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SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Mixture Product Name: PURE CITRUS ORANGE SOLID AIR FRESHENER 8 OZ. CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Solid Air Freshener 1.3. Name, Address, and Telephone of the Responsible Party Company: Technical Chemical Company P.O. BOX 139 Cleburne, Texas 76033 Telephone: 817-645-6088 1.4. Emergency Telephone Number Emergency | CHEMTREC 24 Hour 1-800-424-9300, 1-703-527-3887 (International) number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Not classified| | | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |None Signal Word (GHS-US) |Warning Hazard Statements (GHS-US) |None Precautionary Statements |None (GHS-US) | 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None under normal conditions. 2.4. Unknown Acute Toxicity (GHS-US) No data available SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) Not applicable | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Water |7732-18-5 |70 - 85 |Not classified Fatty acids, C8-18 and |67701-10-4 |10 - 30 |Not classified C18-unsaturated, sodium salts | | | Peg-3 Sorbitan Oleate |9005-65-6 |5 - 10 |Not classified Propylene Glycol |57-55-6 |5 - 10 |Not classified Ethanol |64-17-5 |1 - 5 |Flam. Liq. 2, H225 SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid Measures After Inhalation: Allow victim to breathe fresh air. Allow the victim to rest. First-aid Measures After Skin Contact: Remove affected clothing and wash all exposed skin area with mild soap and water followed by warm water rinse. First-aid Measures After Eye Contact: Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. First-aid Measures After Ingestion: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Not expected to present a significant hazard under anticipated conditions of normal use. Symptoms/Injuries After Inhalation: May cause allergy or asthma symptoms or breathing difficulties if inhaled. Symptoms/Injuries After Skin Contact: May cause slight irritation . Itching. Red skin. Skin rash/inflammation. Symptoms/Injuries After Eye Contact: May cause slight eye irritation . Inflammation/damage of the eye tissue. Irritation of the eye tissue. Redness of the eye tissue. Symptoms/Injuries After Ingestion: May be harmful if swallowed and enters airways. Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed No additional information available SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable Extinguishing Media: Do not use a heavy water stream. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: No additional information available. Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Remove ignition sources. 6.1.1. For Non-emergency Personnel Protective Equipment: Safety glasses. Gloves. Emergency Procedures: Evacuate unnecessary personnel. 6.1.2. For Emergency Responders Protective Equipment: : Equip cleanup crew with proper protection. Emergency Procedures: Ventilate area. 6.2. Environmental Precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Dam up the solid spill. Keep in tubing if not used. Methods for Cleaning Up: : On land, sweep or shovel into suitable containers. Minimize generation of dust. Store away from other materials. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Hygiene Measures: Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Wash affected areas thoroughly after handling. Do not eat, drink or smoke when using this product. Wash contaminated clothing before reuse. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Comply with applicable regulations. Storage Conditions: Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. Incompatible products: Strong bases. Strong acids. Incompatible materials: Sources of ignition. Direct sunlight. 7.3. Specific End Use(s) Follow Label Directions. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters 8.2. Exposure Controls Appropriate Engineering |Ensure good ventilation of the work station. Local Controls |exhaust venilation, vent hoods. Personal Protective Equipment|Gloves. Safety glasses. Avoid all unnecessary |exposure. Materials for Protective | Clothing | Hand Protection |Wear protective gloves. Eye Protection |Chemical goggles or safety glasses. Skin and Body Protection |Wear suitable protective clothing. Respiratory Protection |Wear appropriate mask. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Solid Appearance |Solid Odor |Orange. Odor Threshold |No data available pH |9.2 Relative Evaporation Rate |No data available (butylacetate=1) | Melting Point |110 - 125 Â°C Freezing Point |No data available Boiling Point |100 Â°C Flash Point |None Auto-ignition Temperature |No data available Decomposition Temperature |No data available Flammability (solid, gas) |No data available Vapor Pressure |No data available Relative Vapor Density at 20 Â°C |No data available Relative Density |1 Specific Gravity | Solubility |Poorly soluble in water. Partition coefficient: | n-octanol/water | Viscosity | Lower Flammable Limit | Upper Flammable Limit | 9.2. Other Information VOC content : < 3 % SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No additional information available 10.2 Chemical Stability Not established. 