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MSDS 71736 71736: Radial Patch Cement [1]MSDS Last updated: 08/15/2008
REMA
TIP
TOP 8/19/2005
Material Safety Data Sheet
Product No. BL-5, 8, 32, G
1. CHEMICAL PRODUCT & COMPANY IDENTIFICATION
Product Name: Special Cement
Product Use: Adhesive
MSDS Preparation Date: 8/19/2005
Manufacturer: REMA TIP TOP/NO. AMERICA, 119 Rockland Avenue,
Northvale, NJ 07647
24-Hour Emergency Phone Number: 800-424-9300 (CHEMTREC)
2. PRODUCT INGREDIENTS
CHEMICAL NAME: CAS NUMBER: % RANGE: OSHA PEL:
Trichloroethylene 79-01-6 60-90 100 ppm TWA
Component Related Regulatory Information
This product may be regulated, have exposure limits or other information
identified as the following: F025- Hazardous wastes.
The balance of ingredients not rated as hazardous as defined in 29 CFR
1910.1200.
This product is considered hazardous under 29 CFR 1910.1200 (Hazard
Communication) and the Canadian Controlled Products Regulations.
3. HAZARDS IDENTIFICATION
POTENTIAL HEALTH EFFECTS:
This product is a blue liquid adhesive. This product may be irritating to the
eyes, respiratory system and skin. This product may cause central nervous system
depression and allergic reactions. Skin absorption is possible. Component of
this product is known to be a possible carcinogen.
EYE: This product is irritating to the eyes. Vapors may also produce eye
irritation.
SKIN: This product is irritating to the skin. Prolonged and/or repeated skin
contact with this product can cause defatting of skin and dermatitis. Skin
absorption is possible, causing systemic poisoning.
INGESTION: This product may be harmful if it is swallowed. Single dose toxicity
is considered to be low. If aspirated (liquid enters the lung), this product may
be rapidly absorbed through the lungs and result in injury to other body
systems.
INHALATION: This product may be harmful by inhalation. Exposure to high
concentrations of vapor or mist can cause central nervous system depression with
symptoms of headache, dizziness, stupor, loss of consciousness or death. High
concentrations can cause irregular heartbeat, cardiac arrest and death.
Overexposure has been shown to cause adverse effects on the liver and nervous
system.
4. FIRST AID
EYES: Immediately flush eyes with water for at least 15 minutes, while holding
eyelids open. If irritation persists get medical attention.
SKIN: For skin contact flush with large amounts of water while removing
contaminated clothing. If irritation persists, get medical attention. Wash
contaminated clothing before reuse.
INGESTION: Do not induce vomiting. Call a physician immediately.
INHALATION: Move person to non-contaminated air. If the affected person is not
breathing, apply artificial respiration. Seek medical attention.
NOTE TO PHYSICIAN: Provide general supportive measures and treat
symptomatically.
5. FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES:
Flash Point: >200°F (93.3°C) Method Used: TOC, TCC, COC
Upper Flammable Limit (UFL): 44.8% @ 212°F (100°C); Lower Flammable Limit (LFL):
8% @ 212°F (100°C); 8%
10.5% @ 77°F (25°C) @ 77°F (25°C)
Auto Ignition: 788°F (420°C) Flammability Classification:
Class IIIB liquid
HAZARDOUS COMBUSTION PRODUCTS: Hazardous combustion products may include and are
not limited to hydrogen chloride. Hazardous combustion products may include
trace amounts of phosgene and chlorine gases.
EXTINGUISHING MEDIA: Dry chemical, foam, carbon dioxide, water fog.
FIRE FIGHTING INSTRUCTIONS: This product poses a slight fire hazard.
PROTECTIVE EQUIPMENT FOR FIRE FIGHTERS: Fire fighters should wear full-face,
self-contained breathing apparatus and impervious protective clothing. Fire
fighters should avoid inhaling any combustion products.
6. ACCIDENTAL RELEASE MEASURES
CONTAINMENT PROCEDURES: Stop the flow of material, if this is without risk.
Contain the discharged material.
Prevent contamination of soil, surface water or groundwater. Material is heavier
than water and has limited water solubility. It will collect on the lowest
surface.
CLEAN-UP PROCEDURES: Wear appropriate protective equipment and clothing during
clean up. Absorb spill with inert material. Shovel material into appropriate
container for disposal.
EVACUATION PROCEDURES: Isolate area. Keep unnecessary personnel away.
SPECIAL PROCEDURES: Notify National Response Center (800-424-8802) of
uncontained releases to the environment in excess of the Reportable Quantity
(RQ). For all transportation accidents, call CHEMTREC at 800-424-9300.
7. HANDLING & STORAGE
HANDLING: Do not get this material in your eyes, on your skin, or on your
clothing. Avoid breathing vapors or mists of this product. Wash thoroughly
after handling. DO NOT eat, drink or smoke in product area.
