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MSDS 85006

85006: Ecosafe Gloss Green 20 Oz [6]
85006-9: Ecosafe Gloss Green 6 Pack [1]
MSDS Last updated: 10/01/2008
                            MATERIAL SAFETY DATA SHEET
                              Acc. To ISO/DIS 11014

Printing date 01/27/2004                                                        

Reviewed on 01/06/2004
 

                         1.  IDENTIFICATION OF SUBSTANCE


Trade Name:                   MRO SAFETY GREEN
Product code;                 0006201452
Manufacturer/Supplier:        SEYMOUR OF SYCAMORE
                              917 Crosby Avenue
                              Sycamore, IL 60178
                              (815)-895-9101, www.seymourpaint.com 
Information department:       Health & Safety Department
Emergency information:        CHEMTEL  1-800-255-3924, 813-248-0585 if located 
                              outside the U.S. 


                               2.  COMPOSITION DATA


Chemical Description:    This product is a mixture of the substances listed 
                         below with nonhazardous additions.

Dangerous components:
--------------------------------------------------------------------------------
67-64-1            acetone          Xi, F: R 11-36-66-67             19.52%
74-98-6            propane          F+: R12                          15.73%
106-97-8           n-butane         F+: R12                          9.24%
7727-43-7          barium sulphate, natural  Xi: R37                 8.23%
2807-30-9          Glycol Ether EP  Xi: R 10-36/37/38                5.27%
108-10-1           methyl isobutyl ketone  Xn, F: R 11-20-36/37-66   5.1%
13463-67-7         titanium dioxide Xi: R 37                         3.89%
107-87-9           Methyl Propyl Ketone F; R 11                      3.31%
110-19-0           isobutyl acetate F: R 11-66                       2.65%
1330-20-7          xylene (mix)     Xn: R 10-20/21-38                2.48%
108-65-6           PM acetate       Xi: R 10-36                      1.44%

Additional information;  For the wording of the listed risk phrases refer to 
section 3.

 
                            3.  HAZARDS IDENTIFICATION


Hazard description:            Xi   Irritant
                               F+   Extremely flammable

Physical and
Environmental dangers:  Warning!  Pressurized container. Has a narcotizing 
                        effect.      
                        R 12  Extremely flammable.
                        R 36/37 Irritating to eyes and respiratory system.
                        R 67  Vapors may cause drowsiness and dizziness
                        Pressurized container: protect from sunlight and do not 
                        expose to temperatures exceeding 50°C, i.e. electric    

                        lights. Do not pierce or burn, even after use. Keep out 
                        of the reach of children. 

NFPA ratings (scale 0 – 4):    Health = 1
                               Fire = 4
                               Reactivity = 3

HMIS-ratings (scale 0 – 4);    Health = 1
                               Fire = 4
                               Physical Hazard = 3

 
                              4.  FIRST AID MEASURES


After inhalation:     Supply fresh air: consult doctor in case of complaints. 
After skin contact:   Generally the product does not irritate the skin.
After eye contact;    Rinse opened eye for several minutes under running 
                      water. If symptoms persist, consult a doctor.
After swallowing:     Consult a doctor if symptoms persist. 

 
                            5.  FIRE FIGHTING MEASURES


Extinguishing agents:  CO2, sand, extinguishing powder, or water spray. Fight   

                       larger fires with water spray or alcohol resistant foam. 

Protective equipment:  No special measures required. 

 
                         6.  ACCIDENTAL RELEASE MEASURES


Personal safety
precautions:       Wear protective equipment. Keep unprotected persons away.

Environmental safety
precautions;       Do not allow product to reach sewage systems or ground water.
                   Inform appropriate authorities in case of seepage into water 

                   course or sewage system.  

Measures for cleaning/
Collecting:        Do not flush with water or aqueous cleansing agents. Use     

                   diluted caustic solution. Soak up spills with inert absorbent

                   material. Refer to section 13 for disposal information. 

 
                             7.  HANDLING AND STORAGE


Safe handling
information:     Ensure good ventilation/exhaustion at the workplace.
                 Handle carton and cans with care. Avoid dropping.

Fire/explosion 
protection;      Do not spray on a naked flame or any incandescent
                 material. Keep ignition sources away – Do not smoke.
                 Protect against electrostatic charges. 

