|
|
Printer Friendly View
9577: (DISCONTINUED)
MSDS Last updated: 08/08/2003
MATERIAL SAFETY DATA SHEET
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name; CONTACT ADHESIVE 5
Item No; 009577-0
Loctite No; 30537
Product Type; Adhesive
Revision Date; 1-25-02
MANUFACTURERS NAME: LOCTITE CORPORATION
MANUFACTURERS ADDRESS: 1001 TROUT BROOK CROSSING
CITY, STATE, ZIP: ROCKY HILL CT 06067-3910
DISTRIBUTORS NAME: IMPERIAL SUPPLIES LLC
DISTRIBUTORS ADDRESS: 789 PACKER DRIVE
CITY, STATE, ZIP: GREEN BAY WI 54307
INFORMATION NUMBER: 800-558-2808
EMERGENCY PHONE: 800-255-3924 (CHEM-TEL)
2. COMPOSITION, INFORMATION ON INGREDIENTS
Ingredients CAS NO. %
--------------------------------------------------------------------------------
ACETONE 67-64-1 20-25
METHYL ETHYL KETONE* 78-93-3 20-25
N-HEXANE* 110-54-3 15-20
TOLUENE* 108-88-3 15-20
*This component is listed as a SARA Section 313 Toxic Chemical.
Ingredients, which have exposure limits.
Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)
--------------------------------------------------------------------------------
ACETONE 500 ppm TWA 1000 ppm TWA None
1188 mg/m3 2400 mg/m3
METHYL ETHYL
KETONE 200 ppm TWA 200 ppm TWA None
590 mg/m3 590 mg/m3
n?HEXANE 50 ppmTWA(skin) 500 ppm TWA None
1800 mg/M3
TOLUENE 50 ppm skin 100 ppm None
188 mg/M3 skin 375mg/M3
Exposure Limits (STEL)
Ingredients ACGIH OSHA
(TLV) (PEL)
--------------------------------------------------------------------------------
ACETONE 750 ppm None
1782 mg/m3
METHYL ETHYL KETONE 300 ppm 300 ppm
885mg/m3 885 mg/m3
TOLUENE None 150 ppm
560 mg/m3
3. HAZARDS IDENTIFICATION
Toxicity
Irritating to the eyes, skin, and respiratory tract. Overexposure may cause
Central Nervous System effects. Harmful if swallowed.
Toluene
Intentional misuse by deliberate inhalation of toluene has been associated
with liver, kidney and brain damage in humans. Repeated exposure to toluene
has been associated with high frequency hearing loss based on evidence in
animals. The human health consequences of this finding is uncertain.
Methyl Ethyl Ketone:
Based on animal studies, it increases the onset of peripneral neuropathy
caused by exposure to Methyl Butyl Ketone and/or N?Hexane, and/or Ethyl Butyl
Ketone. MEK, alone, has not been shown to cause peripheral neuropathy.
N Hexane:
Prolonged and repeated exposure to N Hexane may cause peripheral neuropathy
by damaging peripheral nerve tissue and result in muscular weakness and loss
of sensation. Skin contact, ingestion, inhalation, and eye contact
Primary Routes of Entry: Signs and Symptoms of Exposure:
EYES:
Exposure to liquid or vapor causes mild eye irritation. Symptoms may
include burning, tearing, redness, stinging, blurred vision, and corneal
injury.
SKIN:
Exposure may cause mild skin irritation. Prolonged or repeated exposure may
burn the skin. Symptoms may include redness, burning, drying, cracking and
skin burns. Pre?existing skin disorders may be aggravated by exposure to this
material. Sk1n absorption is possible, but harmful effects are not expected
from this route of exposure under normal conditions of handling and use.
BREATHING;
Symptoms are typically seen at air concentrations exceeding the recommended
exposure limits. Symptoms of exposure may include
1) Nasal and respiratory irritation (nose, Throat, and lung) - pre-existing
lung disorder, e.g. asthma-like conditions, may be aggravated by exposure
to this material.
2) Central Nervous System (CNS) Depression/ Effect(dizziness, drowsiness,
weak-ness, fatigue, nausea, headache, possible unconsciousness, coma, and
even death).
