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MSDS 85001 85001: Ecosafe Gloss Black 20 Oz [6]85001-9: Ecosafe Gloss Black 6 Pack [1] MSDS Last updated: 02/04/2008
MATERIAL SAFETY DATA SHEET
C27978000
01. 00
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NUMBER DATE PREPARATION HMIS CODES
C27978000 02-0CT-07 Health 2*
Flammability 3
Reactivity 0
PRODUCT NAME
85001 & 85001-9 GLOSS BLACK 6 Pack
MANUFACTURER'S NAME
Imperial Supplies LLC
789 Armed Forces Drive
Green Bay, WI 54304
TELEPHONE NUMBER AND WEBSITES
Regulatory Information
(800)-558-2808
Emergency Information for chemical Emergency
(800) 255-3924 Chem-Tel ONLY (spill, leak, fire, exposure,
or accident).
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
% by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE
14 74-98-6 Propane
ACGIH TLV 2500 ppm 760 mm
OSHA PEL 1000 ppm
13 106-97-8 Butane
ACGIH TLV 800 ppm 760 mm
OSHA PEL 800 ppm
8 108-88-3 Toluene
ACGIH TLV 20 ppm 22 mm
OSHA PEL 100 ppm (Skin)
OSHA PEL 150 ppm (Skin) STEL
0.6 100-41-4 Ethylbenzene
ACGIH TLV 100 ppm 7.1 mm
ACGIH TLV 125 ppm STEL
OSHA PEL 100 ppm
OSHA PEL 125 ppm STEL
3 1330-20-7 Xylene
ACGIH TLV 100 ppm 5.9 mm
ACGIH TLV 150 ppm STEL
OSHA PEL 100 ppm
OSHA PEL 150 ppm STEL
24 67-64-1 Acetone
ACGIH TLV 500 ppm 180 mm
ACGIH TLV 750 ppm STEL
OSHA PEL 1000 ppm
2 108-10-1 Methyl Isobutyl Ketone
ACGIH TLV 50 ppm 16 mm
ACGIH TLV 75 ppm STEL
OSHA PEL 50 ppm
OSHA PEL 75 ppm STEL
3 763-69-9 Ethyl 3-Ethoxypropionate
ACGIH TLV Not Available 1.11 mm
OSHA PEL Not Available
5 123-86-4 n-Butyl Acetate
ACGIH TLV 150 ppm 10 mm
ACGIH TLV 200 ppm STEL
OSHA PEL 150 ppm
OSHA PEL 200 ppm STEL
4 471-34-1 Calcium Carbonate
ACGIH TLV 10 mg/m3 as Dust
OSHA PEL 15 mg/m3 Total Dust
OSHA PEL 5 mg/m3 Respirable
Fraction
0.8 1333-86-4 Carbon Black
ACGIH TLV 3.5 mg/m3
OSHA PEL 3.5 mg/m3
SECTION 3 - HAZARDS IDENTIFICATION
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver, urinary, blood forming, cardiovascular and
reproductive systems.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
SECTION 4 - FIRST AID MEASURES
EYES: Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re-use.
INHALATION: If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
INGESTION: Do not induce vomiting.
Get medical attention immediately.
SECTION 5-FIRE FIGHTING MEASURES
FLASH POINT LEL UEL
Propellant < 0 F 1.0 12.8
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent.
Obtain medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build-up and possible auto ignition or explosion when exposed to
extreme heat.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
SECTION 7 - HANDLING AND STORAGE
STORAGE CATEGORY
Not Available
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat, sparks, and open flame. Vapors will accumulate
readily and may ignite explosively.
During use and until all vapors are gone: Keep area ventilated - Do not
smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves,
electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate, or expose to temperature
above 120 F. Heat from sunlight, radiators, stoves, hot water, and other
heat sources could cause container to burst. Do not take internally. Keep
out of the reach of children.
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels only
during sanding or abrading of the dried film. If no specific dusts are listed
in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3
(total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5
mg/m3 (respirable fraction).
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 if maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal
skin contact is expected. For long or repeated contact, wear chemical resistant
gloves.
