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MATERIAL SAFETY DATA SHEET 3M Scotch-Brite Bristle Disc. Scotch-Brite Radial Bristle Disc, Scotch-Brite Radial Bristle Brush, Scoth- Brite Roloc Body Man's Bristle Disc 09/23/2008 3M MATERIAL SAFETY DATA SHEET Copyright, 2008 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 3M Scotch-Brite(TM) Bristle Disc, Scotch-Brite(TM) Radial Bristle Disc, Scotch- Brite(TM) Radial Bristle Brush, Scotch-Brite Roloc Body Man's Bristle Disc MANUFACTURER: 3M DIVISION: Abrasives Systems Division ADDRESS: 3M Center St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 OR (651) 737-6501 (24 hours) Issue Date: 09/23/2008 Supercedes Date: 07/15/2008 Document Group: 19-1098-3 Product Use: Intended use: Abrasive Product SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt Themoplastic Binder Mixture 35 - 80 Aluminum Oxide Mineral 1344-28-1 10 - 30 Cubitron Mineral 66402-68-4 3 - 20 Polysiloxane Mixture 1 - 20 Roloc Button Mixture 0 - 5 Pigment Mixture .25 - 1.0 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVER VIEW Odor, Color, Grade: Abrasive Product, no odor. General Physical Form: Solid Immediate health, physical, and environmental hazards: This document covers only the 3M product. For complete assessment, when determining the degree of hazard, the material being abraded must also be considered. 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Mechanical eye irritation: Signs/symptoms may include pain, redness, tearing and corneal abrasion. Dust created by cutting, grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: Mechanical Skin irritation: Signs/symptoms may include abrasion, redness, pain, and itching. Inhalation: Dust from cutting, grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Prolonged or repeated exposure may cause: Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and changes in lung function tests. Ingestion: No health effects are expected. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention. Inhalation: Remove person to fresh air. If signs'/symptoms develop, get medical attention. If Swallowed: No need for first aid is anticipated. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Auto ignition temperature Not Applicable Flash Point Not Applicable Flammable Limits - LEL Not Applicable Flammable Limits - UEL Not Applicable 5.2 EXTINGUISHING MEDIA Ordinary combustible material. Use fire extinguishers with class A extinguishing agents (e.g. water, foam). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Wear full protective equipment (bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Not applicable. None inherent in this product. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Not applicable. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING For industrial or professional use only. Avoid breathing of dust created by sanding, grinding or machining. Avoid eye contact with dust or airborne particles. Damaged product can break apart during use and cause serious injury to face or eyes. Check product for damage such as cracks or nicks prior to use. Replace if damaged. Always wear eye and face protection when working at sanding or grinding operations or when near such operations. Sparks and particles flying from the product during sanding or grinding can cause injury and fire. 7.2 STORAGE Store in a cool, dry place. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use with appropriate local exhaust ventilation. Provide appropriate local exhaust ventilation for sanding, grinding or machining. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational exposure Limits and/or control dust, fume, or airborne particles. If ventilation is not adequate, use respiratory protection equipment. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact. To minimize the risk of injury to face and eyes, always wear eye and face protection when working at sanding or grinding operations or when near such operations. The following eye protection(s) are recommended: Safety Glasses with side shields. 8.2.2 Skin Protection Avoid skin contact. Wear appropriate gloves to minimize risk of injury to skin from contact with dust or physical abrasion from grinding or sanding. 8.2.3 Respiratory Protection Avoid breathing of dust created by sanding, grinding or machining. Assess exposure concentrations of all materials involved in the work process. Consider material being abraded when determining the appropriate respiratory protection. Select and use appropriate respirators to prevent inhalation overexposure. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half face piece or full face air-purifying respirator with N95 particulate filters . Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance. 8.2.4 Prevention of Swallowing Not an expected route of exposure. Wash hands after handling and before eating. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information Aluminum Oxide Mineral ACGIH TWA, particulate 10 mg/m3 Table A4 Matter, < 1% Crystalline silica Aluminum Oxide Mineral CMRG TWA 1 fiber/cc Aluminum Oxide Mineral OSHA TWA, respirable 5 mg/m3 Table Z-1 Aluminum Oxide Mineral OSHA TWA, Vacated, as 10 mg/m3 Dust Aluminum Oxide Mineral OSHA TWA, as total dust 15 mg/m3 Table Z-1 VAC Vacated PEL: Vacated Permissible Exposure Limits {PEL} are enforced as the OSHA PEL in some states. Check with your local regulatory agency.. SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Odor, Color, Grade: Abrasive Product, no odor. General Physical Form: Solid Auto ignition temperature Not Applicable Flash Point Not Applicable Flammable Limits - LEL Not Applicable Flammable Limits - UEL Not Applicable Boiling Point: Not Applicable Vapor Density Not Applicable Vapor Pressure Not Applicable Specific Gravity Not Applicable pH Not Applicable Melting Point Not Applicable Solubility In Water Not Applicable SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: Not Applicable Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion Hazardous Decomposition: Under recommended usage conditions, hazardous decomposition products are not expected. Hazardous decomposition products may occur as a result of oxidation, heating, or reaction with another material. SECTION 11: TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: The substrate that was abraded must be considered as a factor in the disposal method for this product. Dispose of waste product in a sanitary landfill. As a disposal alternative, incinerate in an industrial or commercial facility. EPA Hazardous Waste Number (RCRA): Not regulated Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14: TRANSPORT INFORMATION Not regulated per U.S. DOT, IATA, or IMO. These transportation classifications are provided as a customer service. As the shipper YOU remain responsible for complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M's transportation classifications are based on product formulation, packaging. 3M policies and 3M's understanding of applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to transportation classification and not the packaging, labeling, or marking requirements. The original 3M package is certified for U.S. ground shipment only. If you are shipping by air or ocean, the package may not meet applicable regulatory requirements. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes STATE REGULATIONS Contact 3M for more information. CHEMICAL INVENTORIES This product is an article as defined by TSCA regulations, and is exempt from TSCA Inventory listing requirements. Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information. WHMIS: Hazardous This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: OTHER INFORMATION NFPA Hazard Classification Health:1 Flammability: 1 Reactivity: 0 Special Hazard: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel address the hazards that are presented by short- term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Revision Changes: Section 2: Ingredient table was modified. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely Within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. 3M MSDSs are available at www.3M.com