


12.3. Bioaccumulative Potential
No data available.                                                              
 


12.4. Mobility in Soil
No data available.                                                              
 


12.5. Other Adverse Effects
No data available.                                                              
 

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: Unused or Used Liquid: May be considered
hazardous
in your area depending on usage and tonnage of disposal - check with local,     
 
regional, and or national regulations for appropriate methods of disposal.      
 
Additional Information: Empty Containers: Dispose of in accordance with local   
 
regulations. Never dispose of used degreasing rinsates into lakes, streams, and 
 
open bodies of water or storm drains.                                           
 

SECTION 14: TRANSPORT INFORMATION                                               
 


14.1 In Accordance with DOT
Proper Shipping Name |Not Regulated for shipping.                               
 
Hazard Class         |                       |<PICTOGRAM PHRASE>                
 
Identification Number|                       |                                  
 
Label Codes          |                       |                                  
 
ERG Number           |                                                          
 


14.2 In Accordance with IMDG
Proper Shipping Name |Not classified as Hazardous                               
 
Hazard Class         |                                                          
 
Identification Number|                                                          
 
Label Codes          |                      |<PICTOGRAM PHRASE>                 
 
ntification Of The   |                      |                                   
 
Substance/m          |                      |                                   
 
EmS-No. (Fire)       |                      |                                   
 
EmS-No. (Spillage)   |                      |                                   
 


14.3 In Accordance with IATA
Proper Shipping Name |Not classified as Hazardous                               
 
Identification Number|                       |<PICTOGRAM PHRASE>                
  
Hazard Class         |                       |                                  
  
Label Codes          |                       |                                  
  
ntification Of The   |                       |                                  
  
Substance/m          |                       |                                  
  
ERG Code (IATA)      |                                                          
 

SECTION 15: REGULATORY INFORMATION                                              
 

15.1      US Federal Regulations
<COMPONENT>                                                                     
 
SARA Section 311/312 Hazard Classes |Not applicable.                            
 
Toxic Substances Control Act (TSCA) |TSCA and DSL Inventory.                    
 

15.2      US State Regulations
Clean Air Act (CAA):                                                            
 
Benzyl Alcohol 100-51-6           Group III                                     
 
Clean Water Act (CWA): Not applicable                                           
 
State Right To Know Lists:                                                      
 
Diisopropanolamine 110-97-4                      Massachusetts, Pennsylvania    
 
Benzyl Alcohol 100-51-6                                 Massachusetts,          
 
Pennsylvania                                                                    
 
California Proposition 65: No ingredients listed                                
 
                                                                                
 
Texas ESL:                                                                      
 
Ethoxylated Alcohol                                                             
 
68439-46-3                                                                      
 
60 ?g/m3 long term                                                              
 
600 ?g/m3 short term                                                            
 
                                                                                
 
Sodium Citrate                                                                  
 
68-04-2                                                                         
 
5 ?g/m3 long term                                                               
 
50 ?g/m3 short term                                                             
 
                                                                                
 
Sodium Carbonate                                                                
 
497-19-8                                                                        
 
5 ?g/m3 long term                                                               
 
50 ?g/m3 short term                                                             
 
                                                                                
 
Citric Acid                                                                     
 
77-92-9                                                                         
 
10 ?g/m3 long term                                                              
 
100 ?g/m3 short term                                                            
 
                                                                                
 
Pumice                                                                          
 
1322-09-8                                                                       
 
5 ?g/m3 long term                                                               
 
50 ?g/m3 short term                                                             
 
                                                                                
 
Diisopropanolamine                                                              
 
110-97-4                                                                        
 
46 ?g/m3 long term                                                              
 
160 ?g/m3 short term                                                            
 
                                                                                
 
Benzyl Alcohol                                                                  
 
100-51-6                                                                        
 
44 ?g/m3 long term                                                              
 
440 ?g/m3 short term                                                            
 
                                                                                
 
                                                                                
 

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION   
 

Revision date   |September 26, 2014                                             
 
Other           |This document has been prepared in accordance with the SDS     
 
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR  
 
                |1910.1200.                                                     
 
GHS Full Text Phrases:                                                          
 
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Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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