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SDS Sheet 0040780

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SECTION 1: IDENTIFICATION                                                       
 


1.1.  Product Identifier
Product Form: Mixture                                                           
 
Product Name: PURE CITRUS APPLE CINNAMON 7 OZ.                                  
 
CAS No:                                                                         
 
Synonyms:                                                                       
 


1.2.  Intended Use of the Product
Use of the substance/mixture: Air Freshener                                     
 


1.3.  Name, Address, and Telephone of the Responsible Party
Company                                                                         
 
Technical Chemical Company                                                      
 
P.O. BOX 139                                                                    
 
Cleburne, Texas 76033                                                           
 
Phone: 817-645-6088                                                             
 


1.4.  Emergency Telephone Number
Emergency     | CHEMTREC 24 Hour 1-800-424-9300, 1-703-527-3887 (International) 
 
number        |                                                                 
 

SECTION 2: HAZARDS IDENTIFICATION                                               
 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Flam. Aerosol |H222          
1             |              
Compressed gas|H280          
Skin Irrit. 2 |H315          
Eye Irrit. 2A |H319          


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Flame |Gas Cylinder |Exclamation Mark
        
Signal Word (GHS-US)         |Danger                                            
 
Hazard Statements (GHS-US)   |H222 - Extremely flammable aerosol                
 
                             |H280 - Contains gas under pressure; may explode if
 
                             |heated                                            
 
                             |H315 - Causes skin irritation                     
 
                             |H319 - Causes serious eye irritation              
 
Precautionary Statements     |P210 - Keep away from heat,sparks,open flames,hot 
 
(GHS-US)                     |surfaces. - No smoking                            
 
                             |P211 - Do not spray on an open flame or other     
 
                             |ignition source                                   
 
                             |P251 - Pressurized container: Do not pierce or
burn,
                             |even after use                                    
 
                             |P264 - Wash affected areas thoroughly after
handling
                             |                                                  
 
                             |P280 - Wear protective gloves,protective          
 
                             |clothing,eye protection,face protection           
 
                             |P302+P352 - If on skin: Wash with plenty of soap
and
                             |water                                             
 
                             |P305+P351+P338 - If in eyes: Rinse cautiously with
 
                             |water for several minutes. Remove contact lenses,
if
                             |present and easy to do. Continue rinsing          
 
                             |P321 - Specific treatment: See section 4.1 on SDS 
 
                             |P332+P313 - If skin irritation occurs: Get medical
 
                             |advice/attention                                  
 
                             |P337+P313 - If eye irritation persists: Get
medical 
                             |advice/attention                                  
 
                             |P362 - Take off contaminated clothing and wash    
 
                             |before reuse                                      
 
                             |P410+P403 - Protect from sunlight. Store in a     
 
                             |well-ventilated place                             
 
                             |P410+P412 - Protect from sunlight. Do not expose
to 
                             |temperatures exceeding 50 °C/122 °F               
 


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification:  Contains gas under       
 
pressure; may explode if heated.                                                
 


2.4.  Unknown Acute Toxicity (GHS-US)
No data available                                                               
 

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                               
 


3.1.  Substance: Not applicable
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
Terpenes, Limonene Fraction     |8028-48-6            |95 - 100|Flam. Liq. 3,
H226
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


SECTION 4: FIRST AID MEASURES                                                   
 


4.1.  Description of First Aid Measures
First-aid Measures General:  Never give anything by mouth to an unconscious     
 
person. If you feel unwell, seek medical advice                                 
 
(show the label where possible).                                                
 
First-aid Measures After Inhalation:  Cough. Allow victim to breathe fresh air. 
 
