MSDS Sheet 85013

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MATERIAL SAFETY DATA SHEET SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION **** DRAFT COPY - FOR EVALUATION USE ONLY **** PRODUCT NAME: ALLIED GREEN IDENTIFICATION NUMBER: IM00085007 DATE PRINTED: 02/22/08 PRODUCT USE/CLASS: SUPPLIER: MANUFACTURER: IMPERIAL SUPPLIES LLC IMPERIAL SUPPLIES LLC 789 ARMED FORCES DRIVE 789 ARMED FORCES DRIVE GREEN BAY, WI. 54304 GREEN BAY, WI. 54304 INFORMATION NUMBER: EMERGENCY NUMBER: 800-558-2808 800-255-3924 CHEM-TEL PREPARER: Rich, PHONE: PREPARE DATE: 02/22/08 SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS WT/WT % ITEM CHEMICAL NAME CAS NUMBER EQUAL TO 01 Acetone 00067-64-1 20.90 % 02 Propane 00074-98-6 15.80 % 03 N-Butane 00106-97-8 9.30 % 04 Barium Sulfate 07727-43-7 8.80 % 05 Glycol Ether EP 02807-30-9 5.60 % 06 Methyl Isobutyl Ketone 00108-10-1 5.40 % 07 Methyl Propyl Ketone 00107-87-9 3.30 % 08 Xylene 01330-20-7 2.60 % 09 Titanium Dioxide 13463-67-7 2.30 % 10 Isobutyl Acetate 00110-19-0 2.20 % 11 PM Acetate 00108-65-6 1.30 % EXPOSURE LIMITS ACGIH OSHA COMPANY ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN 01 500 ppm 750 ppm 750 ppm 1000 ppm N.E. YES 02 1000 ppm N.E. 1000 ppm N.E. N.E. NO 03 800 ppm N.E. 800 ppm N.E. N.E. NO 04 N.E. N.E. N.E. N.E. N.E. NO 05 25 ppm N.E. 25 ppm N.E. N.E. YES 06 50 ppm 75 ppm 50 ppm 75 ppm N.E. YES 07 200 ppm 250 ppm 200 ppm 250 ppm N.E. NO 08 100 ppm 150 ppm 100 ppm 150 ppm N.E. YES 09 5 mg/m3 N.E. 5 mg/m3 N.E. N.E. NO 10 150 ppm N.E. 150 ppm N.E. N.E. YES 11. N.E. N.E. N.E. N.E. N.E. NO (See Section 16 for abbreviation legend) SECTION 3 - HAZARDS IDENTIFICATION *** EMERGENCY OVERVIEW ***: Contents under pressure! Avoid temperatures over 120 F. EFFECTS OF OVEREXPOSURE - EYE CONTACT: Liquid, aerosols and vapors of this product are irritating and can cause pain, tearing, reddening and swelling accompanied by s stinging sensation and/or a feeling like that of fine dust in the eyes. EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Causes skin irritation. Allergic reactions are possible. Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash). EFFECTS OF OVEREXPOSURE - INHALATION: Headaches, dizziness, nausea, decreased blood pressure, changes in heart rate and cyanosis may result from over-exposure to vapor or skin exposure. Prolonged inhalation may be harmful. EFFECTS OF OVEREXPOSURE - INGESTION: This material may be harmful or fatal if swallowed. Irritating to mouth, throat and stomach. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Possible reproductive hazard. PRIMARY ROUTE (S) OF ENTRY: SKIN CONTACT SKIN ABSORPTION INHALATION INGESTION EYE CONTACT SECTION 4 - FIRST AID MEASURES FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water. Get medical attention, if irritation persists. FIRST AID - SKIN CONTACT: Wash with soap and water. Get medical attention if irritation develops or persists. Remove contaminated clothing. Wash skin with soap and water. Get medical attention if irritation develops or persists. FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. FIRST AID - INGESTION: If swallowed, do NOT induce vomiting. Give victim a glass of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. If swallowed, induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. SECTION 5 - FIRE FIGHTING MEASURES FLASH POINT: -4 F LOWER EXPLOSIVE LIMIT: 1.0 % (PENSKY-MARTENS C.C.) UPPER EXPLOSIVE LIMIT: 12.8 % AUTO IGNITION TEMPERATURE: EXTINGUISHING MEDIA: ALCOHOL FOAM CO2 DRY CHEMICAL FOAM WATER FOG UNUSUAL FIRE AND EXPLOSION HAZARDS: Vapors may form explosive mixture with air. Flammability classification, as defined by 29 CFR 1910.1200: Flammable SPECIAL FIREFIGHTING PROCEDURES: Containers can build up pressure if exposed to heat (fire). As in any fire, wear self-contained breathing apparatus pressure- demand (MSHA/NIOSH approved or equivalent) and full protective gear. SECTION 6 - ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Absorb spill with inert Material (e.g. dry sand or earth) then place in a chemical waste container. SECTION 7 - HANDLING AND STORAGE HANDLING: Wash thoroughly after handling. Use with adequate ventilation. Avoid breathing vapors or mist. Avoid contact with eyes, skin, and clothing. STORAGE: Keep away from heat, sparks and flame. Contents under pressure. Do not store above 120F. SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: Local exhaust ventilation may be necessary to control any air contaminants to within their TLVs during the use of this product. RESPIRATORY PROTECTION: A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. SKIN PROTECTION: Skin contact should be minimized. Rubber or neoprene gloves should be worn for prolonged or repeated contact. EYE PROTECTION: Wear safety glasses with side shields (or goggles) and a face shield. OTHER PROTECTIVE EQUIPMENT: Where splashing is possible, full chemically resistant protective clothing (e.g. acid suit) and boots are required. HYGIENIC PRACTICES: No Information. