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SDS Sheet 0041280

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Safety Data Sheet | |
Date of Issue: 02/24/2015  |Revision Date: 02/26/2015  |Revision Number: 1.2      
Imperial Supplies Part Number: 0041280                                            

SECTION 1: IDENTIFICATION                                                         


1.1.  Product Identifier
Product Form:                                                                     
Product Name: GOJO® SUPRO MAX Cherry Hand Cleaner                                 
CAS No:                                                                           
Synonyms:                                                                         


1.2.  Intended Use of the Product
Use of the substance/mixture: Skin-care.                                          


1.3.  Name, Address, and Telephone of the Responsible Party
Company                                                                           
GOJO Industries, Inc.                                                             
One GOJO Plaza, Suite 500                                                         
Akron OH 44311                                                                    
Phone:  1 (330) 255-6000                                                          


1.4.  Emergency Telephone Number
Emergency     | 1-800-424-9300 CHEMTREC                                           
number        |                                                                   

SECTION 2: HAZARDS IDENTIFICATION                                                 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Eye irritation|Category 2A   
              |              
              |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Exclamat|        |        |        |        |        
                             |ion Mark|        |        |        |        |        
Signal Word (GHS-US)         |Warning                                             
Hazard Statements (GHS-US)   |H319 Causes serious eye irritation.                 
Precautionary Statements     |Prevention:                                         
(GHS-US)                     |P264 Wash skin thoroughly after handling.           
                             |P280 Wear eye protection/ face protection.          
                             |Response:                                           
                             |P305 + P351 + P338 IF IN EYES: Rinse cautiously with
                             |water for several minutes. Remove contact lenses, if
                             |present and easy to do. Continue rinsing.           
                             |P337 + P313 If eye irritation persists: Get medical 
                             |advice/ attention.                                  


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification: None known.                 


2.4.  Unknown Acute Toxicity (GHS-US)
                                                                                  

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                                 


3.1.  Substance
Name                            |Product identifier   |%       |Classification    
                                |                     |        |(GHS-US)          
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification    
                                |                     |        |(GHS-US)          
Distillates (petroleum),        |64742-47-8           |>= 10 - |                  
hydrotreated light              |                     |< 20    |                  
Glycerine                       |56-81-5              |>= 5 - <|                  
                                |                     |10      |                  
Cocoamidopropyl betaine         |61789-40-0           |>= 1 - <|                  
                                |                     |5       |                  
Titanium dioxide                |13463-67-7           |>= 1 - <|                  
                                |                     |5       |                  
5-Chloro-2-methyl-4-isothiazolin|26172-55-4           |< 0.1   |                  
-3-one                          |                     |        |                  


SECTION 4: FIRST AID MEASURES                                                     


4.1.  Description of First Aid Measures
First-aid Measures General: In the case of accident or if you feel unwell, seek   
medical advice immediately. When symptoms persist or in all cases of doubt seek   
medical advice.                                                                   
First-aid Measures After Inhalation: If inhaled, remove to fresh air. Get medical 
attention if symptoms occur.                                                      
First-aid Measures After Skin Contact: Wash with water and soap as a precaution.  
Get medical attention if symptoms occur.                                          
First-aid Measures After Eye Contact: In case of contact, immediately flush eyes  
with plenty of water for at least 15 minutes.                                     
If easy to do, remove contact lens, if worn. Get medical attention.               
First-aid Measures After Ingestion: If swallowed, DO NOT induce vomiting. Get     
medical attention if symptoms occur. Rinse mouth thoroughly with water.           


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries: Causes serious eye irritation.                                 
Symptoms/Injuries After Inhalation:                                               
Symptoms/Injuries After Skin Contact:                                             
Symptoms/Injuries After Eye Contact:                                              
Symptoms/Injuries After Ingestion:                                                
Chronic Symptoms:                                                                 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
Protection of first-aiders: First Aid responders should pay attention to          
self-protection, and use the recommended personal protective equipment when the   
potential for exposure exists.                                                    
Notes:  Treat symptomatically and supportively.                                   

SECTION 5: FIRE-FIGHTING MEASURES                                                 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Water spray. Alcohol-resistant foam Dry chemical.   
Carbon dioxide (CO2).                                                             
Unsuitable Extinguishing Media: None known.                                       


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: Exposure to combustion products may be a hazard to health.           
Explosion Hazard:                                                                 
Reactivity:                                                                       


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                      
Firefighting Instructions: Use extinguishing measures that are appropriate to     
local circumstances and the surrounding environment. Use water spray to cool      
unopened containers. Remove undamaged containers from fire area if it is safe to  
do so. Evacuate area.                                                             
Protection During Firefighting: In the event of fire, wear self-contained         
breathing apparatus. Use personal protective equipment.                           

