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Safety Data Sheet | | Date of Issue: |Revision Date: 17-Nov-2015 |Revision Number: 1 Imperial Supplies Part Number: 0040170 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: FAST ORANGE PUMICE BAR SOAP 5.75OZ CAS No: Synonyms: None. 1.2. Intended Use of the Product Use of the substance/mixture: Bar soap. 1.3. Name, Address, and Telephone of the Responsible Party Company ITW Permatex 6875 Parkland Blvd. Solon, OH 44139 USA Phone: 1-87-Permatex (877) 376-2839 1.4. Emergency Telephone Number Emergency |Chem-Tel: 800-255-3924, International Emergency: 00+1+ number |813-248-0585, Contract Number: MIS0003453 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) | | | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) | | | | | | Signal Word (GHS-US) | Hazard Statements (GHS-US) | Precautionary Statements |Storage: (GHS-US) |Store in a well-ventilated place |Disposal: |Dispose of contents/container to an approved waste |disposal plant 2.3. Other Hazards Other Hazards Not Contributing to the Classification: The product contains no substances which at their given concentration, are considered to be hazardous to health. This product contains titanium dioxide in a non-respirable form. Inhalation of titanium dioxide is unlikely to occur from exposure to this product. 2.4. Unknown Acute Toxicity (GHS-US) 77.05 % of the mixture consists of ingredient(s) of unknown toxicity. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) SODIUM PALMATE |8052-48-0 |15 - 40 | | |Trade | | |Secret *| PUMICE |1332-09-8 |10 - 30 | | |Trade | | |Secret *| GLYCERIN |56-81-5 |5 - 10 | | |Trade | | |Secret *| TITANIUM DIOXIDE |13463-67-7 |1 - 5 | | |Trade | | |Secret *| | | | *The exact percentage (concentration) of composition has been withheld as a trade secret. SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Get medical advice/attention if you feel unwell. First-aid Measures After Inhalation: None under normal use conditions. First-aid Measures After Skin Contact: None under normal use conditions. First-aid Measures After Eye Contact: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Self-protection of the first aider: Avoid contact with eyes. First-aid Measures After Ingestion: IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: See section 2 for more information. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Note to physicians: Treat symptomatically. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Carbon dioxide (CO2), Dry chemical, Foam. Unsuitable Extinguishing Media: None. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: None in particular. Explosion Hazard: Sensitivity to Mechanical Impact: None. Sensitivity to Static Discharge: None. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Personal precautions: Avoid contact with eyes. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological Information. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Prevent further leakage or spillage if safe to do so. Prevention of secondary hazards: Clean contaminated objects and areas thoroughly observing environmental regulations. Methods for Cleaning Up: Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Advice on safe handling: Handle in accordance with good industrial hygiene and safety practice. Avoid contact with eyes. Hygiene Measures: Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Keep containers tightly closed in a dry, cool and well-ventilated place. Incompatible materials: None known. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Exposure Guidelines: Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH GLYCERIN 56-81-5 - TWA: 15 mg/m3 mist, total particulate TWA: 5 mg/m3 mist, respirable fraction (vacated) TWA: 10 mg/m3 mist, total particulate (vacated) TWA: 5 mg/m3 mist, respirable fraction - TITANIUM DIOXIDE 13463-67-7 TWA: 10 mg/m3 TWA: 15 mg/m3 total dust (vacated) TWA: 10 mg/m3 total dust IDLH: 5000 mg/m3 Other Information: Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). 8.2. Exposure Controls Appropriate Engineering |Eyewash stations. Controls | Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |None under normal use conditions. Skin and Body Protection |None under normal use conditions. Respiratory Protection |None under normal use conditions. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Solid Appearance |Orange Odor |Citrus Odor Threshold |No information available pH |10.0-10.5 Relative Evaporation Rate (butyl |No information available acetate=1) | Melting Point |No information available Freezing Point |No information available Boiling Point |Not Applicable Flash Point |None Auto-ignition Temperature |No information available Decomposition Temperature |No information available Flammability (solid, gas) |No information available Vapor Pressure |No information available Relative Vapor Density at 20 �C |No information available Relative Density |No information available Specific Gravity | Solubility |No information available Partition coefficient: |No information available n-octanol/water | Viscosity |Kinematic viscosity: No information available | |Dynamic viscosity: No information available Lower Flammable Limit |No information available Upper Flammable Limit |No information available 9.2. Other Information Softening point: No information available Molecular weight: No information available VOC Content (%): 0 Density: No information available Bulk density: No information available SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No data available. 10.2 Chemical Stability Stable under recommended storage conditions. 10.3 Possibility of Hazardous Reactions None under normal processing. 10.4 Conditions to Avoid Excessive heat. 10.5 Incompatible Materials None known. 10.6 Hazardous Decomposition Products Carbon oxides. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: No information available. Germ Cell Mutagenicity: No information available. Carcinogenicity: The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA TITANIUM DIOXIDE 13463-67-7 - Group 2B - X IARC (International Agency for Research on Cancer) Group 2B - Possibly Carcinogenic to Humans OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): Eyes, kidney, Lungs, Respiratory system, Skin. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 15288 mg/kg ATEmix (dermal) 30631 mg/kg ATEmix (inhalation-dust/mist) 0.4 mg/l Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: None under normal use conditions. Symptoms/Injuries After Skin Contact: None under normal use conditions. Symptoms/Injuries After Eye Contact: Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Symptoms/Injuries After Ingestion: Ingestion may cause irritation to mucous membranes. Chronic Symptoms: No information available. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Ecotoxicity: 81 % of the mixture consists of components(s) of unknown hazards to the aquatic environment. Chemical Name Algae/aquatic plants Fish Crustacea GLYCERIN 56-81-5 - 51 - 57: 96 h Oncorhynchus mykiss mL/L LC50 static 500: 24 h Daphnia magna mg/L EC50 12.2. Persistence and Degradability No information available. 12.3. Bioaccumulative Potential No information available. 12.4. Mobility in Soil No information available. Chemical Name Partition coefficient GLYCERIN 56-81-5 -1.76 12.5. Other Adverse Effects No information available. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Disposal should be in accordance with applicable regional, national and local laws and regulations. Additional Information: Contaminated packaging: Do not reuse container. US EPA Waste Number: Not applicable. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Not regulated Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |Not regulated Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Not regulated Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA 313: Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. CWA (Clean Water Act): This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). CERCLA: This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material. SARA Section 311/312 Hazard Classes |Acute health hazard - No |Chronic Health Hazard - No |Fire hazard - No |Sudden release of pressure hazard - No |Reactive Hazard - No Toxic Substances Control Act (TSCA) |Complies 15.2 US State Regulations <COMPONENT> California Proposition 65: This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 TITANIUM DIOXIDE - 13463-67-7 Carcinogen U.S. State Right-to-Know Regulations: Chemical Name New Jersey Massachusetts Pennsylvania GLYCERIN 56-81-5 X X X TITANIUM DIOXIDE 13463-67-7 X X X U.S. EPA Label Information: EPA Pesticide Registration Number: Not applicable. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |17-Nov-2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.