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SDS Sheet 0040170

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Safety Data Sheet | |
Date of Issue:             |Revision Date: 17-Nov-2015 |Revision Number: 1        
Imperial Supplies Part Number: 0040170                                            

SECTION 1: IDENTIFICATION                                                         


1.1.  Product Identifier
Product Form:                                                                     
Product Name: FAST ORANGE PUMICE BAR SOAP 5.75OZ                                  
CAS No:                                                                           
Synonyms: None.                                                                   


1.2.  Intended Use of the Product
Use of the substance/mixture: Bar soap.                                           


1.3.  Name, Address, and Telephone of the Responsible Party
Company                                                                           
ITW Permatex                                                                      
6875 Parkland Blvd.                                                               
Solon, OH 44139 USA                                                               
Phone: 1-87-Permatex (877) 376-2839                                               


1.4.  Emergency Telephone Number
Emergency     |Chem-Tel: 800-255-3924, International Emergency: 00+1+             
number        |813-248-0585, Contract Number: MIS0003453                          

SECTION 2: HAZARDS IDENTIFICATION                                                 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
              |              
              |              
              |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |        |        |        |        |        |        
Signal Word (GHS-US)         |                                                    
Hazard Statements (GHS-US)   |                                                    
Precautionary Statements     |Storage:                                            
(GHS-US)                     |Store in a well-ventilated place                    
                             |Disposal:                                           
                             |Dispose of contents/container to an approved waste  
                             |disposal plant                                      


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification: The product contains no     
substances which at their given concentration, are considered to be hazardous to  
health.                                                                           
This product contains titanium dioxide in a non-respirable form. Inhalation of    
titanium dioxide is unlikely to occur from exposure to this product.              


2.4.  Unknown Acute Toxicity (GHS-US)
77.05 % of the mixture consists of ingredient(s) of unknown toxicity.             

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                                 


3.1.  Substance
Name                            |Product identifier   |%       |Classification    
                                |                     |        |(GHS-US)          
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification    
                                |                     |        |(GHS-US)          
SODIUM PALMATE                  |8052-48-0            |15 - 40 |                  
                                |                     |Trade   |                  
                                |                     |Secret *|                  
PUMICE                          |1332-09-8            |10 - 30 |                  
                                |                     |Trade   |                  
                                |                     |Secret *|                  
GLYCERIN                        |56-81-5              |5 - 10  |                  
                                |                     |Trade   |                  
                                |                     |Secret *|                  
TITANIUM DIOXIDE                |13463-67-7           |1 - 5   |                  
                                |                     |Trade   |                  
                                |                     |Secret *|                  
                                |                     |        |                  


*The exact percentage (concentration) of composition has been withheld as a
trade secret.

SECTION 4: FIRST AID MEASURES                                                     


4.1.  Description of First Aid Measures
First-aid Measures General: Get medical advice/attention if you feel unwell.      
First-aid Measures After Inhalation: None under normal use conditions.            
First-aid Measures After Skin Contact: None under normal use conditions.          
First-aid Measures After Eye Contact: IF IN EYES: Rinse cautiously with water for 
several minutes. Remove contact lenses, if present and easy to do. Continue       
rinsing. If eye irritation persists: Get medical advice/attention.                
Self-protection of the first aider: Avoid contact with eyes.                      
First-aid Measures After Ingestion: IF SWALLOWED:. Do NOT induce vomiting. Never  
give anything by mouth to an unconscious person. Call a physician.                


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries: See section 2 for more information.                            
Symptoms/Injuries After Inhalation:                                               
Symptoms/Injuries After Skin Contact:                                             
Symptoms/Injuries After Eye Contact:                                              
Symptoms/Injuries After Ingestion:                                                
Chronic Symptoms:                                                                 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
Note to physicians: Treat symptomatically.                                        

SECTION 5: FIRE-FIGHTING MEASURES                                                 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Carbon dioxide (CO2), Dry chemical, Foam.           
Unsuitable Extinguishing Media: None.                                             


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: None in particular.                                                  
Explosion Hazard:                                                                 
Sensitivity to Mechanical Impact: None.                                           
Sensitivity to Static Discharge: None.                                            
Reactivity:                                                                       


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                      
Firefighting Instructions:                                                        
Protection During Firefighting: As in any fire, wear self-contained breathing     
apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective
gear.                                                                             

SECTION 6: ACCIDENTAL RELEASE MEASURES                                            


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Personal precautions: Avoid contact with eyes.                  


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                             
Emergency Procedures:                                                             


6.1.2.      For Emergency Responders
Protective Equipment:                                                             
Emergency Procedures:                                                             


6.2.  Environmental Precautions
Do not flush into surface water or sanitary sewer system. See Section 12 for      
additional ecological Information.                                                


6.3.  Methods and Material for Containment and Cleaning Up
For Containment: Prevent further leakage or spillage if safe to do so.            
Prevention of secondary hazards: Clean contaminated objects and areas thoroughly  
observing environmental regulations.                                              
Methods for Cleaning Up: Ensure adequate ventilation. Soak up with inert absorbent
material. Sweep up and shovel into suitable containers for disposal.              