SECTION 6: ACCIDENTAL RELEASE MEASURES                                            


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Use personal protective equipment. Follow safe handling advice  
and personal protective equipment recommendations.                                


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                             
Emergency Procedures:                                                             


6.1.2.      For Emergency Responders
Protective Equipment:                                                             
Emergency Procedures:                                                             


6.2.  Environmental Precautions
Discharge into the environment must be avoided. Prevent further leakage or        
spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment
or oil barriers). Retain and dispose of contaminated wash water. Local authorities
should be advised if significant spillages cannot be contained.                   


6.3.  Methods and Material for Containment and Cleaning Up
For Containment:                                                                  
Methods for Cleaning Up: Soak up with inert absorbent material. For large spills, 
provide diking or other appropriate containment to keep material from spreading.  
If diked material can be pumped, store recovered material in appropriat container.
Clean up remaining materials from spill with suitable absorbent. Local or national
regulations may apply to release and disposal of this material, as well as those  
materials and items employed in the cleanup of releases. You will need to         
determine which regulations are applicable. Sections 13 and 15 of this SDS provide
information regarding certain local or national requirements.                     


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                        


SECTION 7: HANDLING AND STORAGE                                                   


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Avoid inhalation of vapor or mist. Do not      
swallow. Do not get in eyes. Avoid prolonged or repeated contact with skin. Handle
in accordance with good industrial hygiene and safety practice. Take care to      
prevent spills, waste and minimize release to the environment.                    
Hygiene Measures: Ensure that eye flushing systems and safety showers are located 
close to the working place. When using do not eat, drink or smoke. Wash           
contaminated clothing before re-use.                                              


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures: See Engineering measures under EXPOSURE CONTROLS/PERSONAL     
PROTECTION section.                                                               
Local/Total ventilation: Use only with adequate ventilation.                      
Storage Conditions: Keep in properly labeled containers. Store in accordance with 
the particular national regulations.                                              
Materials to avoid: Do not store with the following product types: Strong         
oxidizing agents.                                                                 


7.3.  Specific End Use(s)
                                                                                  

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                  


8.1.  Control Parameters
Ingredients with workplace control parameters:                                    
Ingredients                                                                       
CAS-No.                                                                           
Value type (Form of exposure)                                                     
Control parameters / Permissible concentration                                    
Basis                                                                             
                                                                                  
Distillates (petroleum), hydrotreated light                                       
64742-47-8                                                                        
TWA (Mist)                                                                        
5 mg/m3                                                                           
OSHA Z-1                                                                          
                                                                                  
                                                                                  
                                                                                  
TWA (Mist)                                                                        
5 mg/m3                                                                           
NIOSH REL                                                                         
                                                                                  
                                                                                  
                                                                                  
ST (Mist)                                                                         
                                                                                  
NIOSH REL                                                                         
                                                                                  
Glycerine                                                                         
56-81-5                                                                           
TWA (mist, respirable fraction)                                                   
5 mg/m3                                                                           
OSHA Z-1                                                                          
                                                                                  
                                                                                  
                                                                                  
TWA (mist, total dust)                                                            
15 mg/m3                                                                          
OSHA Z-1                                                                          
                                                                                  
Titanium dioxide                                                                  
13463-67-7                                                                        
TWA (total dust)                                                                  
15 mg/m3                                                                          
OSHA Z-1                                                                          
                                                                                  
                                                                                  
                                                                                  
TWA                                                                               
10 mg/m3 (Titanium dioxide)                                                       
ACGIH                                                                             
                                                                                  
                                                                                  
Hazardous components without workplace control parameters:                        
Ingredients                                                                       
CAS-No.                                                                           
                                                                                  
Cocoamidopropyl betaine                                                           
61789-40-0                                                                        
                                                                                  
5-Chloro-2-methyl-4-isothiazolin-3-one                                            
26172-55-4                                                                        
                                                                                  