STORAGE: Keep packaged in original, labeled containers until use. Store in a
cool, dry place. Do not store in aluminum, zinc, aluminum alloys and plastic
containers. Do not remove or deface label. Prevent water or moist air from
entering containers. Do not reuse container without recycling or reconditioning
in accordance with any Federal, Provincial, State or local laws. Do not use
cutting or welding torches, open flames, or electric arcs on empty or full
containers.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: Provide adequate local exhaust ventilation to maintain
worker exposure below exposure limits.
PERSONAL PROTRECTIVE EQUIPMENT
EYE/FACE PROTECTION: Wear safety glasses with side shields. Contact lenses
should not be exposed. Wear chemical goggles; face shield (if splashing is
possible). If vapor exposure causes eye discomfort, use a full-face respirator.
SKIN PROTECTION: Use impervious gloves. Use of impervious apron and boots are
recommended.
RESPIRATORY PROTECTION: If airborne concentrations are above the applicable
exposure limits, use NIOSH approved respiratory protection.
EXPOSURE GUIDELINE(s): Component Exposure Limits
REMA TIP/TOP USA recommends that its customers minimize employee exposure. REMA
therefore suggests that its customers consider adopting the lower of the current
OSHA PEL or the ACGIH TLV's for the purpose of evaluating employee exposures.
The TLV's recommended by the ACGIH have been updated on a continuing basis.
Trichloroethylene (79-01-6)
ACGIH: 50 ppm TWA
100 ppm STEL
OSHA: 100 ppm TWA
200 ppm Ceiling
Component Exposure Limits - Canada
The following Provincial Exposure Limits apply for this product's components.
Trichloroethylene (79-01-6)
Alberta: 50 ppm TWA; 269 mg/m3 TWA
100 ppm STEL; 537 mg/m3 STEL
British Columbia: 50 ppm TWA
100 ppm STEL
Manitoba: 50 ppm TWA; 270 mg/m3 TWA
200 ppm STEL; 1080 mg/m3 STEL
New Brunswick: 50 ppm TWA; 269 mg/m3 TWA
100 ppm STEL; 537 mg/m3 STEL
NW Territories: 100 ppm TWA; 537 mg/m3 TWA
150 ppm STEL; 806 mg/m3 STEL
Nova Scotia: 50 ppm TWA
100 ppm STEL
Nunavut: 100 ppm TWA; 537 mg/m3 TWA
150 ppm STEL; 806 mg/m3 STEL
Ontario: 50 ppm TWAEV
100 ppm STEV
Quebec: 50 ppm TWAEV; 269 mg/m3 TWAEV
200 ppm STEV; 1070 mg/m3 STEV
Saskatchewan: 269 mg/m3 TWA; 50 ppm TWA
537 mg/m3 STEL; 100 ppm STEL
Yukon: 100 ppm TWA; 535 mg/m3 TWA
150 ppm STEL; 800 mg/m3 STEL
9. PHYSICAL & CHEMICAL PROPERTIES
APPEARANCE: Blue liquid
ODOR: Mildly sweet, ether-like ODOR THRESHOLD: ~60 ppm
BOILING POINT: 188°F (86.7°C)
SOLUBILITY IN WATER: 0.1 g/100g @ 77°F (25°C)
SPECIFIC GRAVITY: 1.45 @ 77°F (25°C)
VAPOR PRESSURE: 58 mmHg @ 20°C (68°F)
% VOLATILE: 82%
10. STABILITY & REACTIVITY
INCOMPATIBILITY WITH OTHER MATERIALS: Materials to avoid are strong alkalies,
oxidizers, barium, lithium, magnesium and titanium.
HAZARDOUS POLYMERIZATION: Will not occur.
DECOMPOSITION PRODUCTS: Upon decomposition, this product may produce hydrogen
chloride and trace amounts of chlorine and phosgene (intense heat of fire).
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
This product may be irritating to the eyes, skin, and respiratory system. This
product may cause sensitization in previously exposed individuals and result in
contact dermatitis. This product may be absorbed through the skin. Acute
inhalation may cause central nervous system depression with drowsiness,
dizziness, headache, nausea, vomiting, unconsciousness and
coma. Death may occur from respiratory arrest or ventricular fibrillation
resulting in primary cardiac failure. Liver and kidney damage may also occur.
CHRONIC TOXICITY
Prolonged or repeated liquid contact can result in defatting and drying of the
skin, which may result in skin irritation and dermatitis. Sensitization may
occur. Repeated exposure to the eyes may cause conjunctivitis.
CARCINOGENICITY
This product contains component(s) that may be listed by ACGIH, IARC, NIOSH,
NTP OR OSHA.
Component Carcinogenicity
Trichloroethylene (79-01-6)
ACGIH: A5 - Not Suspected as a Human Carcinogen
NIOSH: potential occupational carcinogen
NTP: Reasonably Anticipated To Be A Carcinogen (Possible Select
Carcinogen)
IARC: Monograph 63, 1995 (Group 2A (probably carcinogenic to
humans))
12. ECOLOGICAL INFORMATION
Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic
environment.