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                        


SECTION 7: HANDLING AND STORAGE                                                   


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Advice on safe handling: Handle in accordance  
with good industrial hygiene and safety practice. Avoid contact with eyes.        
Hygiene Measures: Handle in accordance with good industrial hygiene and safety    
practice. Regular cleaning of equipment, work area and clothing is recommended.   


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                               
Storage Conditions: Keep containers tightly closed in a dry, cool and             
well-ventilated place.                                                            
Incompatible materials: None known.                                               


7.3.  Specific End Use(s)
                                                                                  

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                  


8.1.  Control Parameters
Exposure Guidelines:                                                              
Chemical Name                                                                     
ACGIH TLV                                                                         
OSHA PEL                                                                          
NIOSH IDLH                                                                        
                                                                                  
GLYCERIN                                                                          
56-81-5                                                                           
-                                                                                 
TWA: 15 mg/m3 mist, total particulate                                             
TWA: 5 mg/m3 mist, respirable fraction                                            
(vacated) TWA: 10 mg/m3 mist, total particulate                                   
(vacated) TWA: 5 mg/m3 mist, respirable fraction                                  
-                                                                                 
                                                                                  
TITANIUM DIOXIDE                                                                  
13463-67-7                                                                        
TWA: 10 mg/m3                                                                     
TWA: 15 mg/m3 total dust                                                          
(vacated) TWA: 10 mg/m3 total dust                                                
IDLH: 5000 mg/m3                                                                  
                                                                                  
                                                                                  
Other Information: Vacated limits revoked by the Court of Appeals decision in     
AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992).                                  


8.2.  Exposure Controls
Appropriate Engineering      |Eyewash stations.                                   
Controls                     |                                                    
Personal Protective Equipment|                                                    
Materials for Protective     |                                                    
Clothing                     |                                                    
Hand Protection              |                                                    
Eye Protection               |None under normal use conditions.                   
Skin and Body Protection     |None under normal use conditions.                   
Respiratory Protection       |None under normal use conditions.                   
Thermal Hazard Protection    |                                                    

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                       


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |Solid                                        
Appearance                          |Orange                                       
Odor                                |Citrus                                       
Odor Threshold                      |No information available                     
pH                                  |10.0-10.5                                    
Relative Evaporation Rate (butyl    |No information available                     
acetate=1)                          |                                             
Melting Point                       |No information available                     
Freezing Point                      |No information available                     
Boiling Point                       |Not Applicable                               
Flash Point                         |None                                         
Auto-ignition Temperature           |No information available                     
Decomposition Temperature           |No information available                     
Flammability (solid, gas)           |No information available                     
Vapor Pressure                      |No information available                     
Relative Vapor Density at 20 °C     |No information available                     
Relative Density                    |No information available                     
Specific Gravity                    |                                             
Solubility                          |No information available                     
Partition coefficient:              |No information available                     
n-octanol/water                     |                                             
Viscosity                           |Kinematic viscosity: No information available
                                    |                                             
                                    |Dynamic viscosity: No information available  
Lower Flammable Limit               |No information available                     
Upper Flammable Limit               |No information available                     


9.2.  Other Information
Softening point: No information available                                         
Molecular weight: No information available                                        
VOC Content (%): 0                                                                
Density: No information available                                                 
Bulk density: No information available                                            

SECTION 10: STABILITY AND REACTIVITY                                              


10.1      Reactivity
No data available.                                                                


10.2      Chemical Stability
Stable under recommended storage conditions.                                      


10.3      Possibility of Hazardous Reactions
None under normal processing.                                                     


10.4      Conditions to Avoid
Excessive heat.                                                                   


10.5      Incompatible Materials
None known.                                                                       


10.6      Hazardous Decomposition Products
Carbon oxides.                                                                    

SECTION 11: TOXICOLOGICAL INFORMATION                                             


11.1. Information on Toxicological Effects
Acute Toxicity:                                                                   
Skin Corrosion/Irritation:                                                        
Serious Eye Damage/Irritation:                                                    
Respiratory or Skin Sensitization: No information available.                      
Germ Cell Mutagenicity: No information available.                                 
Carcinogenicity: The table below indicates whether each agency has listed any     
ingredient as a carcinogen.                                                       
Chemical Name                                                                     
ACGIH                                                                             
IARC                                                                              
NTP                                                                               
OSHA                                                                              
                                                                                  
TITANIUM DIOXIDE                                                                  
13463-67-7                                                                        
-                                                                                 
Group 2B                                                                          
-                                                                                 
X                                                                                 
                                                                                  