8.2.  Exposure Controls
Appropriate Engineering      |Ensure adequate ventilation, especially in confined 
Controls                     |areas. Minimize workplace exposure concentrations.  
                             |Dust formation may be relevant in the processing of 
                             |this product. In addition to substance-specific     
                             |OELs, general limitations of concentrations of      
                             |particulates in the air at workplaces have to be    
                             |considered in workplace risk assessment. Relevant   
                             |limits include: OSHA PEL for Particulates Not       
                             |Otherwise Regulated of 15 mg/m3 - total dust, 5     
                             |mg/m3 - respirable fraction; and ACGIH TWA for      
                             |Particles (insoluble or poorly soluble) Not         
                             |Otherwise. Specified of 3 mg/m3 - respirable        
                             |particles, 10 mg/m3 - inhalable particles.          
Personal Protective Equipment|                                                    
Materials for Protective     |                                                    
Clothing                     |                                                    
Hand Protection              |Material: Impervious gloves.                        
                             |Remarks: Choose gloves to protect hands against     
                             |chemicals depending on the concentration specific to
                             |place of work. Breakthrough time is not determined  
                             |for the product. Change gloves often! For special   
                             |applications, we recommend clarifying the resistance
                             |to chemicals of the aforementioned protective gloves
                             |with the glove manufacturer. Wash hands before      
                             |breaks and at the end of workday.                   
Eye Protection               |Wear the following personal protective equipment:   
                             |Safety goggles.                                     
Skin and Body Protection     |Select appropriate protective clothing based on     
                             |chemical resistance data and an assessment of the   
                             |local exposure potential. Skin contact must be      
                             |avoided by using impervious protective clothing     
                             |(gloves, aprons, boots, etc).                       
Respiratory Protection       |General and local exhaust ventilation is recommended
                             |to maintain vapor exposures below recommended       
                             |limits. Where concentrations are above recommended  
                             |limits or are unknown, appropriate respiratory      
                             |protection should be worn. Follow OSHA respirator   
                             |regulations (29 CFR 1910.134) and use NIOSH/MSHA    
                             |approved respirators. Protection provided by air    
                             |purifying respirators against exposure to any       
                             |hazardous chemical is limited. Use a positive       
                             |pressure air supplied respirator if there is any    
                             |potential for uncontrolled release, exposure levels 
                             |are unknown, or any other circumstance where air    
                             |purifying respirators may not provide adequate      
                             |protection.                                         
Thermal Hazard Protection    |                                                    

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                       


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |liquid                                       
Appearance                          |                                             
Odor                                |fruity                                       
Odor Threshold                      |No data available                            
pH                                  |4.5 - 8.0                                    
Relative Evaporation Rate (butyl    |No data available                            
acetate=1)                          |                                             
Melting Point                       |No data available                            
Freezing Point                      |No data available                            
Boiling Point                       |No data available                            
Flash Point                         |> 100 °C                                     
Auto-ignition Temperature           |No data available                            
Decomposition Temperature           |The substance or mixture is not classified   
                                    |self-reactive.                               
Flammability (solid, gas)           |Not applicable                               
Vapor Pressure                      |No data available                            
Relative Vapor Density at 20 °C     |No data available                            
Relative Density                    |                                             
Specific Gravity                    |                                             
Solubility                          |soluble                                      
Partition coefficient:              |Not applicable                               
n-octanol/water                     |                                             
Viscosity                           |Viscosity, kinematic: 12,000 - 40,000 mm2/s  
                                    |(20 °C)                                      
Lower Flammable Limit               |No data available                            
Upper Flammable Limit               |No data available                            


9.2.  Other Information
Density: 1 g/cm3                                                                  

SECTION 10: STABILITY AND REACTIVITY                                              


10.1      Reactivity
Not classified as a reactivity hazard.                                            


10.2      Chemical Stability
Stable under normal conditions.                                                   


10.3      Possibility of Hazardous Reactions
Can react with strong oxidizing agents.                                           


10.4      Conditions to Avoid
None known.                                                                       


10.5      Incompatible Materials
Oxidizing agents                                                                  


10.6      Hazardous Decomposition Products
No hazardous decomposition products are known.                                    
Carbon oxides, Sulfur oxides, Nitrogen oxides (NOx), Metal oxides, Chlorine       
compounds.                                                                        

SECTION 11: TOXICOLOGICAL INFORMATION                                             


11.1. Information on Toxicological Effects
Acute Toxicity: Not classified based on available information.                    
Skin Corrosion/Irritation: Not classified based on available information.         
Serious Eye Damage/Irritation: Causes serious eye irritation.                     
Respiratory or Skin Sensitization:                                                
Skin sensitization: Not classified based on available information.                
Respiratory sensitization: Not classified based on available information.         
Germ Cell Mutagenicity: Not classified based on available information.            
Carcinogenicity: Not classified based on available information.                   
Reproductive Toxicity: Not classified based on available information.             
Specific Target Organ Toxicity (Single Exposure): Not classified based on         
available information.                                                            
Specific Target Organ Toxicity (Repeated Exposure): Not classified based on       
available information.                                                            
Aspiration Hazard: Not classified based on available information.                 
Symptoms/Injuries After Inhalation:                                               
Symptoms/Injuries After Skin Contact:                                             
Symptoms/Injuries After Eye Contact:                                              
Symptoms/Injuries After Ingestion:                                                
Chronic Symptoms:                                                                 