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES BOILING RANGE: -44 - 308 F VAPOR DENSITY: Is heavier than air ODOR: Mild Solvent ODOR THRESHOLD: APPEARANCE: Color EVAPORATION RATE: Is faster than Ether SOLUBILITY IN H2O: Nonmisible FREEZE POINT: SPECIFIC GRAVITY: 0.8385 VAPOR PRESSURE: Ph @ 0.0 %: PHYSICAL STATE: VISCOSITY: COEFFICIENT OR WATER/OIL DISTRIBUTION: SECTION 10 - STABILITY AND REACTIVITY CONDITIONS TO AVOID: Do not store above 120 deg. F. Keep away from sparks, pilot lights, and/or open flames. INCOMPATIBILITY: No information. HAZARDOUS DECOMPOSITION PRODUCTS: May produce hazardous fumes when heated To decomposition. Fumes may contain carbon dioxide and/or carbon monoxide. HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. STABILITY: This product is stable under normal storage conditions. SECTION 11 - TOXICOLOGICAL PROPERTIES SECTION 12 - ECOLOGICAL INFORMATION ECOLOGICAL INFORMATION: This product does not contain chlorinated solvents or lead. No specific ecological data is available for this product. Please refer to section 6 for information regarding accidental releases and section 15 for regulatory reporting. SECTION 13 - DISPOSAL CONSIDERATIONS DISPOSAL METHOD: Dispose of in accordance with local, state, and federal regulations. Do not puncture, incinerate, or compact. Empty containers must be handled with care due to product residue. Do not heat or cut empty containers with electric or gas torches. SECTION 14 - TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME: Consumer Commodity ORM-D. DOT TECHNICAL NAME: None DOT HAZARD CLASS: None HAZARD SUBCLASS: None DOT UN/NA NUMBER: None PACKING GROUP: None RESP. GUIDE PAGE: None SECTION 15 - REGULATORY INFORMATION U.S. FEDERAL REGULATIONS: AS FOLLOWS - OSHA: Hazardous by definition of hazard communication standard (29 CFR 1910.1200) CERCLA - SARA HAZARD CATEGORY: This product has been reviewed according to the EPA 'Hazard Categories' promulgated Under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: IMMEDIATE HEALTH HAZARD CHRONIC HEALTH HAZARD FIRE HAZARD PRESSURIZED GAS HAZARD SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: CHEMICAL NAME CAS NUMBER WT/WT % Glycol Ether EP 02807-30-9 5.60 % Methyl Isobutyl Ketone 00108-10-1 5.40 % Xylene 01330-20-7 2.60 % Ethyl Benzene 00100-41-4 0.50 % Trimethyl benzene 25551-13-7 0.00 % Methanol 00067-56-1 0.01 % U.S. STATE REGULATIONS: AS FOLLOWS - NEW JERSEY RIGHT-TO-KNOW: The following materials are non-hazardous, but are among the top five components in this product: CHEMICAL NAME CAS NUMBER Soya Alkyd Resin NA PENNSYLVANIA RIGHT-TO-KNOW: The following non-hazardous ingredients are present in the product at greater than 3%: CHEMICAL NAME CAS NUMBER Soya Alkyd Resin NA CALIFORNIA PROPOSITION 65: WARNING: The chemical(s) noted below and contained in this product, are known to the state of California to cause cancer or birth defects and other reproductive harm: CHEMICAL NAME CAS NUMBER No Proposition 65 chemicals exist in this product. INTERNATIONAL REGULATIONS: AS FOLLOWS - CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings. CANADIAN WHMIS CLASS: No information available. SECTION 16 - OTHER INFORMATION HMIS RATINGS - HEALTH: 1 FLAMMABILITY: 4 REACTIVITY: 3 PREVIOUS MSDS REVISION DATE: 02/22/08 LEGEND: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined This product was manufactured to conform to the USDA Food Safety and Inspection Service performance standards. These standards include, but are not limited to the ability of this product to be safe for use in official meat and poultry establishments, and to perform well under a daily regimen of thorough cleaning, cyclical temperature change, and wet conditions. The dried film of this product will neither adulterate food product nor create unsanitary conditions if used according to directions. The information contained on this MSDS has been checked and should be accurate. However, it is the responsibility of the user to comply with all Federal, State, and Local laws and regulations. <END OF MSDS>