MSDS 7616

                            Material Safety Data Sheet

                   
                      1.  PRODUCT AND COMPANY IDENTIFICATION

PRODUCT IDENTIFICATION
Brand Name            MANUS-BOND 64-A Butyl Tape
Product Use            Adhesive / Sealant
Product Identification Number   N/A
 
MANUFACTURER                    EMERGENCY TELEPHONE NUMBER
 
Manus Products, Inc.            CHEMTREC: 800-424-9300
866 Industrial Blvd West         
Waconia, MN 55387                Plant Telephone: 952-442-3323
 

                   2.  COMPOSITION / INFORMATION ON INGREDIENTS

 
CHEMICAL NAME                     CAS NUMBER     WEIGHT %
--------------------------------------------------------------------------------
Calcium Carbonate                    1317-65-3      <30
Talc                                  14807-96-6      <40
Carbon Black  (Black, Gray)       1333-86-4      <10
Titanium Dioxide (White)          13463-67-7      <10
 
See Section 15 of this MSDS for OSHA Regulatory Status
 

                            3.  HAZARDS IDENTIFICATION

 
EMERGENCY OVERVIEW
 
Tacky rubber based extrusion with very little odor.
      
In case of fire, use foam, dry chemical, CO2.
 
POTENTIAL HEALTH EFFECTS
 
PRIMARY ROUTE(S) OF ENTRY
 
Ingestion
 
SYMPTOMS OF EXPOSURE
 
Inhalation:        N/A
Eye Contact:    May cause eye irritation, stinging, tearing, and redness. 
 
Skin Contact:  May cause loss of natural oils, dermatitis. Symptoms may include 
redness, drying and cracking of skin.

Ingestion:   May cause gastrointestinal tract irritation.
 
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
 
Not Known
 
REPORTED AS CARCINOGEN OR POTENTIAL CARCINOGEN
 
_Not Applicable               _OSHA
_National Toxicology Program (NTP)      3 International Agency for Research 
                                               on Cancer (IARC)
                                               (See Section 11)
 

                              4.  FIRST AID MEASURES

 
Inhalation:      Not Applicable
 
Eye Contact:      Flush with water until irritation is removed. 
 
Skin Contact:      Wash exposed areas with soap and water.
 
Ingestion:      Do not induce vomiting. Do not give anything by mouth to an
         unconscious or convulsing person.
         Get immediate medical attention.
 
NOTE TO PHYSICIAN
 
None
 

                            5.  FIRE FIGHTING MEASURES

 
EXTINGUISHING MEDIA
For small fires, use foam, CO2, or dry chemical. For large fires, use water 
spray, fog, or foam. 
 
SPECIAL FIREFIGHTING INSTRUCTIONS
Thermal decomposition may produce toxic organic compounds. Avoid breathing 
smoke. 
 
FIREFIGHTING EQUIPMENT
As in any fire, wear NIOSH approved, positive-pressure self-contained breathing 
apparatus and full protective gear. 
 

                         6.  ACCIDENTAL RELEASE MEASURES

 
Recover for reprocessing or disposal. 
 

                             7.  HANDLING AND STORAGE

 
HANDLING
Wear appropriate protective equipment (See Section 8).
 
STORAGE
Store in a cool dry place. 
 

                    8.  EXPOSURE CONTROLS/PERSONAL PROTECTION

 
ENGINEERING CONTROLS
Ventilation not required. 
 
PERSONAL PROTECTION
Respirator:        Not normally needed
 
Eye Protection:    Wear vented safety goggles.
 
Gloves:        Not normally needed.
 
Clothing:        Protective clothing not normally needed. 
 
Other:                   Not normally needed. 
 
EXPOSURE CONTROLS
 
COMPONENT                    OSHA PEL               ACGIH TLV
                              TWA         STEL      TWA           STEL
--------------------------------------------------------------------------------
Calcium Carbonate*         15 mg/m3   N/E       10 mg/m3    N/E
Carbon Black*               3.5 mg/m3  N/E     3.5 mg/m3   N/E
Talc*                         5 mg/m3    N/E     2 mg/m3     N/E
Titanium Dioxide*           15 mg/m3   N/E     10 mg/m3    N/E

* Exposure limits are provided for information only. These chemicals are not in 
a respirable form in this product. 
 

                       9.  PHYSICAL AND CHEMICAL PROPERTIES

 
State:         Solid               Vapor Density      Heavier than air. 
Color;         N/A                 Reactivity in Water:   Negligible
Odor;         Very little odor   Specific Gravity;   ~ 1.48
Melting Point ºF: >400ºF      Water Solubility:   Negligible
Boiling Point:      N/A           pH:         NA
Vapor Pressure 
(mm Hg):      N/A
 

                          10.  STABILITY AND REACTIVITY

 
REACTIVITY
Stable.
 
INCOMPATIBILITIES
Avoid contact with strong acids, caustic materials and oxidizers. 
 
HAZARDOUS DECOMPOSITION PRODUCTS
May form oxides of carbon and various unidentified organic compounds. 
 
CONDITIONS TO AVOID
Avoid temperatures above 120ºF.
 

                          11.  TOXICOLOGICAL INFORMATION

 
For Titanium Dioxide
Trochimowicz, et al., J. Appl. Tox., 8, 383-385 (1988).
 
