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MSDS 85523

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85523: Sno Bol Toilet Cleaner 32 Oz [12] (DISCONTINUED)
MSDS Last updated: 04/20/2010
                         CHURCH & DWIGHT CO., INC
                         MATERIAL SAFETY DATA SHEET
MSDS NUMBER:   MSDS-110                             ISSUE DATE: 06/23/09    

1. PRODUCT AND COMPANY IDENTIFICATION
Church & Dwight Co. Inc.
469 N. Harrison Street
Princeton, NJ 08540

Product Name
SNO BOL Toilet Bowl Cleaner                           Emergency Phone:
                                                      1-800-926-5222
EPA Reg. No. 10772-5                                  Medical Emergency Phone;
                                                      1-888-234-1828

2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Clear blue, liquid, wintergreen odor.
Can cause chemical burns to skin, eyes and mucous membranes.
Ingestion or inhalation can cause severe injury and possibly death.
Hazardous fumes will be generated if mixed with chlorine bleach, ammonia, or
other household cleaners and chemicals.
This product is labeled in accordance with regulations administered by the
Environmental Protection Agency (EPA). The use pattern and exposure in the
workplace are generally not consistent with those experienced by consumers. The
requirements of the Occupational Safety and Health Administration applicable to
this MSDS differ from the labeling requirements of the EPA and, as a result,
this MSDS may contain additional health hazard information not pertinent to
consumer use and not found on the product label.
                         HMIS Rating
                         Health       3
                         Fire         0
                         Reactivity   0
Potential Health Effects
EYE: Can cause burns with impairment of permanent loss of vision.
SKIN CONTACT: Can cause severe irritation and chemical burns.
INGESTION: Harmful and may be fatal. Can cause mucous membrane and circumoral
burns, abominal pain and discomfort, perforation of the esophagus and
gastrointestinal tract, necrosis of the stomach, respiratory distress (secondary
to epiglottal swelling, shock, and renal failure.    
INHALATION: Fumes can cause irritation with possible corrosive burns of the
upper respiratory tract, pain and coughing, difficult breathing, headache,
chemical pneumonitis, and pulmonary edema.  
SUBCHRONIC EFFECTS/CARCINOGENICITY: None known. Not classified as carcinogenic
by IARC, NTP, OSHA, ACGIH or NIOSH. 

3. COMPOSITION/INFORMATION ON INGREDIENTS
                                 CEILING EXPOSURE LIMITS(for hydrogen chloride)
Ingredient      CAS No.    % By Wt.    OSHA        ACGIH
Water           7732-18-5    80-90%    None        None      
Hydrochloric    7647-01-0    10-20%    5ppm        5ppm
Acid                                             

4. FIRST AID MEASURES
SKIN: Immediately remove contaminated clothing. Immediately flush affected areas
with a large amount of water until no evidence of product remains. Get medical 
attention if irritation develops and persist. Wash clothing before reuse. 
EYES:  Immediately flush eyes with large amounts of clean, flowing water, 
occasionally  lifting upper and lower eyelids. Flush eyes for 15 minutes or 
until no evidence of product remails. Get immediate medical attention.
INHALATION: Immediately move from area of exposure to fresh air. Get medical 
attention if person has difficulty breathing. If breathing has stopped, give 
artificial respiration and get medical attention immediately. Keep affected 
person warm and at rest. Treat symptomatically and supportively. 
INGESTION: Get immediate medical attention. Do not induce vomiting. If vomiting 
occurs, keep head below hips to prevent aspiration. Dilution by rinsing the 
mouth and giving water or milk to drink is generally  recommended. Do not 
attempt to give anything orally to an unconscious person.

5. FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES                   FLAMMABLE LIMITS
FLASHPOINT: Not Determined             LFL: Not Determined
METHOD USED: Not Applicable            UFL: Not Determined
EXTINGUISHING MEDIA: Use extinguishing media appropriate for surrounding fire. 
Use water to cool containers that can not be moved. 
FIRE-FIGHTING INSTRUCTIONS: Keep upwind and avoid breathing corrosive vapors. 
Thermal decomposition may release corrosive hydrogen chloride. Apply cooling 
water in flooding amounts and from as far a distance as possible to sides of 
containers that are exposed to flames until well after fire is out. Water should
not be used directly on material, but water spray can be used to absorb 
corrosive vapors. Wear proper full protective equipment (Bunker Gear) and a 
self-contained breathing apparatus (SCBA)  with full face piece  operated in 
positive pressure mode. 
UNUSUAL FIRE AND EXPLOSION HAZARDS: None identified.

6. ACCIDENTAL RELEASE MEASURES
Isolate spill area and deny entry to unauthorized persons. Wear proper 
protective equipment (see Section 8) to prevent exposure to the spilled 
material. Stop the source of the leak if you can do so without risk. Ventilate 
the area. Dike to contain large spills. For all spills, neutralize with soda ash
or lime. Take up with sand or other absorbent material and shovel into clean, 
dry containers. Cover containers and remove from area for later disposal as 
regulations permit (See Section 12). Flush spill area thoroughly with water. 

7. HANDLING AND STORAGE
Store in original containers away from incompatible materials (See Section 10). 
Keep containers tightly closed. Do not store in carbon steel or aluminum 
containers. Prevent exposure to material during handling by wearing  appropriate
protective equipment (See Section 8).

