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SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: Simple Green� Hand Cleaner Gel CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: 1.3. Name, Address, and Telephone of the Responsible Party Company: Sunshine Makers, Inc. 15922 Pacific Coast Highway Huntington Beach, CA 92649 USA Telephone: 800-228-0709 ? 562-795-6000 1.4. Emergency Telephone Number Emergency | Chem-Tel 24-Hour Emergency Service: 800-255-3924 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Ex. Compressed|H280 gas | | | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |None Signal Word (GHS-US) |Warning Hazard Statements (GHS-US) |H320 - Causes eye irritation. Precautionary Statements |P264 - Wash hands thoroughly after handling. (GHS-US) |P305 + P351 + P338 - IF IN EYS: Rinse cautiously |with water for several minutes. Remove contact |lenses, if present and easy to do. Continue rinsing. | |P337 + P313 - If eye irritation persists: Get |medical advice/attention. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None Known 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Water |7732-18-5 |> 87.5% | Pumice |1332-09-8 |< 2% | Acrylates/C10-30 Alkyl Acrylate |proprietary |< 1% | Crosspolymer | | | Diisopropanolamine |110-97-4 |< 1% | Sodium Citrate |68-04-2 |< 1% | Ethoxylated alcohol |68439-46-3 |< 1% | Acetylated Lanolin Alcohol |61788-49-6 |< 1% | Sodium Carbonate |497-19-8 |< 1% | Citric Acid |77-92-9 |< 1% | Tetrasodium |51981-21-6 |< 1% | N,N-bis(carboxymethyl)-L-glutama| | | te | | | Fragrance |Proprietary |< 1% | Colorant |Proprietary |< 1% | Benzyl Alcohol |100-51-6 |< 0.5% | Dehydroacetic acid |520-45-6 |< 0.5% | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Not expected to cause respiratory irritation. If adverse effect occurs, move to fresh air. First-aid Measures After Skin Contact: Not expected to cause skin irritation. If adverse effect occurs, rinse skin with water. First-aid Measures After Eye Contact: Causes eye irritation. IF IN EYS: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid Measures After Ingestion: May cause upset stomach. Drink plenty of water to dilute. See section 11. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Treat symptomatically SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use Dry chemical, CO2, water spray or "alcohol" foam. Avoid high volume jet water. Unsuitable Extinguishing Media: Use Dry chemical, CO2, water spray or "alcohol" foam. Avoid high volume jet water. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: In event of fire, fire created carbon oxides may be formed. Protection During Firefighting: Wear positive pressure self-contained breathing apparatus; Wear full protective clothing. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: For non-emergency and emergency personnel: See section 8 - personal protection. Avoid eye contact. Wear safety goggles. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Do not allow into open waterways and ground water systems. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Dike or soak up with inert absorbent material. See section 13 for disposal considerations. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Ensure adequate ventilation. Keep out of reach of children. Keep away from heat, sparks, open flame and direct sunlight. Do not pierce any part of the container. Do not mix or contaminate with any other chemical. Do not eat, drink or smoke while using this product. Hygiene Measures: Wash thoroughly after handling and before eating or drinking. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Conditions for Safe Storage including Incompatibilities: Keep container tightly closed. Keep in cool dry area. Avoid prolonged exposure to sunlight. Do not store at temperatures above 109oF (42.7oC). If separation occurs, mix the product for reconstitution. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters No components listed with TWA or STEL values under OSHA or ACGIH. 8.2. Exposure Controls Appropriate Engineering | Controls | Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Use protective glasses or safety goggles if |splashing or spray-back is likely. Skin and Body Protection |Use protective gloves (any material) when used for |prolonged periods or dermally sensitive. Respiratory Protection |Use in well ventilated areas or local exhaust |ventilations when cleaning small spaces. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State | Appearance |Viscous Green Gel Odor |Sassafras (sweet herbal) Odor Threshold |Not determined pH |9.8 - 10.8 Relative Evaporation Rate |Not determined (butylacetate=1) | Melting Point | Freezing Point |0degC (32degF) Boiling Point |101degC (213.8degF) Flash Point |> 212degF Auto-ignition Temperature |109degF Decomposition Temperature |Non-flammable Flammability (solid, gas) |Not determined Vapor Pressure |Not determined Relative Vapor Density at 20 �C |Not determined Relative Density |7.923 - 8.757 lb/gal Specific Gravity |0.95 - 1.05 Solubility |100% in water Partition coefficient: |Not determined n-octanol/water | Viscosity |7500 - 12000 cps Lower Flammable Limit |Not applicable Upper Flammable Limit |Not applicable 9.2. Other Information VOCs: **Water & fragrance exemption in calculation SCAQMD 304-91 / EPA 24: Not tested CARB Method 310**: 0.8 g/L 0.033 lb/gal 0.08% SCAQMD Method 313: Not tested VOC Composite Partial Pressure: Not determined SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity Non-reactive. 10.2 Chemical Stability Stable under normal conditions 70oF (21oC) and 14.7 psig (760 mmHg). 10.3 Possibility of Hazardous Reactions None known. 10.4 Conditions to Avoid Excessive heat or cold. 10.5 Incompatible Materials Do not mix with oxidizers, acids, bathroom cleaners, or disinfecting agents. 10.6 Hazardous Decomposition Products Normal products of combustion - CO, CO2. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Non-irritant per Dermal Irritection� assay modeling. No animal testing performed. Serious Eye Damage/Irritation: Irritant per Ocular Irritection� assay modeling. No animal testing performed. Respiratory or Skin Sensitization: Germ Cell Mutagenicity: Mixture does not classify under this category. Carcinogenicity: No ingredients trigger or classify under this category under NTP, IARC or OSHA. Reproductive Toxicity: Mixture does not classify under this category. Specific Target Organ Toxicity (Single Exposure): Mixture does not classify under this category. Specific Target Organ Toxicity (Repeated Exposure): Mixture does not classify under this category. Aspiration Hazard: Mixture does not classify under this category. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Volume of ingredients used does not trigger toxicity classifications under the Globally Harmonized System of Classification and Labelling of Chemicals. 12.2. Persistence and Degradability No data available. 12.3. Bioaccumulative Potential No data available. 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects No data available. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Unused or Used Liquid: May be considered hazardous in your area depending on usage and tonnage of disposal - check with local, regional, and or national regulations for appropriate methods of disposal. Additional Information: Empty Containers: Dispose of in accordance with local regulations. Never dispose of used degreasing rinsates into lakes, streams, and open bodies of water or storm drains. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Not Regulated for shipping. Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |Not classified as Hazardous Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Not classified as Hazardous Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA Section 311/312 Hazard Classes |Not applicable. Toxic Substances Control Act (TSCA) |TSCA and DSL Inventory. 15.2 US State Regulations Clean Air Act (CAA): Benzyl Alcohol 100-51-6 Group III Clean Water Act (CWA): Not applicable State Right To Know Lists: Diisopropanolamine 110-97-4 Massachusetts, Pennsylvania Benzyl Alcohol 100-51-6 Massachusetts, Pennsylvania California Proposition 65: No ingredients listed Texas ESL: Ethoxylated Alcohol 68439-46-3 60 ?g/m3 long term 600 ?g/m3 short term Sodium Citrate 68-04-2 5 ?g/m3 long term 50 ?g/m3 short term Sodium Carbonate 497-19-8 5 ?g/m3 long term 50 ?g/m3 short term Citric Acid 77-92-9 10 ?g/m3 long term 100 ?g/m3 short term Pumice 1322-09-8 5 ?g/m3 long term 50 ?g/m3 short term Diisopropanolamine 110-97-4 46 ?g/m3 long term 160 ?g/m3 short term Benzyl Alcohol 100-51-6 44 ?g/m3 long term 440 ?g/m3 short term SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |September 26, 2014 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.