SECTION 12: ECOLOGICAL INFORMATION                                                


12.1. Toxicity
                                                                                  


12.2. Persistence and Degradability
                                                                                  


12.3. Bioaccumulative Potential
                                                                                  


12.4. Mobility in Soil
No data available.                                                                


12.5. Other Adverse Effects
No data available.                                                                

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: Dispose of in accordance with local regulations.  
Additional Information:  Contaminated packaging: Dispose of as unused product.    
Empty containers should be taken to an approved waste handling site for recycling 
or disposal.                                                                      

SECTION 14: TRANSPORT INFORMATION                                                 


14.1 In Accordance with DOT
Proper Shipping Name |                                                            
Hazard Class         |                       |<PICTOGRAM PHRASE>                  
Identification Number|                       |                                    
Label Codes          |                       |                                    
ERG Number           |                                                            


14.2 In Accordance with IMDG
Proper Shipping Name |Not regulated as a dangerous good                           
Hazard Class         |                                                            
Identification Number|                                                            
Label Codes          |                      |<PICTOGRAM PHRASE>                   
ntification Of The   |                      |                                     
Substance/m          |                      |                                     
EmS-No. (Fire)       |                      |                                     
EmS-No. (Spillage)   |                      |                                     


14.3 In Accordance with IATA
Proper Shipping Name |Not regulated as a dangerous good                           
Identification Number|                       |<PICTOGRAM PHRASE>                   
Hazard Class         |                       |                                     
Label Codes          |                       |                                     
ntification Of The   |                       |                                     
Substance/m          |                       |                                     
ERG Code (IATA)      |                                                            

SECTION 15: REGULATORY INFORMATION                                                

15.1      US Federal Regulations
<COMPONENT>                                                                       
EPCRA - Emergency Planning and Community Right-to-Know:                           
CERCLA Reportable Quantity: This material does not contain any components with a  
CERCLA RQ.                                                                        
SARA 304 Extremely Hazardous Substances Reportable Quantity: This material does   
not contain any components with a section 304 EHS RQ.                             
SARA 302: No chemicals in this material are subject to the reporting requirements 
of SARA Title III, Section 302.                                                   
SARA 313: This material does not contain any chemical components with known CAS   
numbers that exceed the threshold (De Minimis) reporting levels established by    
SARA Title III, Section 313.                                                      
SARA Section 311/312 Hazard Classes |Acute Health Hazard                          
Toxic Substances Control Act (TSCA) |                                             

15.2      US State Regulations
<COMPONENT>                                                                       
Pennsylvania Right To Know:                                                       
Water                                                                    7732-18-5
30 - 50 %                                                                         
Distillates (petroleum), hydrotreated light    64742-47-8        10 - 20 %        
Walnut seed extract                                           84012-43-1         5
- 10 %                                                                            
Glycerine                                                              56-81-5    
5 - 10 %                                                                          
Castor oil, sulfated                                             8002-33-3        
5 - 10 %                                                                          
Titanium dioxide                                                13463-67-7        
1 - 5 %                                                                           
2-Phenoxyethanol                                             122-99-6             
0.1 - 1 %                                                                         
                                                                                  
New Jersey Right To Know:                                                         
Water                                                                             
7732-18-5             30 - 50 %                                                   
Distillates (petroleum), hydrotreated light     64742-47-8          10 - 20 %     
Walnut seed extract                                            84012-43-1         
5 - 10 %                                                                          
Glycerine                                                               56-81-5   
5 - 10 %                                                                          
Castor oil, sulfated                                              8002-33-3       
5 - 10 %                                                                          
Titanium dioxide                                                 13463-67-7       
1 - 5 %                                                                           
                                                                                  
California Prop 65: This product does not contain any chemicals known to the State
of California to cause cancer, birth, or any other reproductive defects.          
                                                                                  

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION     

Revision date   |02/26/2015                                                       
Other           |This document has been prepared in accordance with the SDS       
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR    
                |1910.1200.                                                       
GHS Full Text Phrases:                                                            
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Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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