10.3 Possibility of Hazardous Reactions Not established. 10.4 Conditions to Avoid Direct sunlight. Extremely high or low temperatures. 10.5 Incompatible Materials Strong acids. Strong bases. 10.6 Hazardous Decomposition Products Toxic fume. . Carbon monoxide. Carbon dioxide. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Not classified Skin Corrosion/Irritation: Not classified pH: 9.2 Serious Eye Damage/Irritation: Not classified pH: 9.2 Respiratory or Skin Sensitization: Not classified Germ Cell Mutagenicity: Not classified Carcinogenicity: Not classified Reproductive Toxicity: Not classified Specific Target Organ Toxicity (Single Exposure): Not classified Specific Target Organ Toxicity (Repeated Exposure): Not classified Aspiration Hazard: Not classified Symptoms/Injuries After Inhalation: May cause allergy or asthma symptoms or breathing difficulties if inhaled. Symptoms/Injuries After Skin Contact: May cause slight irritation . Itching. Red skin. Skin rash/inflammation. Symptoms/Injuries After Eye Contact: May cause slight eye irritation . Inflammation/damage of the eye tissue. Irritation of the eye tissue. Redness of the eye tissue. Symptoms/Injuries After Ingestion: May be harmful if swallowed and enters airways. Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Propylene Glycol (57-55-6) LC50 fish 1 51400 mg/l (96 h; Pimephales promelas) LC50 other aquatic organisms 1 > 1000 mg/l (96 h) EC50 Daphnia 1 34400 mg/l (48 h; Daphnia magna) LC50 fish 2 51600 mg/l (96 h; Oncorhynchus mykiss) TLM fish 1 > 1000 ppm (96 h; Pisces) TLM other aquatic organisms 1 > 1000 ppm (96 h) Threshold limit other aquatic organisms 1 > 1000 mg/l (96 h) Threshold limit algae 1 15000 mg/l (336 h; Selenastrum capricornutum) Threshold limit algae 2 < 5300 mg/l (336 h; Skeletonema costatum Ethanol (64-17-5) LC50 fish 1 14200 mg/l (96 h; Pimephales promelas) EC50 Daphnia 1 9300 mg/l (48 h; Daphnia magna) LC50 fish 2 13000 mg/l 96 h; Salmo gairdneri (Oncorhynchus mykiss) EC50 Daphnia 2 10800 mg/l (24 h; Daphnia magna) Threshold limit other aquatic organisms 1 65 mg/l (72 h; Protozoa) Threshold limit algae 1 1450 mg/l (192 h; Microcystis aeruginosa; Growth rate) Threshold limit algae 2 5000 mg/l (168 h; Scenedesmus quadricauda; Growth rate) Peg-3 Sorbitan Oleate (9005-65-6) Threshold limit algae 1 500 mg/l (504 h; Selenastrum capricornutum; Growth) 12.2. Persistence and Degradability PURE CITRUS ORANGE SOLID AIR FRESHENER 8 OZ. Persistence and degradability Not established. Propylene Glycol (57-55-6) Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Not established Biochemical oxygen demand (BOD) 0.96 - 1.08 g O? /g substance Chemical oxygen demand (COD) 1.63 g O? /g substance ThOD 2.10 g O? /g substance BOD (% of ThOD) 0.43 % ThOD Peg-3 Sorbitan Oleate (9005-65-6) 12.3. Bioaccumulative Potential PURE CITRUS ORANGE SOLID AIR FRESHENER 8 OZ. Bioaccumulative potential Not established. Propylene Glycol (57-55-6) Log Pow -1.41 - -0.30 Bioaccumulative potential Not bioaccumulative. Not established. Ethanol (64-17-5) BCF fish 1 1 (72 h; Cyprinus carpio) Log Pow -0.31 (Experimental value) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Peg-3 Sorbitan Oleate (9005-65-6) Bioaccumulative potential No bioaccumulation data available. Water (7732-18-5) Bioaccumulative potential Not established. Fatty acids, C8-18 and C18-unsaturated, sodium salts (67701-10-4) Bioaccumulative potential Not established. 12.4. Mobility in Soil Propylene Glycol (57-55-6) Surface tension 0.036 N/m (25 Â°C) Ethanol (64-17-5) Surface tension 0.022 N/m (20 Â°C) 12.5. Other Adverse Effects Other information : Avoid release to the environment. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Dispose of contents/container to appropriate waste disposal facility, in accordance with local, regional, national, international regulations. . Dispose in a safe manner in accordance with local/national regulations. Additional Information: Ecology - waste materials : Avoid release to the environment. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Not Regulated Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |Not Regulated Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Not Regulated Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA Section 311/312 Hazard Classes |Immediate (acute) health hazard Toxic Substances Control Act (TSCA) |Propylene Glycol (57-55-6) |Listed on the United States TSCA (Toxic |Substances Control Act) inventory 15.2 US State Regulations No additional information available Propylene Glycol (57-55-6) Listed on KECI (Korean Existing Chemicals Inventory) Listed on the AICS (Australian Inventory of Chemical Substances SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |12/10/2014 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----|Flam. Liq. 2 |Flammable liquids Category 2 -- | | ----|H225 |Highly flammable liquid and vapor -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.