Allow the victim to rest.                                                       
 
First-aid Measures After Skin Contact:  Wash with plenty of soap and water. Wash
 
contaminated clothing before reuse. If skin irritation occurs: Get medical      
 
advice/attention.                                                               
 
First-aid Measures After Eye Contact:  Rinse cautiously with water for several  
 
minutes. Direct contact with the eyes is likely to be irritating. Remove contact
 
lenses, if present and easy to do. Continue rinsing. If eye irritation persists:
 
Get medical advice/attention.                                                   
 
First-aid Measures After Ingestion:  Rinse mouth. Do NOT induce vomiting. Obtain
 
emergency medical attention.                                                    
 


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries:                                                              
 
Symptoms/Injuries After Inhalation:  Shortness of breath.                       
 
Symptoms/Injuries After Skin Contact:  Causes skin irritation.                  
 
Symptoms/Injuries After Eye Contact:  Causes serious eye irritation.            
 
Symptoms/Injuries After Ingestion:                                              
 
Chronic Symptoms:                                                               
 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
No additional information available                                             
 

SECTION 5: FIRE-FIGHTING MEASURES                                               
 

5.1.  Extinguishing Media
Suitable Extinguishing Media:  Foam. Dry powder. Carbon dioxide. Water spray.
Sand
Unsuitable Extinguishing Media:  Do not use a heavy water stream.               
 


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: Combustible liquid. Extremely flammable aerosol.                   
 
Explosion Hazard: Heat may build pressure, rupturing closed containers,
spreading 
fire and increasing risk of burns and injuries.                                 
 
Reactivity:                                                                     
 


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                    
 
Firefighting Instructions:  Use water spray or fog for cooling exposed
containers.
Exercise caution when fighting any chemical fire. Prevent fire-fighting water
from
entering environment. DO NOT fight fire when fire reaches explosives. Evacuate  
 
area.                                                                           
 
Protection During Firefighting:  Do not enter fire area without proper
protective 
equipment, including respiratory protection.                                    
 

SECTION 6: ACCIDENTAL RELEASE MEASURES                                          
 


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures:  No open flames. No smoking. Isolate from fire, if possible,  
 
without unnecessary risk. Remove ignition sources. Use special care to avoid    
 
static electric charges.                                                        
 


6.1.1.      For Non-emergency Personnel
Protective Equipment:   Gloves. Safety glasses.                                 
 
Emergency Procedures:  Evacuate unnecessary personnel.                          
 


6.1.2.      For Emergency Responders
Protective Equipment:  Equip cleanup crew with proper protection.               
 
Emergency Procedures:  Ventilate area.                                          
 


6.2.  Environmental Precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters  
 
sewers or public waters.                                                        
 


6.3.  Methods and Material for Containment and Cleaning Up
For Containment:  Dam up the liquid spill.                                      
 
Methods for Cleaning Up:  Store away from other materials.                      
 


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                      
 


SECTION 7: HANDLING AND STORAGE                                                 
 


7.1.  Precautions for Safe Handling
Additional Hazards When Processed:  Hazardous waste due to potential risk of    
 
explosion. Pressurized container: Do not pierce  burn, even after use.          
 
Hygiene Measures:                                                               
 


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:  Proper grounding procedures to avoid static electricity    
 
should be followed.                                                             
 
Storage Conditions:  Keep only in the original container in a cool, well        
 
ventilated place away from : Keep container closed when not in use. Do not
expose 
to temperatures exceeding 50 °C/ 122 °F. Keep in fireproof place.               
 


7.3.  Specific End Use(s)
Follow Label Directions.                                                        
 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                
 


8.1.  Control Parameters
PURE CITRUS APPLE CINNAMON 7 OZ.                                                
 
USA ACGIH                                                                       
 
ACGIH TWA (ppm)                                                                 
 
30 ppm 8 HOURS                                                                  
 
                                                                                
 


8.2.  Exposure Controls
Appropriate Engineering      |Local exhaust venilation, vent hoods.             
 
Controls                     |                                                  
 
Personal Protective Equipment|Gloves. Safety glasses. Avoid all unnecessary     
 
                             |exposure.                                         
 
Materials for Protective     |                                                  
 
Clothing                     |                                                  
 
Hand Protection              |Wear protective gloves.                           
 
