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MSDS 85002

85002: Ecosafe Gloss White 20 Oz [6]
85002-9: Ecosafe Gloss White 6 Pack [1]
MSDS Last updated: 02/26/2008

85002
02 00           MATERIAL SAFETY DATA SHEET

SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NUMBER            DATE OF PREPARATION         HMIS CODES
85002                       25-FEB-08               Health         2*
                                                    Flammability   3
                                                    Reactivity     0

PRODUCT NAME
      ECOSAFE® Enamel, Gloss White

MANUFACTURER'S NAME
      MFg. for:  IMPERIAL SUPPLIES LLC
      P.O. Box   11008
      Green Bay, WI 54307-1008

TELEPHONE NUMBERS AND WEBSITES
      Product Information
      (800) 558-2808
      Regulatory Information
      (216) 566-2902
      Medical Emergency
      (216) 566-2917
      Transportation Emergency    for Chemical Emergency ONLY (spill, leak,
      (800) 424-9300              fire, exposure, or accident)

SECTION 2 - COMPOSITION/INFORMAITON ON INGREDIENTS
% By WT     CAS No.       INGREDIENT      UNITS       VAPOR PRESSURE
14         74-98-6        Propane
                              ACGIH TLV   2500 ppm         760 mm
                              OSHA PEL    1000 ppm
13         106-97-8       Butane
                              ACGIH TLV   800  ppm         760 mm
                              OSHA  PEL   800  ppm
7          108-88-3       Toluene
                              ACGIH TLV     20 ppm          22 mm
                              OSHA  PEL    100 ppm  (Skin)
                              OSHA  PEL    150 ppm  (Skin) STEL
0.5        100-41-4       Ethyl benzene
                              ACGIH TLV    100 ppm         7.1 mm
                              ACGIH TLV    125 ppm  STEL
                              OSHA  PEL    100 ppm
                              OSHA  PEL    125 ppm  STEL
3          1330-20-7      Xylene
                              ACGIH TLV    100 ppm         5.9 mm
                              ACGIH TLV    150 ppm  STEL
                              OSHA  PEL    100 ppm
                              OSHA  PEL    150 ppm  STEL
20         67-64-1        Acetone
                              ACGIH TLV    500 ppm         180 mm
                              ACGIH TLV    750 ppm  STEL
                              OSHA  PEL   1000 ppm
3          763-69-9       Ethyl 3-Ethoxypropionate
                              ACGIH TLV  Not Available    1.11 mm
                              OSHA  PEL  Not Available
4          123-86-4       n-Butyl Acetate
                              ACGIH TLV     150 ppm         10 mm
                              ACGIH TLV     200 ppm STEL
                              OSHA  PEL     150 ppm
                              OSHA  PEL     200 ppm STEL
2          110-19-0       Isobutyl Acetate
                              ACGIH TLV     150 ppm       12.5 mm
                              OSHA  PEL     150 ppm
17         13463-67-7     Titanium Dioxide
                              ACGIH TLV     10 mg/m3 as Dust
                              OSHA  PEL     10 mg/m3 Total Dust
                              OSHA  PEL      5 mg/m3 Respirable Fraction

SECTION 3 - HAZARDS IDENTIFICATION
ROUTES OF EXPOSURE
      INHALATION of vapor or spray mist.
      EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
      EYES: Irritation.
      SKIN: Prolonged or repeated exposure may cause irritation.
      INHALATION: Irritation of the upper respiratory system.
      May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
      Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver, urinary, blood forming, cardiovascular and 
reproductive systems.

SIGNS AND SYMPTOMS OF OVEREXPOSURE
      Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
      Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
      None generally recognized.
CANCER INFORMATION
      For complete discussion of toxicology data refer to Section 11.

SECTION 4 - FIRST AID MEASURES
      EYES: Flush eyes with large amounts of water for 15 minutes. Get medical
      attention.
      SKIN: Wash affected area thoroughly with soap and water.
      Remove contaminated clothing and launder before re-use.
      INHALATION: If affected, remove from exposure. Restore breathing.
      Keep warm and quite.
      INGESTION: Do not induce vomiting.  Get medical attention immediately.


SECTION 5 - FIRE FIGHTING MEASURES
FLASH POINT                  LEL        UEL
      Propellant < 0 F       1.0        12.8
EXTINGUISHING MEDIA
      Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
      Containers may explode when exposed to extreme heat.
      Application to hot surfaces requires special precautions.
      During emergency conditions overexposure to decomposition products may
      cause a health hazard. Symptoms may not be immediately apparent.
      Obtain medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
      Full protective equipment including self-contained breathing apparatus
      should be used.
      Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent pressure
build-up and possible auto ignition or explosion when exposed to extreme heat.

SECTION 6 - ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
      Remove all sources of ignition. Ventilate the area.
      Remove with inert absorbent.

SECTION 7 - HANDLING AND STORAGE
STORAGE CATEGORY
      Not Available
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
      Keep away from heat, sparks, and open flame. Vapors will accumulate
readily and may ignite explosively.
      During use and until all vapors are gone: Keep area ventilated - Do not
smoke - Extinguish all flames, pilot lights, and heaters -Turn off stoves,
electric tools and appliances, and any other sources of ignition.
      Consult NFPA Code. Use approved Bonding and Grounding procedures.
      Contents under pressure. Do not puncture, incinerate, or expose to
temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and
other heat sources could cause  container to burst. Do not take internally. Keep
out of the reach of children.

SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
PRECAUTIONS TO BE TAKEN IN USE
      Use only with adequate ventilation.
      Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
      Wash hands after using.
      This coating may contain materials classified as nuisance particulates
      (listed "as Dust" in Section 2) which may be present at hazardous levels
      only during sanding or abrading of the dried film. If no specific dusts   
   are listed in Section 2, the applicable limits for nuisance dusts are      
ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL      
15 mg/m3 (total dust), 5 mg/m3 (respirable Fraction).
VENTILATION
      Local exhaust preferable. General exhaust acceptable if the exposure to
      materials in Section 2 is maintained below applicable exposure limits.
      Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
      If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
      When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
      None required for normal application of aerosol products where minimal
skin contact is expected. For long or repeated contact, wear chemical resistant
gloves.
EYE PROTECTION
      Wear safety spectacles with unperforated side shields.
OTHER PRECAUTIONS
      Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.

SECTION 9 - PHYSICAL AND CHEMICL PROPERTIES
PRODUCT WEIGHT         7.15 lb/gal      856 g/l
SPECIFIC GRAVITY       0.86
BOILING POINT          <0 - 342 F       <-18 - 172 C
MELTING POINT          Not Available
VOLATILE VOLUME        85 %
EVAPORATION RATE       Faster than ether
VAPOR DENSITY          Heavier than air
SOLUBILITY IN WATER    N.A.
Ph                     7.0
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)
      Volatile Weight 47.49%  Less Water and Federally Exempt Solvents

SECTION 10 - STABILITY AND REACTIVITY
STABILITY - Stable
CONDITIONS TO AVOID
      None known.
INCOMPATIBILITY
      None known.
HAZARDOUS DECOMPOSITION PRODUCTS
      By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
      Will not occur

SECTION 11 - TOXICOLOGICAL INFORMATION
CHRONIC HEALTH HAZARDS
      Reports have associated repeated and prolonged overexposure to solvents
      with permanent brain and nervous system damage.
      Ethyl benzene is classified by IARC as possible carcinogenic to humans
(2B) based on inadequate evidence in humans and sufficient evidence in
laboratory animals. Lifetime inhalation exposure of rats and mice to high ethyl
benzene concentrations resulted in increases in certain types of cancer,
including kidney tumors in rats and lung and liver tumors in mice.  These
effects were not observed in animals exposed to lower concentrations.  There is
no evidence that ethyl benzene causes cancer in humans.
      IARC's Monograph No. 93 reports there is sufficient evidence of
carcinogenicity in Experimental rats exposed to titanium dioxide but in adequate
evidence for Carcinogenicity in humans and has assigned a Group 2B rating. In
addition, the IARC summary concludes, "No significant exposure to titanium
dioxide is thought to occur during the use of products in which titanium is
bound to other materials, such as paint".
TOXICOLOGY DATA
      CAS No.     Ingredient Name
      74-98-6     Propane
                                LC50 RAT   4Hr  Not Available
                                LD50 RAT        Not Available
      106-97-8    Butane
                                LC50 RAT   4HR  Not Available
                                LD50 RAT        Not Available
      108-88-3    Toluene
                                LC50 RAT   4HR  4000  ppm
                                LD50 RAT        5000  mg/kg
      100-41-4    Ethyl benzene
                                LC50 RAT   4HR  Not Available
                                LD50 RAT        3500  mg/kg
      1330-20-7   Xylene
                                LC50 RAT   4HR  5000  ppm
                                LD50 RAT        4300  mg/kg
      67-64-1     Acetone
                                LC50 RAT   4HR  Not Available
                                LD50 RAT        5800  mg/kg
      763-69-9    Ethyl 3-Ethoxypropionate
                                LC50 RAT   4HR  Not Available
                                LD50 RAT        5000 mg/kg
      123-86-4    n-Butyl Acetate
                                LC50 RAT   4HR   2000 ppm
                                LD50 RAT        13100 mg/kg
      110-19-0    Isobutyl Acetate
                                LC50 RAT   4HR   Not Available
                                LD50 RAT        13400 mg/kg
      13463-67-7  Titanium Dioxide
                                LC50 RAT   4HR   Not Available
                                LD50 RAT         Not Available


SECTION 12 - ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
       No data available.


SECTION 13 - DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD
      Waste from this product may be hazardous as defined under the
      Resource Conservation and Recovery Act (RCRA) 40 CFR 261.
      Waste must be tested for ignitability to determine the applicable
      EPA hazardous waste numbers.
      Do not incinerate. Depressurize container. Dispose of in accordance
      with Federal, State/Provincial, and local regulations regarding pollution.



SECTION 14 - TRANSPORT INFORMATION
US GROUND  (DOT)
       May be classed as Consumer Commodity, ORM-D
       UN1950, AEROLSOLS, 2.1, LIMITED QUANTITY, (ERG#126)

Canada  (TDG)
       May be classed as Consumer Commodity, ORM-D
       UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126)

IMO
       May be shipped as Limited Quantity
       UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, EmS F-D, S-U


SECTION 15 - REGULATORY INFORMATION
SARA 313  (40 CFR 372.65C) SUPPLIER NOTIFICATION


   CAS No.     CHEMICAL/COMPOUND      % by WT     % Element
   108-88-3    Toluene                 7
   100-41-4    Ethyl benzene          0.5
   1330-20-7   Xylene                  3


CALIFORNIA PROPOSITION 65
   WARNING: This product contains chemicals known to the State of
   California to cause cancer and birth defects or other reproductive harm. 
TSCA CERTIFICATION
   All chemicals in this product are listed, or are exempt from
   listing, on the TSCA Inventory.


SECTION 16 - OTHER INFORMATION
       This product has been classified in accordance with the hazard
criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS
contains all of the information required by the CPR.


       The above information pertains to this product as currently
formulated, and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are outside our
control, we make no warranties, express or implied, and assume no liability in
connection with any use of this information.

The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance.

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Imperial Supplies LLC does not provide services and products outside the United States

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