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SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Mixture Product Name: PURE CITRUS VANILLA 7 OZ. CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Air Freshener 1.3. Name, Address, and Telephone of the Responsible Party Company Technical Chemical Company P.O. BOX 139 Cleburne, Texas 76033 Phone: 817-645-6088 1.4. Emergency Telephone Number Emergency | CHEMTREC 24 Hour 1-800-424-9300, 1-703-527-3887 (International) number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flam. Aerosol |H222 1 | Compressed gas|H280 Skin Irrit. 2 |H315 Eye Irrit. 2A |H319 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Gas Cylinder |Exclamation Mark Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |H222 - Extremely flammable aerosol |H280 - Contains gas under pressure; may explode if |heated |H315 - Causes skin irritation |H319 - Causes serious eye irritation Precautionary Statements |P210 - Keep away from heat,sparks,open flames,hot (GHS-US) |surfaces. - No smoking |P211 - Do not spray on an open flame or other |ignition source |P251 - Pressurized container: Do not pierce or burn, |even after use |P264 - Wash affected areas thoroughly after handling | |P280 - Wear protective gloves,protective |clothing,eye protection,face protection |P302+P352 - If on skin: Wash with plenty of soap and |water |P305+P351+P338 - If in eyes: Rinse cautiously with |water for several minutes. Remove contact lenses, if |present and easy to do. Continue rinsing |P321 - Specific treatment: See section 4.1 on SDS |P332+P313 - If skin irritation occurs: Get medical |advice/attention |P337+P313 - If eye irritation persists: Get medical |advice/attention |P362 - Take off contaminated clothing and wash |before reuse |P410+P403 - Protect from sunlight. Store in a |well-ventilated place |P410+P412 - Protect from sunlight. Do not expose to |temperatures exceeding 50 Â°C/122 Â°F 2.3. Other Hazards Other Hazards Not Contributing to the Classification: Contains gas under pressure; may explode if heated. 2.4. Unknown Acute Toxicity (GHS-US) No data available SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance: Not applicable Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Terpenes, Limonene Fraction |8028-48-6 |95 - 100|Flam. Liq. 3, H226 | | | | | | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid Measures After Inhalation: Cough. Allow victim to breathe fresh air. Allow the victim to rest. First-aid Measures After Skin Contact: Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. First-aid Measures After Eye Contact: Rinse cautiously with water for several minutes. Direct contact with the eyes is likely to be irritating. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid Measures After Ingestion: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Shortness of breath. Symptoms/Injuries After Skin Contact: Causes skin irritation. Symptoms/Injuries After Eye Contact: Causes serious eye irritation. Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed No additional information available SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable Extinguishing Media: Do not use a heavy water stream. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Combustible liquid. Extremely flammable aerosol. Explosion Hazard: Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. DO NOT fight fire when fire reaches explosives. Evacuate area. Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: No open flames. No smoking. Isolate from fire, if possible, without unnecessary risk. Remove ignition sources. Use special care to avoid static electric charges. 6.1.1. For Non-emergency Personnel Protective Equipment: Gloves. Safety glasses. Emergency Procedures: Evacuate unnecessary personnel. 6.1.2. For Emergency Responders Protective Equipment: Equip cleanup crew with proper protection. Emergency Procedures: Ventilate area. 6.2. Environmental Precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Hazardous waste due to potential risk of explosion. Pressurized container: Do not pierce or burn, even after use. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Do not spray on an open flame or other ignition source. Hygiene Measures: Wash affected areas thoroughly after handling. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Proper grounding procedures to avoid static electricity should be followed. Storage Conditions: Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. Do not expose to temperatures exceeding 50 Â°C/ 122 Â°F. Keep in fireproof place. 7.3. Specific End Use(s) Follow Label Directions. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters PURE CITRUS VANILLA 7 OZ. USA ACGIH ACGIH TWA (ppm) 30 ppm 8 HOURS 8.2. Exposure Controls Appropriate Engineering |Local exhaust venilation, vent hoods. Controls | Personal Protective Equipment|Gloves. Safety glasses. Avoid all unnecessary |exposure. Materials for Protective | Clothing | Hand Protection |Wear protective gloves. Eye Protection |Chemical goggles or safety glasses. Skin and Body Protection |Wear suitable protective clothing. Respiratory Protection |Wear appropriate mask. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Gas Appearance |Liquid. Odor |Vanilla. Odor Threshold |No data available pH |No data available Relative Evaporation Rate |0.2 (butylacetate=1) | Melting Point |-96 Â°C Freezing Point |No data available Boiling Point |176 Â°C Flash Point |43 Â°C Auto-ignition Temperature |237 Â°C Decomposition Temperature |No data available Flammability (solid, gas) |No data available Vapor Pressure |< 2 mm Hg @ 20 deg C Relative Vapor Density at 20 Â°C |No data available Relative Density |0.84 @ 25 deg C Specific Gravity | Solubility |Insoluble in water. Partition coefficient: | n-octanol/water | Viscosity |No data available Lower Flammable Limit |No data available Upper Flammable Limit |No data available 9.2. Other Information VOC content: 0 % SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No additional information available 10.2 Chemical Stability Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Extreme risk of explosion by shock, friction, fire or other sources of ignition. 10.3 Possibility of Hazardous Reactions Not established. 10.4 Conditions to Avoid Direct sunlight. Extremely high or low temperatures. Heat. Sparks. Open flame. Overheating. 10.5 Incompatible Materials Strong acids. Strong bases. 10.6 Hazardous Decomposition Products Toxic fume. . Carbon monoxide. Carbon dioxide. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Not classified PURE CITRUS VANILLA 7 OZ. LD50 oral rat > 5 g/kg LD50 dermal rabbit > 5 g/kg Skin Corrosion/Irritation: Causes skin irritation. Serious Eye Damage/Irritation: Causes serious eye irritation. Respiratory or Skin Sensitization: Not classified Germ Cell Mutagenicity: Not classified Carcinogenicity: Not classified Reproductive Toxicity: Not classified Specific Target Organ Toxicity (Single Exposure): Not classified Specific Target Organ Toxicity (Repeated Exposure): Not classified Aspiration Hazard: Not classified Symptoms/Injuries After Inhalation: Shortness of breath. Symptoms/Injuries After Skin Contact: Causes skin irritation. Symptoms/Injuries After Eye Contact: Causes serious eye irritation. Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity No additional information available 12.2. Persistence and Degradability PURE CITRUS VANILLA 7 OZ. Persistence and degradability Not established. Terpenes, Limonene Fraction (8028-48-6) Persistence and degradability Not established. 12.3. Bioaccumulative Potential PURE CITRUS VANILLA 7 OZ. Bioaccumulative potential Not established. Terpenes, Limonene Fraction (8028-48-6) Bioaccumulative potential Not established. 12.4. Mobility in Soil No additional information available 12.5. Other Adverse Effects Other information: Avoid release to the environment. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Dispose in a safe manner in accordance with local/national regulations. Container under pressure. Do not drill or burn even after use. Additional Information: Flammable vapors may accumulate in the container. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols Hazard Class |2.1 |<PICTOGRAM PHRASE> | |[pic] Identification Number|UN1950 | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |Aerosols Hazard Class |2.1 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Aerosols Identification Number|UN1950 |<PICTOGRAM PHRASE> Hazard Class |2.1 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA Section 311/312 Hazard Classes |PURE CITRUS VANILLA 7 OZ. |Fire hazard |Immediate (acute) health hazard |Sudden release of pressure hazard Toxic Substances Control Act (TSCA) | 15.2 US State Regulations <COMPONENT> No additional information available SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |08/20/2014 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----|Compressed gas |Gases under pressure Compressed gas -- | | ----|Eye Irrit. 2A |Serious eye damage/eye irritation Category 2A -- | | ----|Flam. Aerosol 1 |Flammable aerosol Category 1 -- | | ----|Flam. Liq. 3 |Flammable liquids Category 3 -- | | ----|Skin Irrit. 2 |Skin corrosion/irritation Category 2 -- | | |H222 |Extremely flammable aerosol |H226 |Flammable liquid and vapor |H280 |Contains gas under pressure; may explode if | |heated |H315 |Causes skin irritation |H319 |Causes serious eye irritation Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.