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MSDS 85016 85016: Spruce Medium Blue 16 Oz [12]85016-8: Spruce Medium Blue 12 Pack [1] MSDS Last updated: 10/01/2008
MATERIAL SAFETY DATA SHEET
Acct. to ISO/DIS 11014
Printing date 11/12/2003 Reviewed on
10/09/2003
1. Identification of Substance
Trade Name: SPRUCE MEDIUM BLUE
Product code: 0000980035
Manufacturer/Supplier: SEYMOUR OF SYCAMORE
917 Crosby Avenue
Sycamore, IL 60178
(815)-895-9101 WWW.seymourpaint.com
Information department: Health & Safety Department
Emergency information: CHEMTEL 1-800-255-3924, 813-248-0585 if located
outside the U.S.
2. Composition/Data on components
Chemical Description: This product is a mixture of the substances listed
below
with nonhazardous additions.
Dangerous components:
67-64-1 acetone Xi, F: R 11-36-66-67 23.14%
74-98-6 Propane F+: R12 18.9%
108-88-3 toluene Xn, F: R 11-20 12.71%
64742-89-8 VM&P Naptha Xn: R 20/22 12.08%
106-97-8 n-butane F+: R 12 11.1%
64742-47-8 Mineral Spirits Xn, F: R 11-65 4.44%
13463-67-7 titanium dioxide Xi: R 37 2.86%
67-63-0 isopropyl alcohol Xi, F: R 11-36-67 2.56%
Additional information: For the wording of the listed risk phrases refer to
section 3.
3. Hazards identification
Hazard description: Xn Harmful
F+ Extremely flammable
Physical and environmental dangers:
Warning! Pressurized container.
R 12 Extremely flammable.
R 20 Harmful by inhalation.
R 36/37 Irritating to eyes and respiratory system.
Pressurized container: protect from sunlight and do not expose
to temperatures exceeding 50ºC, i.e. electric lights. Do not
pierce or burn, even after use.
Keep out of the reach of children.
NFPA ratings (scale 0 - 4): Health = 1
Fire = 4
Reactivity = 3
HMIS-ratings (scale 0 - 4): Health = 1
Fire = 4
Physical Hazard = 3
4. First aid measures
General information: Symptoms of poisoning may occur even after several
hours. Medical observation for at least 48 hours after the accident
is recommended.
After inhalation: In case of unconsciousness, place patient in side
position
for transportation. Supply fresh air. If necessary, provide
artificial respiration. Keep patient warm. Consult doctor if symptoms
persist.
After skin contact: Generally the product does not irritate the skin.
After eye contact: Rinse opened eye for several minutes under running
water.
If symptoms persist, consult a doctor.
After swallowing: Consult a doctor if symptoms persist.
5. Fire fighting measures
Extinguishing agents: CO2. sand, extinguishing powder, or spray. Fight
larger
fires with water spray or alcohol resistant foam.
Protective equipment: A respiratory protective device may be necessary when
spraying in a confined or poorly ventilated workplace to avoid overexposure.
6. Accidental release measures
Personal safety precautions: Wear protective equipment. Keep unprotected
persons away.
Environmental safety precautions: Do not allow product to reach sewage systems
or ground water. Inform appropriate authorities in case of seepage into water
course or sewage system.
Measures for cleaning/collecting: Do not flush with water or aqueous cleansing
agents. Use diluted caustic solution. Soak up spills with inert absorbent
material. Refer to section 13 for disposal information.
7. Handling and Storage
Safe handling information; Ensure good ventilation/exhaustion at the
workplace. Handle carton and cans with care.
Fire/explosion protection: Do not spray on a naked flame or any incandescent
material. Keep ignition sources away - do not smoke. Protect against
electrostatic charges.
Storage requirements: Observe official regulations on storing packaging with
pressurized containers. Consult with your local authorities. Keep away from
sources of heat and direct sunlight. Do not warehouse in subfreezing
conditions.
8. Exposure controls and personal protection:
Components with limit values that require monitoring at the workplace:
67-64-1 acetone
PEL 2400mg/m3, 1000 ppm
REL 590 mg/m3, 250 ppm
TLV Short-term value: 1782 mg/m3, 750 ppm
Long-term value: 1188 mg/m3, 500 ppm
BEI
74-98-6 propane
PEL 1800 mg/m3, 1000 ppm
REL 1800 mg/m3, 1000 ppm
TLV 4508 mg/m3, 2500 ppm
108-88-3 toluene
PEL Short-term value: C 300: 500*ppm
Long-term value: 200 ppm
*10-min peak per 8-hr shift
REL Short-term value: 560 mg/m3, 150 ppm
Long-term value: 375 mg/m3, 100 ppm
TLV 188 mg/m3, 50 ppm
Skin: BEI
106-97-8 n-butane
REL 1900 mg/m3, 800 ppm
TLV 1900 mg/m3, 800 ppm
67-63-0 isopropyl alcohol
PEL 980 mg/m3, 400 ppm
REL Short-term value: 1225 mg/m3, 500 ppm
Long-term value: 980 mg/m3, 400 ppm
TLV Short-term value: (1230) mg/m3, (500) ppm
Long-term value: (983) mg/m3, (400) ppm
NIC-200: 491: 400: 984: A4
Protective hygienic measures: Keep away from foodstuffs, beverages, and
animal
feed. Immediately remove all soiled and contaminated clothing. Wash hands before
breaks and at the end of work. Breathing equipment: A respirator is generally
not necessary when using this product outdoors or in large open area. In cases
of inadequate ventilation,a respiratory protective device should be worn to
avoid over-exposure.