Storage 
requirements:    Observe official regulations on storing packaging with
                 pressurized containers. Consult with your local authorities. 
                 Keep away from sources of heat and direct sunlight. Do not 
                 warehouse in subfreezing conditions. 

 
                    8.  EXPOSURE CONTROLS/PERSONAL PROTECTION


Components with limit value that require monitoring at the workplace;

67-64-1     acetone
PEL                 2400 mg/m3, 1000 ppm
REL                 590 mg/m3, 250 ppm
TLV                 Short-term value; 1782 mg/m3, 750 ppm
                    Long-term value; 1188 mg/m3, 500 ppm
                    BEI
74-98-6     propane
PEL                 1800 mg/m3, 1000 ppm
REL                 1800 mg/m3, 1000 ppm
TLV                 (4508) mg/m3, (2500) ppm
106-97-8    n-butane
REL                 1900 mg/m3, 800 ppm
TLV                 1900 mg/m3, 800 ppm
7727-43-7   barium sulphate, natural
PEL                 15*, 5** mg/m3
                    *Total dust ** Respirable fraction
REL                 10*, 5** mg/m3
                    *Total dust ** Respirable fraction
TLV                 10 mg/m3
                    (e)
108-10-1    methyl isobutyl ketone
PEL                 410 mg/m3, 100 ppm
REL                 Short-term value: 300 mg/m3, 75 ppm
                    Long-term value; 205 mg/m3, 50 ppm
TLV                 Short-term value; 307 mg/m3, 75 ppm
                    Long-term value; 205 mg/m3, 50 ppm
                    BEI
107-87-9    Methyl Propyl Ketone
PEL                 700 mg/m3, 200 ppm
REL                 530 mg/m3, 150 ppm
TLV                 Short-term value; 881 mg/m3, 250 ppm
                    Long-term value; 705 mg/m3, 200 ppm
110-19-0    isobutyl acetate
PEL                 700 mg/m3, 150 ppm
REL                 700 mg/m3, 150 ppm
TLV                 713 mg/m3, 150 ppm
1330-20-7   xylene (mix)
PEL                 435 mg/m3, 100 ppm
REL                 Short-term value; 655 mg/m3, 150 ppm
                    Long-term value; 435 mg/m3, 100 ppm
                    (o-, m-, & p-isomers)
TLV                 Short-term value; 651 mg/m3, 150 ppm
                    Long-term value; 434 mg/m3, 100 ppm
                    BEI

Protective hygienic
measures;            Keep away from foodstuffs, beverages, and animal feed.
                     Immediately remove all soiled and contaminated clothing.
                     Wash hands before breaks and at the end of work. 
Breathing
equipment;           A respirator is generally not necessary when using this    

                     product outdoors or in large open areas. In cases of 
                     inadequate ventilation, a respiratory protective device 
                     should be worn to prevent overexposure.
                     Use suitable respiratory protective device in case of 
                     insufficient ventilation. 

Protection 
of hands;            Protective gloves. The glove material has to be impermeable

                     and resistant to the substance. No glove recommendation can

                     be given.

Eye protection;      Tightly sealed goggles. 

 
                       9.  PHYSICAL AND CHEMICAL PROPERTIES


General Information;

Form;                   Aerosol
Color;                  According to trade name description in section 1.
Odor;                   Solvent
Boiling point/
Boiling range:          -44°C (-47°F)
Flash Point:            -19°C (-2°F)
Ignition temperature;   230.0°C (446°F)
Auto igniting;          Product is not self-igniting. 
Danger of explosion;    Heating may cause an explosion.
                        In use, may form flammable/explosive vapor-air mixture.
Lower Explosion
Limit:                  1.7 Vol %
Upper Explosion
Limit:                  13.0 Vol %
Vapor Pressure:         40 PSI, 2750 hPa 
Density;                Not determined.
Specific Gravity;       Between 0.77 and 0.90 (Water equals 1.00)
VOC content:            0.46 kg/l / 3.87 lb/gl
VOC in weight percent
(less acetone):         46.3 %
Solids content:         34.0 %
 

                          10.  STABILITY AND REACTIVITY


Conditions to be 
avoided;             Do not allow the can to exceed 120 degrees Fahrenheit. 
                     Stable at normal temperatures. 