IARC (International Agency for Research on Cancer) Group 2B - Possibly            
Carcinogenic to Humans                                                            
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present                                                                       
Reproductive Toxicity:                                                            
Specific Target Organ Toxicity (Single Exposure): Eyes, kidney, Lungs, Respiratory
system, Skin.                                                                     
The following values are calculated based on chapter 3.1 of the GHS document .    
ATEmix (oral) 15288 mg/kg                                                         
ATEmix (dermal) 30631 mg/kg                                                       
ATEmix (inhalation-dust/mist) 0.4 mg/l                                            
Specific Target Organ Toxicity (Repeated Exposure):                               
Aspiration Hazard:                                                                
Symptoms/Injuries After Inhalation: None under normal use conditions.             
Symptoms/Injuries After Skin Contact: None under normal use conditions.           
Symptoms/Injuries After Eye Contact: Contact with eyes may cause irritation. May  
cause redness and tearing of the eyes.                                            
Symptoms/Injuries After Ingestion: Ingestion may cause irritation to mucous       
membranes.                                                                        
Chronic Symptoms: No information available.                                       

SECTION 12: ECOLOGICAL INFORMATION                                                


12.1. Toxicity
Ecotoxicity: 81 % of the mixture consists of components(s) of unknown hazards to  
the aquatic environment.                                                          
Chemical Name                                                                     
Algae/aquatic plants                                                              
Fish                                                                              
Crustacea                                                                         
                                                                                  
GLYCERIN                                                                          
56-81-5                                                                           
-                                                                                 
51 - 57: 96 h Oncorhynchus mykiss mL/L LC50 static                                
500: 24 h Daphnia magna mg/L EC50                                                 
                                                                                  


12.2. Persistence and Degradability
No information available.                                                         


12.3. Bioaccumulative Potential
No information available.                                                         


12.4. Mobility in Soil
No information available.                                                         
Chemical Name                                                                     
Partition coefficient                                                             
                                                                                  
GLYCERIN                                                                          
56-81-5                                                                           
-1.76                                                                             
                                                                                  


12.5. Other Adverse Effects
No information available.                                                         

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: Disposal should be in accordance with applicable  
regional, national and local laws and                                             
regulations.                                                                      
Additional Information:                                                           
Contaminated packaging: Do not reuse container.                                   
US EPA Waste Number: Not applicable.                                              

SECTION 14: TRANSPORT INFORMATION                                                 


14.1 In Accordance with DOT
Proper Shipping Name |Not regulated                                               
Hazard Class         |                       |<PICTOGRAM PHRASE>                  
Identification Number|                       |                                    
Label Codes          |                       |                                    
ERG Number           |                                                            


14.2 In Accordance with IMDG
Proper Shipping Name |Not regulated                                               
Hazard Class         |                                                            
Identification Number|                                                            
Label Codes          |                      |<PICTOGRAM PHRASE>                   
ntification Of The   |                      |                                     
Substance/m          |                      |                                     
EmS-No. (Fire)       |                      |                                     
EmS-No. (Spillage)   |                      |                                     


14.3 In Accordance with IATA
Proper Shipping Name |Not regulated                                               
Identification Number|                       |<PICTOGRAM PHRASE>                   
Hazard Class         |                       |                                     
Label Codes          |                       |                                     
ntification Of The   |                       |                                     
Substance/m          |                       |                                     
ERG Code (IATA)      |                                                            

SECTION 15: REGULATORY INFORMATION                                                

15.1      US Federal Regulations
<COMPONENT>                                                                       
SARA 313: Section 313 of Title III of the Superfund Amendments and Reauthorization
Act of 1986 (SARA). This product does not contain any chemicals which are subject 
to the reporting requirements of the Act and Title 40 of the Code of Federal      
Regulations, Part 372.                                                            
                                                                                  
CWA (Clean Water Act): This product does not contain any substances regulated as  
pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42).     
                                                                                  
CERCLA: This material, as supplied, does not contain any substances regulated as  
hazardous substances under the Comprehensive Environmental Response Compensation  
and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and           
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting          
requirements at the local, regional, or state level pertaining to releases of this
material.                                                                         
SARA Section 311/312 Hazard Classes |Acute health hazard - No                     
                                    |Chronic Health Hazard - No                   
                                    |Fire hazard - No                             
                                    |Sudden release of pressure hazard - No       
                                    |Reactive Hazard - No                         
Toxic Substances Control Act (TSCA) |Complies                                     

15.2      US State Regulations
<COMPONENT>                                                                       
California Proposition 65: This product contains the following Proposition 65     
chemicals                                                                         
Chemical Name                                                                     
California Proposition 65                                                         
                                                                                  
TITANIUM DIOXIDE - 13463-67-7                                                     
Carcinogen                                                                        
                                                                                  
                                                                                  
U.S. State Right-to-Know Regulations:                                             
Chemical Name                                                                     
New Jersey                                                                        
Massachusetts                                                                     
Pennsylvania                                                                      
                                                                                  
GLYCERIN                                                                          
56-81-5                                                                           
X                                                                                 
X                                                                                 
X                                                                                 
                                                                                  
TITANIUM DIOXIDE                                                                  
13463-67-7                                                                        
X                                                                                 
X                                                                                 
X                                                                                 
                                                                                  
U.S. EPA Label Information:                                                       
EPA Pesticide Registration Number: Not applicable.                                
                                                                                  

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION     

Revision date   |17-Nov-2015                                                      
Other           |This document has been prepared in accordance with the SDS       
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR    
                |1910.1200.                                                       
GHS Full Text Phrases:                                                            
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--  |                               |                                             
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--  |                               |                                             


Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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