Component Analysis - Ecotoxicity - Aquatic Toxicity
Trichloroethylene (79-01-6)
Test & Species Conditions
96 Hr LC50 fathead minnow 44.1 mg/L flow-through
13. DISPOSAL CONSIDERATIONS
DISPOSAL: Dispose of waste material according to Local, State, Federal, and
Provincial Environmental Regulations.
UNUSED & UNCONTAMINATED PRODUCT:
Component Waste Numbers
Trichloroethylene (79-01-6)
RCRA: waste number U228, D040
0.5 mg/L regulatory level
This product contains a component identified as hazardous under 40 CFR 261.24.
14. TRANSPORT INFORMATION
US DOT Information
Shipping Name: Trichloroethylene Mixture
UN/NA #: UN1710 Hazard Class: 6.1 Packing Group: III
Required Label(s): POISON
Additional Info.: Check RQ regulations for the product packaging.
PLACARD (WHEN REQUIRED): POISON, 6.
EXCEPTIONS: DOT Paragraphs 173.153 & 173.203.
ALTERNATE SHIPPING ARRANGEMENTS: Based on package or shipping container
size, this product may be shipped as a, "Limited Quantity", or, renamed,
"Consumer Commodity" and reclassified as, "ORM-D" Material.
TDG Information
Shipping Name: Trichloroethylene
UN/NA #: UN1710 Hazard Class: 6.1 Packing Group: III
Required Label(s): POISON
IMDG Information
Additional Info.: EmS No. = F-A, S-A
IATA Information
Additional Info.: 6.1
15. REGULATORY INFORMATION
US FEDERAL REGULATIONS
SARA 313 INFORMATION:
Component Analysis
This material contains one or more of the following chemicals required to be
identified under SARA Section 313 (40 CFR 372.65).
Trichloroethylene (79-01-6)
SARA 313: 0.1 % de minimis concentration
SARA HAZARD CATEGORY:
Acute Health: Yes Chronic Health: Yes Fire: No Pressure: No Reactive: No
COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION AND LIABILITY ACT (CERCLA):
Component Analysis
This material contains one or more of the following chemicals required to be
identified under CERCLA (40 CFR 302.4).
Trichloroethylene (79-01-6)
CERCLA: 100 lb final RQ; 45.4 kg final RQ
TOXIC SUBSTANCES CONTROL ACT (TSCA): Components of this product have been
checked against the non- confidential TSCA inventory by CAS Registry Number.
Components not identified on this non-confidential inventory are
exempt from listing (i.e. as polymers) or are listed on the confidential
inventory as declared by the supplier.
Component Analysis - Inventory
Component CAS # TSCA CAN EEC
Trichloroethylene 79-01-6 Yes DSL EINECS
STATE RIGHT-TO-KNOW:
Component Analysis - State
The following components appear on one or more of the following state hazardous
substances lists:
Component CAS CA MA MN NJ PA RI
Trichloroethylene 79-01-6 Yes Yes Yes Yes Yes Yes
This product is not a consumer product. This product may not be legally
authorized for consumer use or sale in a state that has adopted the OTC Model
Rule, or in California pursuant to the Consumer Products Regulation of the
California Air Resources Board, or in states with similar laws. Please check
federal, state, and local air control laws for guidance.
The following statement(s) are provided under the California Safe Drinking Water
and Toxic Enforcement Act of 1986 (Proposition 65):
WARNING! This product contains a chemical known to the state of California to
cause cancer.
CANADIAN REGULATIONS
This product is regulated under the Canadian Controlled Products Regulations.
WHMIS INFORMATION:
WHMIS Classification: D1A, D2A, D2B
Component Analysis - WHMIS IDL
The following components are identified under the Canadian Hazardous Products
Act Ingredient Disclosure List:
Component CAS # Minimum Concentration
Trichloroethylene 79-01-6 1 % (English Item 1612, French
Item 1646)
EUROPE:
Component Analysis
Component (CAS#) EC #
Trichloroethylene (79-01-6) 201-167-4
16. OTHER INFORMATION
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) RATINGS:
NFPA Ratings: Health: 2 Fire: 1 Reactivity: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
MEDICAL EMERGENCIES: FOR ANY OTHER INFORMATION:
Call CHEMTREC 24 hours a REMA TIP TOP/NO. AMERICA
Day for emergency information 119 Rockland Ave.
800-424-9300 NORTHVALE, NJ 07647
201-768-8100
NOTICE: REMA TIP/TOP USA believes that the information contained on this
material safety data sheet is accurate. The suggested procedures are based on
experience as of the date of publication. They are not necessarily all-inclusive
nor fully adequate in every circumstance.
Also, the suggestions should not be confused with nor followed in violation
of applicable laws, regulations, rules or insurance requirements.
NO WARRANTY IS MADE, EXPRESS OR IMPLIED, OF MERCHANTABILITY,
FITNESS FOR A PARTICULAR PURPOSE OR OTHERWISE.
The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance. For more product information by email, click here Imperial Supplies LLC does not provide services and products outside the United States |