Protection of hands: Protective gloves. The glove material has to be
impermeable and resistant to the substance. No glove recommendation can be
given.
Eye protection: Tightly sealed goggles.
9. Physical and chemical properties.
General Information:
Form: Aerosol
Color: According to trade name description in Section 1.
Odor: Solvent
Boiling point/Boiling range: -44ºC (-47ºF)
Flash Point: -19ºC (-2ºF)
Ignition temperature: 365.0ºC (689ºF)
Auto igniting: Product is not self-igniting.
Danger of explosion: Heating may cause an explosion.
In use, may form flammable/explosive vapor-air
mixture.
Lower Explosion Limit: 0.9 Vol%
Upper Explosion Limit: 13.0 Vol%
Vapor pressure at 20ºC (68ºF): 8300.0 hPa (6226 mm Hg)
Density: Not determined
Specific Gravity: Between 0.77 and 0.90 (Water equals 1.00)
VOC content: 0.62 kg/l / 5.21 lb/gl
VOC in weight percent (less acetone): 62.5%
Solids content: 14.5%
10. Stability and reactivity:
Conditions to be avoided: Do not allow the can to exceed 120 degrees
Fahrenheit.
Stable at normal temperatures.
Possibility of Hazardous Reactions: No dangerous reactions known.
11. Toxicological Information
Primary effect on the skin; No irritant effect.
Primary effect on the eye: Irritating effect.
Sensitization: No sensitizing effects known.
Additional toxicological information: Harmful
12. Ecological information
Other information: This product does not contain any chlorinated solvents
or lead. No specific ecological data is available for this product.
Aquatic toxicity; Harmful to aquatic organisms. Hazardous for water, do
not
empty into drains.
13. Disposal considerations
DISPOSAL METHOD: Dispose of in accordance with local, state, and federal
regulations. Do not puncture, incinerate, or compact. Empty containers must be
handled with care due to product residue. Do not heat or cut empty containers
with electric or gas torches .
Recommendation: Do not dispose with household garbage. Do not allow product
to reach sewage system.
14. Transport information:
Hazard class: 2.1
Identification number: N/A
Label 2.1
ADR/RID Class: 2 5F Gases
UN-Number: 1950
IMDG Class: 2.1
Packaging group: II
EMS Number: F-D-,S-U
Marine pollutant: No
ICAO/IATA Class; 2.1
Proper shipping name: Aerosols, Flammable
Consumer Commodity ORM-D
15. Regulations
SARA Section 355 (extremely hazardous substances):
None of the ingredients in this product are listed.
SARA Section 313 (Specific toxic chemical listings):
108-88-3 toluene
67-63-0 isopropyl alcohol
1330-20-7 xylene (mix)
TSCA (Toxic Substances Control Act):
67-64-1 acetone
74-98-6 propane
108-88-3 toluene
64742-89-8 VM&P Naptha
106-97-8 n-butane
71243-64-6 V.T. Alkyd Resin
64742-47-8 Mineral Spirits
13463-67-7 titanium dioxide
67-63-0 isopropyl alcohol
108-65-6 PM acetate
147-14-8 Copper Phthalocyanine
1330-20-7 xylene (mix)
PROPOSITION 65 Chemicals known to cause cancer:
None of the ingredients in this product are listed.
PROPOSITION 65 Chemicals known to cause reproductive toxicity:
108-88-3 toluene
Canadian WHMIS: This product has been classified according to the Controlled
Product Regulations and the MSDS contains all the necessary information required
by the CPR. Class B, D5 --- Flammable Aerosols.
EPA; A = Known human carcinogen
B = Probable human carcinogen
C = Possible human carcinogen
D = Not classifiable as to human carcinogenicity: Inadequate human
and animal evidence of carcinogenicity (or no data is
available).
67-64-1 acetone D
108-88-3 toluene D
1330-20-7 xylene (mix) D
110-19-0 isobutyl acetate D
100-41-4 ethyl benzene D
IARC: Group 2B: The ingredient is possibly carcinogenic to humans.
There
is limited evidence of carcinogenictity.
Group 3: The ingredient is unclassifiable as to its
carcinogenicity
to humans.
108-88-3 toluene 3
13463-67-7 titanium dioxide 3
67-63-0 isopropyl alcohol 3
1330-20-7 xylene (mix) 3
ACGIH TLVs: A 1-designates a confirmed human carcinogen.
A 2-designates a suspected human carcinogen.
A 3-designates an animal carcinogen.
A 4-designates "not classifiable as a human carcinogen".
67-64-1 acetone A4
108-88-3 toluene A4
13463-67-7 titanium dioxide A4
1330-20-7 xylene (mix) A4
110-19-0 isobutyl acetate A4
NIOSH:
13463-67-7 titanium dioxide
USDA (United States Department of Agriculture): This product was manufactured
to conform to the USDA Food Safety and Inspection Service performance
standards.
These standards include, but are not limited to, the ability of this
product to be safe for use in official meat and poultry establishments,
and to perform well under a daily regimen of thorough cleaning,
cyclical temperature change, and wet conditions.
16. Other information
This information is based on our present knowledge. However, this shall not
constitute a guarantee for any specific product features and shall not establish
a legally valid contractual relationship.
Contact: Craig Swafford
Regulatory Affairs
The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance. For more product information by email, click here Imperial Supplies LLC does not provide services and products outside the United States |
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