Eye Protection               |Chemical goggles or safety glasses.               
 
Skin and Body Protection     |Wear suitable protective clothing.                
 
Respiratory Protection       |Wear appropriate mask.                            
 
Thermal Hazard Protection    |                                                  
 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                     
 


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |Gas                                        
 
Appearance                          |Liquid.                                    
 
Odor                                |Cinnamon.                                  
 
Odor Threshold                      |No data available                          
 
pH                                  |No data available                          
 
Relative Evaporation Rate           |0.2                                        
 
(butylacetate=1)                    |                                           
 
Melting Point                       |-96 °C                                     
 
Freezing Point                      |No data available                          
 
Boiling Point                       |176 °C                                     
 
Flash Point                         |43 °C                                      
 
Auto-ignition Temperature           |237 °C                                     
 
Decomposition Temperature           |No data available                          
 
Flammability (solid, gas)           |No data available                          
 
Vapor Pressure                      |< 2 mm Hg @ 20 deg C                       
 
Relative Vapor Density at 20 °C     |No data available                          
 
Relative Density                    |0.84 @ 25 deg C                            
 
Specific Gravity                    |                                           
 
Solubility                          |Insoluble in water.                        
 
Partition coefficient:              |                                           
 
n-octanol/water                     |                                           
 
Viscosity                           |No data available                          
 
Lower Flammable Limit               |No data available                          
 
Upper Flammable Limit               |No data available                          
 


9.2.  Other Information
VOC content: 0 %                                                                
 

SECTION 10: STABILITY AND REACTIVITY                                            
 


10.1      Reactivity
No additional information available                                             
 


10.2      Chemical Stability
Extremely flammable aerosol. Contains gas under pressure; may explode if heated.
 
Extreme risk of explosion by shock, friction fire or other sources of ignition. 
 


10.3      Possibility of Hazardous Reactions
Not established.                                                                
 


10.4      Conditions to Avoid
Direct sunlight. Extremely high or low temperatures. Heat. Sparks. Open flame.  
 
Overheating.                                                                    
 


10.5      Incompatible Materials
Strong acids. Strong bases.                                                     
 


10.6      Hazardous Decomposition Products
Toxic fume. . Carbon monoxide. Carbon dioxide.                                  
 

SECTION 11: TOXICOLOGICAL INFORMATION                                           
 


11.1. Information on Toxicological Effects
Acute Toxicity: Not classified                                                  
 
PURE CITRUS APPLE CINNAMON 7 OZ.                                                
 
LD50 oral rat                                                                   
 
> 5 g/kg                                                                        
 
                                                                                
 
LD50 dermal rabbit                                                              
 
> 5 g/kg                                                                        
 
                                                                                
 
                                                                                
 
                                                                                
 
Skin Corrosion/Irritation: Causes skin irritation.                              
 
Serious Eye Damage/Irritation: Causes serious eye irritation.                   
 
Respiratory or Skin Sensitization: Not classified                               
 
Germ Cell Mutagenicity: Not classified                                          
 
Carcinogenicity: Not classified                                                 
 
Reproductive Toxicity: Not classified                                           
 
Specific Target Organ Toxicity (Single Exposure): Not classified                
 
Specific Target Organ Toxicity (Repeated Exposure): Not classified              
 
Aspiration Hazard: Not classified                                               
 
Symptoms/Injuries After Inhalation:  Shortness of breath.                       
 
Symptoms/Injuries After Skin Contact:  Causes skin irritation.                  
 
Symptoms/Injuries After Eye Contact:  Causes serious eye irritation.            
 