3) Cardiac arrhythmias (irregular heartbeat)
4. Cough
SWALLOWING;
This material can enter the lungs during swallowing or vomiting and cause
lung inflammation and/or damage. Aspiration of material into the lungs can
cause chemical pneumonia, which can be fatal. Symptoms of exposure may
include;
1) Throat irritation
2) Gastrointestinal irritation (nausea, vomiting, diarrhea)
3) Central Nervous System (CNS) Depression/Effect (dizziness, drowsiness,
Weakness, fatigue, nausea, headache, possible unconsciousness,
Coma, and even death)
4) High blood sugar
Existing conditions
Aggravated by Exposure; Toluene; Eye, liver, skin, respiratory and central
nervous system diseases; alcoholism; Methyl ethyl ketone; eye problems, skin
and respiratory disorders. These or other components may also aggravate
pre-existing disorder of these organs; liver, kidney, nervous system, lungs,
nose, testis, eyes.
Literature Referenced Carcinogen
Ingredients Target Organ and other Health Effects NTP IARC OSHA
ACETONE BLO CNS IRR NO NO NO
METHYL ETHYL KETONE CNS IRR NO N/A NO
n-HEXANE DEV IRR LUN NER REP NO NO NO
TOLUENE BEH CAR CNS DEV EAR IRR NO NO NO
Abbreviations
N/A Not Applicable BEH Behavioral
BLO Blood CAR Cardiac
CNS Central Nervous System DEV Developmental
EAR Ear IRR Irritant
LUN Lung NER Nervous System
REP Reproductive
4. FIRST AID MEASURES
Ingestion;
Do not induce vomiting. This material is an aspiration hazard. If individual
is drowsy or unconscious, place on left side with head down. Seek medical
attention. If possible, do not leave individual unattended. Aspiration of
material into lungs can cause chemical pneumonia, which can be fatal.
Inhalation;
If symptoms develop, immediately move individual away from exposure and into
fresh air. Seek immediate medical attention. Keep person warm and quiet. If
person is not breathing, begin artificial respiration. If breathing is
difficult, administer oxygen.
Skin Contact;
Remove contaminated clothing. Flush exposed area with large amounts of water.
If skin is damaged, apply a clean dressing and seek immediate medical
attention. If skin is not damaged, wash exposed area with soap and water. If
symptoms persist, seek medical attention. Launder clothing before reuse.
Eye Contact;
If symptoms develop, move individual away from exposure and into fresh air.
Flush eyes with water for at least 15 minutes while holding eyelids apart.
Seek medical attention.
5. FIRE FIGHTING MEASURES
Flash Point; -10 degrees F Method; Tag Closed Cup
Recommended
Extinguishing Agents;
Carbon dioxide, foam, dry chemical
Special Firefighting
Procedures;
Never use welding or cutting torch on or near drum (even empty) because
product (even just residue) can ignite explosively. All five gallon pails and
larger metal containers should be grounded and/or bonded when material is
transferred. Material is highly volatile and readily gives off vapors which
may travel along the ground or be moved by ventilation and ignited by pilot
lights, other flames, sparks, heaters, smoking, electric motors static
discharge, of other ignition sources at locations distant from material
handling point. WARNING! Sudden release of hot organic chemical vapors or
mist from process equipment operated at elevated temperature and pressure or
sudden ingress of air into vacuum equipment may result in ignitions without
the presence of obvious ignition sources. Published "auto ignition"
or "ignition" temperature values cannot be treated as safe operation
temperatures in chemical processes without analysis of the actual processes
conditions. Any use of this product at elevated temperature processes should
be thoroughly evaluated to establish and maintain safe operation conditions.
hydrocarbon solvents are basically non-conductors of electricity and can
become electrostatically charged during mixing, filtering or pumping at high
flow rates. If this charge reaches a significantly high level, sparks can
form that may ignite vapors of flammable liquids.
Hazardous Products formed
By Fire or Thermal Decomp;
Irritating organic vapors, oxides of carbon, hydrocarbons
Unusual Fire or
Explosion Hazards;
None
Explosive Limits
(% by volume in air) Lower 1%
(% by volume in air) Upper 12.6%
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken in case of
spill or leak;
Eliminate all ignition sources (flares, flames including
pilot lights, electrical sparks.) Persons not wearing protective equipment
should be excluded from area of spill until clean-up has been completed. Stop
spill at source; dike area to prevent spreading, pump liquid to salvage tank.