8. EXPOSURE CONTROLS/PERSONAL PROTECTION 
VENTILATION: Provide local exhaust ventilation to meet permissible exposure 
limits where fumes or vapors may be generated or released. 
RESPIRATORY PROTECTION: A NIOSH approved respirator with an organic vapor/acid
cartridge may be permissible under certain circumstances where airborne
concentrations are expected to exceed exposure limits, or when symptoms have
been observed that are indicative to exposure.
PROTECTIVE GLOVES: Chemical resistant gloves should be worn during occupational 
use conditions and for cleaning up spills to prevent skin contact. 
EYE PROTECTION: Splash proof, chemical resistant safety goggles should be worn 
to prevent eye contact with this product during occupational use conditions or 
when cleaning up spills. Eye wash facility is recommended for the work area or 
in close proximity.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Impervious clothing should be worn 
during occupational use conditions to prevent skin contact with this product.
PROTECTIVE WORK/HYGIENIC PRACTICES: No special requirements with respect to 
chemical exposure beyond those noted above. Specific requirements with respect 
to equipment and applications are the responsibility of the handler/user.

9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: Clear blue liquid. 
ODOR: Wintergreen odor
PHYSICAL STATE: Liquid
pH CONCENTRATE: 1.0 (approx.)
VAPOR PRESSURE: Not determined
VAPOR DENSITY: Not determined
BOILING POINT: >200F (>93C)
FREEZING POINT: Not determined
SOLUBILITY IN WATER:  Complete
SPECIFIC GRAVITY (Water=1): 1.0738 - 1.0753 @ 15 C
APPARENT DENSITY: 8.95 lbs/gal @ 15 C
%VOLATILES: Approximately 84%

10. STABILITY AND REACTIVITY
CHEMICAL STABILITY: Stable under normal temperatures and pressures.
CONDITIONS TO AVOID:  High temperature extremes and contact with incompatible 
materials. 
INCOMPATIBILITY WITH OTHER MATERIALS: Highly reactive with strong bases, metals,
metal oxides, hydroxides, mines, carbonates, and alkaline materials in general. 
Incompatible with cyanides, sulfides, sulfites , and formaldehyde. 
OTHER PRECAUTIONS: DO NOT MIX with chlorine bleach, ammonia, or other household 
cleansers or chemicals. Do not use on chrome, countertops, bathtubs, washbowls, 
or other enamel surfaces. 
HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition may release corrosive 
hydrogen chloride. 
HAZARDOUS POLYMERIZATION: Has not been reported to occur under normal 
temperatures and pressures. 

11. TOXICOLOGICAL INFORMATION
The acute health effects described below are those which could potentially occur
for the finished product. They are based on the toxicology information available
for the finished product and/or each hazardous ingredient, and are consistent 
with the product type and the likelihood of a specific route of exposure. Known 
chronic health effects related to exposure to a specific ingredient are 
indicated. 
EYE EFFECTS; May cause burns with impairment or permanent loss of vision. 
Symptoms may include pain, tearing and photophobia. 
SKIN EFFECTS; May cause irritation and chemical burns.
ACUTE ORAL EFFECTS; May cause mucous membrane and circumpolar burns, excess
drooling, difficulty in swallowing, pain upon swallowing, vomiting of blood, 
abdominal pain, perforation of the esophagus and gastrointestinal tract, 
necrosis of the stomach, respiratory distress (secondary to epiglottal 
swelling), shock, renal failure, and death.
INHALATION EFFECTS; Fumes may cause irritation with possible burns of the mucous
membranes of the upper respiratory tract, conjunctivitis, bronchitis, immediate 
pain and coughing, choking, headache, dizziness, weakness, chemical pneumonitis,
and pulmonary edema. 

12. ECOLOGICAL INFORMATION
TOXICITY: This product can be acutely toxic to aquatic animals.
PESISTENCE: This product is not expected to persist inthe environment.  
BIOACCUMULATION: This product is not expected to bioaccumulate.
Hydrochloric acid can be acutely toxic to aquatic life through reduction in
aqueous pH to toxic levels. Typically most aquatic species are intolerant ofpH
levels lower than 5.5 for any extended length of time. Reduction of pH levels
may also cause the liberation of metals such as aluminum, which will also
contribute to, exhibited toxicity.

13. DISPOSAL CONSIDERATIONS
Dispose of spilled or waste product in accordance with all local, state and 
federal environmental regulations. State and local regulations may differ from 
federal. Be sure to consult with appropriate agencies for specific rules. 

14. TRANSPORTATION INFORMATION
D.O.T. SHIPPING NAME:  CONSUMER COMMODITY
D.O.T. HAZARD CLASS: ORM-D 
UN/NA: Not Applicable

15. REGULATORY INFORMATION
The ingredients in this product are reported in the U.S. EPA TSCA Inventory 
List. 
CERCLA (40 CFR 302.4): Components present in this product at a level which could
require reporting are;
Hydrochloric Acid (hydrogen chloride) - RQ: 5000 pounds.
SARA TITLE III
Section 302, Extremely Hazardous Substances; None
Section 311/312, Hazard Category; Immediate (acute)
Section 313; Toxic chemical - This product is exempt from supplier notification.

16. OTHER INFORMATION
SUPERSEDES DATE;  07/23/08
REASON FOR REVISION; Name Change
For additional non-emergency health, safety and environmental informaton
telephone 609.279.7705 or write to:
                                   Church & Dwight Co. Inc.
                                   R & D Technical Regulatory Affairs
                                   469 North Harrison St.
                                   Princeton, NJ 08543 
This Product Safety Data Sheet is offered solely for your information, 
consideration and investigation. Church & Dwight Co. Inc. provides no 
warranties, either express or implied, and assumes no responsibility for the 
accuracy or completeness of data contained herein. Church & Dwight Co. Inc. 
urges persons receiving this information to make their own determination as to 
the information suitability for their particular application. 

The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance.

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Imperial Supplies LLC does not provide services and products outside the United States