Symptoms/Injuries After Ingestion:                                              
 
Chronic Symptoms:                                                               
 

SECTION 12: ECOLOGICAL INFORMATION                                              
 


12.1. Toxicity
No additional information available                                             
 


12.2. Persistence and Degradability
PURE CITRUS APPLE CINNAMON 7 OZ.                                                
 
Persistence and degradability                                                   
 
Not established.                                                                
 
                                                                                
 
Terpenes, Limonene Fraction (8028-48-6)                                         
 
Persistence and degradability                                                   
 
Not established.                                                                
 
                                                                                
 


12.3. Bioaccumulative Potential
PURE CITRUS APPLE CINNAMON 7 OZ.                                                
 
Bioaccumulative potential                                                       
 
Not established.                                                                
 
                                                                                
 


12.4. Mobility in Soil
No additional information available                                             
 


12.5. Other Adverse Effects
Other information: Avoid release to the environment.                            
 

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations:  Dispose in a safe manner in accordance with    
 
local/national regulations. Container under pressure. Do not drill or burn even 
 
after use.                                                                      
 
Additional Information:  Flammable vapors may accumulate in the container.      
 

SECTION 14: TRANSPORT INFORMATION                                               
 


14.1 In Accordance with DOT
Proper Shipping Name |Aerosols                                                  
 
Hazard Class         |2.1                    |<PICTOGRAM PHRASE>                
 
                     |                       |[pic]                             
 
Identification Number|UN1950                 |                                  
 
Label Codes          |                       |                                  
 
ERG Number           |                                                          
 


14.2 In Accordance with IMDG
Proper Shipping Name |Aerosols,                                                 
 
Hazard Class         |2.1                                                       
 
Identification Number|UN1950                                                    
 
Label Codes          |                      |<PICTOGRAM PHRASE>                 
 
ntification Of The   |                      |                                   
 
Substance/m          |                      |                                   
 
EmS-No. (Fire)       |                      |                                   
 
EmS-No. (Spillage)   |                      |                                   
 


14.3 In Accordance with IATA
Proper Shipping Name |Aerosols,                                                 
 
Identification Number|UN1950                 |<PICTOGRAM PHRASE>                
  
Hazard Class         |2.1                    |                                  
  
Label Codes          |                       |                                  
  
ntification Of The   |                       |                                  
  
Substance/m          |                       |                                  
  
ERG Code (IATA)      |                                                          
 

SECTION 15: REGULATORY INFORMATION                                              
 

15.1      US Federal Regulations
<COMPONENT>                                                                     
 
SARA Section 311/312 Hazard Classes |PURE CITRUS APPLE CINNAMON 7 OZ.           
 
                                    |Fire hazard                                
 
                                    |Immediate (acute) health hazard            
 
                                    |Sudden release of pressure hazard          
 
Toxic Substances Control Act (TSCA) |                                           
 

15.2      US State Regulations
<COMPONENT>                                                                     
 
No additional information available                                             
 

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION   
 

Revision date   |08/20/2014                                                     
 
Other           |This document has been prepared in accordance with the SDS     
 
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR  
 
                |1910.1200.                                                     
 
GHS Full Text Phrases:                                                          
 
----|Compressed gas                 |Gases under pressure Compressed gas        
 
--  |                               |                                           
 
----|Eye Irrit. 2A                  |Serious eye damage/eye irritation Category
2A
--  |                               |                                           
 
----|Flam. Aerosol 1                |Flammable aerosol Category 1               
 
--  |                               |                                           
 
----|Flam. Liq. 3                   |Flammable liquids Category 3               
 
--  |                               |                                           
 
----|Skin Irrit. 2                  |Skin corrosion/irritation Category 2       
 
--  |                               |                                           
 
H222|H222                           |Extremely flammable aerosol                
 
    |H226                           |Flammable liquid and vapor                 
 
    |H280                           |Contains gas under pressure; may explode if
 
    |                               |heated                                     
 
    |H315                           |Causes skin irritation                     
 
    |H319                           |Causes serious eye irritation              
 


Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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