Remaining liquid may be taken up on sand, clay, earth, floor absorbent, or
other absorbent material and shoveled into containers, which should be kept
closed until disposal. Prevent run-off to sewers, streams or other bodies of
water. If run-off occurs, notify proper authorities as required, that a spill
has occurred. For small spills, absorb liquid on paper, vermiculite, floor
absorbent material and transfer to hood.
7. HANDLING AND STORAGE
Safe Storage;
Store in a cool, well-ventilated place away from incompatible
materials. Keep away from heat, sparks and flame. Protect material from
direct sunlight.
(Contact Loctite Customer Service 1-800-243-4874 for shelf life information)
Handling;
Keep inhalation and skin exposure to a minimum. Wash before eating, smoking
or using the rest room. Ground and bond containers when transferring
material. Empty containers may retain hazardous properties. follow all MSDS
and label warnings even after container is empty.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Eyes;
Chemical splash goggles in compliance with OSHA regulations are
advised; however, OSHA regulations also permit other types of safety
glasses. Consult your safety representative for specific recommendations.
Skin;
Wear resistant gloves. Consult your safety representative for specific
recommendations.
Ventilation;
Sufficient to maintain vapor concentration below TLV and lower
explosive limit. Explosion proof equipment should be considered. Local and
general mechanical exhaust ventilation should be used.
Respiratory;
A NIOSH/MSHA jointly approved air supplied respirator is
Advised in absence of proper environmental control.
See Section 2 for Exposure Limits
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance; Yellow liquid.
Odor; Solvent
Boiling Point; 133 degrees F @ 760 mmHg
pH; Does not apply
Solubility in water; Negligible
Specific Gravity; 0.91
Volatile Organic Compound
(EPA Method 24) 3.58 lbs/gal
Vapor Pressure; 181 mm Hg
Vapor Density; 2,68
Evaporation rate
(Ether = 1) 14.4 (Butyl acetate = 1)
10. STABILITY AND REACTIVITY
Stability; Stable
Hazardous Polymerization; Will not occur
Incompatibility; Strong oxidizers, acids
Conditions to avoid; Heat, sparks, flames, and other sources of
ignition
Hazardous Decomposition
Products (non-thermal); None
11. TOXICOLOGICAL INFORMATION
See Section 3.
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended methods of
disposal;
Incinerate following EPA and local regulations.
EPA Hazardous Waste
Number;
D001/D035 - Hazardous waste per 40 CFR 261.21 and
A TCLP waste per 261.24/ Methyl Ethyl Ketone.
14. TRANSPORTATION INFORMATIOIN
DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name;
Consumer Commodity (Not more than one liter).
Adhesives (More than one liter)
Hazard Class or
Division;
ORM-D (Not more than oneliter); Class 3, Packing Group 11 (More than one
liter) Identification Number; None (Not more than one liter); UN 1133 (More
than one liter) Marine Pollutant; None
IATA
Proper Shipping Name; Adhesives
Class or Division; Class 3, Packing Group 11
UN or ID Number; UN 1133
15. REGULATORY INFORMATION
CA Proposition 65;
Warning; This product contains chemicals known to The state of
California to cause cancer and birth defects or other reproductive harm.
Toluene, benzene
16. OTHER INFORMATION
Estimated NFPA (R) Code;
Health Hazard; 2
Fire Hazard 3
Reactivity Hazard; 0
Specific Hazard; Does not apply
Estimated HMIS ® Code;
Health Hazard; 2*
Flammability Hazard ; 3
Reactivity Hazards; 0
Personal Protection See section 8.
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
Prepared By; Rajal Dhruva
Title; Health & Regulatory Affairs Specialist
Company; Loctite Corp. 1001 Tr Br Cr. Rocky
Hill Ct 06067
(24 hr) Phone (860) 571-5100
Revision 0005
The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance.
For more product information by email, click here
Imperial Supplies LLC does not provide services and products outside the United States
|