EYE PROTECTION
Wear safety spectacles with unperforated side shields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
PRODUCT WEIGHT 6.57 lb/gal 787 g/l
SPECIFIC GRAVITY 0.79
BOILING POINT <0 - 342 F <-18 - 172 C
MELTING POINT Not Available
VOLATILE VOLUME 85 %
EVAPORATION RATE Faster than ether
VAPOR DENSITY Heavier than air
SOLUBILITY IN WATER N.A.
Ph 7.0
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)
Volatile Weight 50.57% Less Water and Federally Exempt Solvents
SECTION 10 - STABILITY AND REACTIVITY
STABILITY - Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
SECTION 11 - TOXICOLOGICAL INFORMATION
CHRONIC HEALTH HAZARDS
Reports have associated repeated and prolonged over exposure to solvents
with permanent brain and nervous system damage.
Ethyl benzene is classified by IARC as possibly carcinogenic to humans
(2B) based on inadequate evidence in humans and sufficient evidence in
laboratory animals. Lifetime inhalation exposure of rats and mice to high ethyl
benzene concentrations resulted in increases in certain types of cancer,
including kidney tumors in rats and lung and liver tumors in mice. These
effects were not observed in animals exposed to lower concentrations. There is
no evidence that ethyl benzene causes cancer in humans.
Carbon Black is classified by IARC as possibly carcinogenic to humans
(group 2B) based on experimental animal data, however, there is insufficient
evidence in humans for its carcinogenicity.
TOXICOLOGY DATA
CAS NO. Ingredient Name
74-98-6 Propane
LC50 RAT 4HR Not Available
LD50 RAT Not Available
106-97-8 Butane
LC50 RAT 4HR Not Available
LD50 RAT Not Available
108-88-3 Toluene
LC50 RAT 4HR 4000 ppm
LD50 RAT 5000 mg/kg
100-41-4 Ethyl benzene
LC50 RAT 4HR Not Available
LD50 RAT 3500 mg/kg
1330-20-7 Xylene
LC50 RAT 4HR 5000 ppm
LD50 RAT 4300 mg/kg
67-64-1 Acetone
LC50 RAT 4HR Not Available
LD50 RAT 5800 mg/kg
108-10-1 Methyl Isobutyl Ketone
LC50 RAT 4HR Not Available
LD50 RAT 2080 mg/kg
763-69-9 Ethyl 3-Ethoxypropionate
LC50 RAT 4HR Not Available
LD50 RAT 5000 mg/kg
123-86-4 n-Butyl Acetate
LC50 RAT 4HR 2000 ppm
LD50 RAT 13100 mg/kg
471-34-1 Calcium Carbonate
LC50 RAT 4HR Not Available
LD50 RAT Not Available
1333-86-4 Carbon Black
LC50 RAT 4HR Not Available
LD50 RAT Not Available
SECTION 12 - ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
No data available.
SECTION 13 - DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Do not incinerate. Depressurize container. Dispose of in accordance with
Federal, State/Provincial, and Local regulations regarding pollution.
US Ground (DOT)
May be classed as Consumer Commodity, ORM-D
UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126)
Canada (TDG)
May be classed as Consumer Commodity, ORM-D
UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY,
(ERG#126)
IMO
May be shipped as Limited Quantity
UN1950, AEROSOLS, CLASS 2, LIMITED QUANTITY,
EmS F-D, S-U
SECTION 15 - REGULATORY INFORMATION
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS NO. CHEMICAL/COMPOUND % by WT % Element
108-88-3 Toluene 8
100-41-4 Ethyl benzene 0.6
1330-20-7 Xylene 3
108-10-1 Methyl Isobutyl Ketone 2
Zinc Compound 1 0.9
CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of California
to cause cancer and birth defects or other reproductive harm.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing, on
the TSCA Inventory.
SECTION 16 - OTHER INFORMATION
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.
The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of reducers or
other additives to this product may substantially alter the composition and
hazards of the product. Since conditions of use are outside our control, we
make no warranties, express or implied, and assume no liability in connection
with any use of this information.
The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance. For more product information by email, click here Imperial Supplies LLC does not provide services and products outside the United States |
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