Possibility of 
Hazardous Reactions: No dangerous reactions known. 

 
                          11.  TOXICOLOGICAL INFORMATION


Primary effect on the skin:   No irritant effect.
Primary effect on the eye:    Irritating effect.
Sensitization;                No sensitizing effects known. 

 
                           12.  ECOLOGICAL INFORMATION


Other information:       This product does not contain any chlorinated solvents
                         to lead. No specific ecological data is available for 
                         this product. 

 
                           13.  DISPOSAL CONSIDERATIONS


DISPOSAL METHOD; Dispose of in accordance with local, state, and federal 
regulations. Do not puncture, incinerate, or compact. Partially empty cans 
cannot be disposed of with regular trash. Do not heat or cut empty containers 
with electric or gas torches. 

Recommendation;       Empty cans should be recycled. 

 

14.  TRANSPORT INFORMATION      

Hazard class:              2.1
Identification number;     N/A
Label                      2.1     
ADR/RID class:             2  5TF Gases
UN-Number:                 1950
IMDG Class;                2
Packaging group;           II
EMS Number:                F-D-,S-U 
Marine pollutant;          No
ICAO/IATA class;           2.1
Proper shipping name;      Aerosols, Flammable
                           Consumer Commodity ORM-D


                                 15.  REGULATIONS


SARA Section 355 (extremely hazardous substances):
None of the ingredients in this product are listed.

SARA Section 313 (Specific toxic chemical listings):
108-10-1               methyl isobutyl ketone
1330-20-7              xylene (mix)
100-41-4               ethyl benzene

TSCA  (Toxic Substances Control Act):
67-64-1                acetone
74-98-6                propane
106-97-8               n-butane
7727-43-7              barium sulphate, natural
2807-30-9              Glycol Ether EP
108-10-1               methyl isobutyl ketone
13463-67-7             titanium dioxide
107-87-9               Methyl Propyl Ketone
110-19-0               isobutyl acetate
1330-20-7              xylene (mix)
108-65-6               PM acetate
51274-00-1             Yellow Iron Oxide
1328-53-6              Phthalocyanine Green 7
100-41-4               ethyl benzene
8002-43-5              Soya Lecithin

PROPOSITION 65 Chemicals known to cause cancer;
None of the ingredients in this product are listed. 

PROPOSITION 65 Chemicals known to cause reproductive toxicity: 
None of the ingredients in this product are listed. 

Canadian WHMIS:    This product has been classified according to the Controlled
                   Product Regulations and the MSDS contains all the necessary
                   information required by the CPR.
                   Class B,D5---Flammable Aerolols
EPA;               A=Known human carcinogen                    
                   B=Probable human carcinogen
                   C=Possible human carcinogen
                   D=Not classifiable as to human carcinogenicity; Inadequate
                     human and animal evidence of  carcinogenicity (or no data 
                     is available)

67-64-1            acetone            D
110-19-0           isobutyl acetate   D
1330-20-7          xylene (mix)       D
100-41-4           ethyl benzene      D

IARC:              Group 2B: The ingredient is possible carcinogenic to humans. 
                             There is limited evidence of carcinogenicity. 
                   Group 3:  The ingredient is unclassifiable as to its 
                             carcinogenicity to humans. 

13463-67-7         titanium dioxide   3
1330-20-7          xylene (mix)       3

ACGIH TLV’s        A1 – designates a confirmed human carcinogen.
                   A2 – designates a suspected human carcinogen. 
                   A3 – designates an animal carcinogen. 
                   A4 – designates “not classifiable as a human carcinogen”.

67-64-1            acetone           A4
13463-67-7         titanium dioxide  A4
110-19-0           isobutyl acetate  A4
1330-20-7          xylene (mix)      A4

NIOSH:

13463-67-7         titanium dioxide


                              16. OTHER INFORMATION


This information is based on our present knowledge. However, this shall not 
constitute a guarantee for any specific product features and shall not establish

a legally valid contractual relationship. 

Contact; Craig Swafford, Regulatory affairs. 
         Email; cswafford@seymourpaint.com 

                                    

The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance.

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Imperial Supplies LLC does not provide services and products outside the United States

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