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MATERIAL SAFETY DATA SHEET FOR COATED ABRASIVES TAF F.E.P.A. Federazione Europea Dei Produttori di Abrasivi Format be FEPA as per EC Directive 91/155 and ISO-Standard 11014- COMPANY TAF ABRASIVI S.p.A. DATE 1/10/2005 ADDRESS Via Beato Angelico 29/31-20052 MONZA MI POSITION AUTHORIZED PERSON Fax no ++39-039-2021549 Phone no. ++39-039-20693.1 IMPORTANCE NOTICE; Coated abrasives are inert products which do not create any risk when handled or stored. When used on grinding machines they require specific measure to protect the operators. During the grinding operation 90% or more of the particulates of the dust come from the material being ground and, for wet grinding, from aerosols generated by the grinding fluid. Specific attention must therefore be given to the nature of the part and of the fluid and the appropriate protection devices must be installed. 1. PRODUCT IDENTIFICATION -------------------------------------------------------------------------------- HA66 ALUMINUM OXIDE POLYESTER CLOTH RESIN OVER RESIN 2. COMPOSITION/INFORMATION ON INGREDIENTS -------------------------------------------------------------------------------- 2.01 Abrasive X Synthetic aluminum oxide Synthetic silicon carbide Zirconia alumina (ZO2 - A12O3) Others 2.02 Bond Glue (natural derived from plant or animal) X Cured phenolic resin Cured urea/melamine resin Others 2.03 Fillers X Calcium carbonate Kaolin X Cryolite X Others IRON OXIDE 2.04 Backing Paper Cotton cloth X Polyester cloth Vulcanized fibre Others 2.05 Other 3. HAZARDS IDENTIFICATION -------------------------------------------------------------------------------- NOT APPLICABLE. Coated abrasives are not dangerous products as stated in EC Directive N. 88/379 4. FIRST AID MEASURES -------------------------------------------------------------------------------- NOT APPLICABLE WHEN COATED ABRASIVES ARE NOT IN USE ON MACHINE. The following recommendations are basic rules during a grinding operation, they must be followed in conjunction with the information appearing in the Safety data sheet of the material ground and of the grinding fluid when used. Dust inhalation; Remove from exposure. Seek medical advice if symptoms persist. Eye; Remove from exposure and flush with clean water. If symptoms persist seek medical advice. Skin; No hazardous effect known. Ingestion; No hazardous effect known. 5. FIRE FIGHTING MEASURES -------------------------------------------------------------------------------- NONE SPECIFIC Water, power, foam, sand, CO2 can be used if compatible with operating conditions. 6. ACCIDENTAL CONTAMINATION MEASURES -------------------------------------------------------------------------------- NOT APPLICABLE 7. HANDLING AND STORAGE -------------------------------------------------------------------------------- Follow recommendations for machines and national regulations. Store coated abrasives in moderate constant temperature and humidity conditions. For detailed recommendation refer to FEPA Safety Leaflet for Coated Abrasives. 8. EXPOSURE CONTROL AND PERSONAL PROTECTION -------------------------------------------------------------------------------- NOT APPLICABLE WHEN COATED ABRASIVES AND HANDLED OR STORED During the grinding operation with coated abrasives particles of dust come from the material being ground. The general value for dust is max 6 mg/m3. When using coated abrasives, refer to grinding machines instructions and to the national rules. Refer also to the EPA Safety Leaflet for Coated Abrasives. 8.01 The following personal protective equipment must be used dependent on the operation and the material being ground. - Eye protection; Machine guarding and safety goggles or face shield. - Dust protection; Use of dust mask. - Hand protection; Use of barrier cream and protection gloves. - Ear protector; Use of ear defenders or equivalent. - Skin protection; Use of suitable protective clothing. 8.02 Hyglen measures; No specific requirements. 9. PHYSICAL AND CHEMICAL PROPERTIES -------------------------------------------------------------------------------- 9.01 Physical State; Solid 9.02 Color; Variable 9.03 Smell; Not applicable (May give off non specific smell in use) 9.04 pH; Not applicable 9.05 Change of physical state; Not applicable 9.06 Density; Not applicable Bulk density; Not applicable 9.07 Vapor pressure; Not applicable 9.08 Flash point; Not applicable 9.09 Explosion properties; Not applicable 9.10 Viscosity; Not applicable 9.11 Solubility in water; Not defined 10. STABILITY AND REACTIVITY -------------------------------------------------------------------------------- Coated abrasives are stable and non reactive when handled or stored. 10.1 Conditions to avoid; Not applicable 10.2 Materials to avoid; Strong acids, strong bases and strong oxidant agents may modify the mechanical characteristics of the products and create safety hazards when used in machines. 10.03 Hazardous decomposition products; If coated abrasives are used in accordance with instructions no hazardous decomposition products are created. 11. TOXICOLOGICAL INFORMATION -------------------------------------------------------------------------------- NON APPLICABLE WHEN HANDLED OR STORED. According to the experience gathered for many years, coated abrasives, when properly used have no adverse effect on health, refer to the preliminary note about dust and aerosols of grinding fluid. 12. ECOLOGICAL INFORMATION -------------------------------------------------------------------------------- 12.01 Mobility; not applicable 12.02 Persistence and degradability; Not defined 12.03 Potential bio accumulative; Not applicable 12.04 Ecotoxicity; Not applicable 13. DISPOSAL CONSIDERATIONS -------------------------------------------------------------------------------- After use, coated abrasives may be contaminated with hazardous materials (particles of cooling agents) and should be disposed in accordance with national regulations. 14. TRANSPORT -------------------------------------------------------------------------------- Coated abrasives are not dangerous products. 15. REGULATORY INFORMATION -------------------------------------------------------------------------------- EC-Regulations; NONE, no specific marking required under EC-Directive Nr. 88/379d National or Local Regulations; Refer to relevant texts. 16. OTHER INFORMATION -------------------------------------------------------------------------------- WARNING; The above indications are based on existing practice and do not constitute a guarantee. The laws and regulations must be strictly followed by the users who may remain responsible for the use of coated abrasives. TAF ABRASIVR S.p.A.