Oral LD50 (rat)               >24 g/kg
Dermal LD50 (rabbit)         >10 g/kg
Inhalation LC50 (rat)         >6.82 mg/l (4 hr)
 
E.I. DuPont's Haskel Toxicology Laboratory conducted lifetime inhalation studies 
of respirable titanium dioxide at levels up to 250 mg/m3: no compound related 
clinical signs of toxicity were seen in the exposed animals. Slight pulmonary 
fibrosis was seen at 50 to 250 mg/m3 respirable titanium dioxide but not at 10 
mg/m3. There was no evidence of cancer in animals exposed to 10 or 50 mg/m3 
respirable titanium dioxide. Microscopic lung tumors were in 17 percent of the 
rats exposed to 250 mg/m3 respirable titanium dioxide. The lung tumors observed 
in the rats were different from common human lung cancers, relative to anatomic 
type and location, and occurred only at dust levels which overwhelmed the 
animals lung clearance mechanism and therefore, are of questionable
biological relevance for man.
 
Results of a DuPont epidemiology study showed that employees who had been 
exposed to titanium dioxide pigments were at no greater risk of developing lung 
cancer than were employees who had not been exposed to titanium dioxide 
pigments. No pulmonary fibrosis was found in any of the employees and no 
associations were observed between titanium dioxide pigment exposure and chronic 
respiratory disease or lung abnormalities. Based on the results of this study, 
DuPont concluded that titanium dioxide pigment will not cause lung cancer or 
chronic respiratory disease in humans at concentrations experienced in the 
workplace. 
 
The National Cancer Institute (NCI) conducted a feed study in rats and mice in 
which either 25,000 or 50,000 parts per million titanium dioxide was given in 
their diet for two years. Under the condition of the NCI test, titanium dioxide 
did not cause cancer by the oral route. 
 
Titanium dioxide has been classified by the American Congress of Governmental 
Industrial Hygienists (ACGIH) as an A4 Carcinogen - Not Classifiable as a Human 
Carcinogen. ("1999 TLVs and BEIs,"  p. 67). It has been classified by the 
International Agency for Research on Cancer (IARC) as Group 3 - Not Classifiable 
as to Its Carcinogenicity to Humans. (IARC Monograph 47, 1989).
 
For Product;   None for Product
 
For Carbon Black:   IARC - Group 2B (Possibly carcinogenic to humans)
 

                           12.  ECOLOGICAL INFORMATION

 
For Product:   Not established. 
 

                           13.  DISPOSAL CONSIDERATIONS

 
RCRA Waste Code:   Not Regulated. 
 
Do not allow material to enter sewer systems. Observe all applicable federal, 
state, and local regulations.
 

                            14.  TRANSPORT INFORMATION

 
DOT Proper Shipping Name:   Not regulated for ground transport.
 

                           15.  REGULATORY INFORMATION

 
OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200)
   __Hazardous         X Non-Hazardous
 
CERCLA/SUPERFUND (40 CFR 117,302)
 
      Chemical Name         RQ (lbs) / (kg)
--------------------------------------------------------------------------------
      N/A                     N/A
 
SARA EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355)
 
      Chemical Name         TPQ (lbs)   RQ (lbs)
--------------------------------------------------------------------------------
      N/A                     N/A          N/A
 
SARA HAZARD CATEGORIES (40 CFR 370)
 
__Acute   __Chronic   __Fire      __Pressure   __Reactive      X  None
 
SARA TOXIC CHEMICALS (40 CFR 372)
 
      Chemical Name      CAS Number      %
--------------------------------------------------------------------------------
      N/A            N/A         N/A
 
WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM
(CPR Section (33))
This product has been classified according to the hazard criteria of the 
Controlled Products Regulations, and the MSDS contains all required information.
 
   3 Controlled Product: Classification: D2B     __Not a Controlled Product
 
INVENTORY STATUS
 
The ingredients of this chemical are listed on the US TSCA Chemical Substance 
Inventory and the Canadian Domestic Substances List. 
 
TOXIC SUBSTANCES CONTROL ACT
 
No specific regulations apply.
 
STATE REGULATIONS
California Proposition 65         Crystalline Silica
Massachusetts Right to Know List      Carbon Black, Titanium Dioxide
Minnesota Hazardous Substance List      Carbon Black, Titanium Dioxide
New Jersey Right to Know List      Carbon Black (SN 0342, Titanium Dioxide   
                  (SN 1861)
Pennsylvania Right to Know List      Carbon Black, Titanium Dioxide
Rhode Island Hazardous Substance List   Carbon Black, Titanium Dioxide
 

                              16.  OTHER INFORMATION

 
ABBREVIATIONS
C- Ceiling limit
LC Lo- The lowest concentration of a substance in air that will kill a test 
animal within a
certain exposure period. 
LC50- The concentration of a substance in air that will kill 50% of test animals 
within a certain exposure period. 
LD50- The dose that causes death in 50% of test animals. 
N/A- Not applicable
N/D- Not determined
N/E- Not established
N/K- Not known
NAERG- North American Emergency Response Guidebook
RQ- Reportable Quantity
TPQ- Threshold Planning Quantity
 
PREPARATION INFORMATION
 
Prepared by:      Manus Chemical Safety and Health Department
MSDS No.:      MANUS-BOND 64-A BUTYL TAPE
Date Prepared:      January 9,2004
Date of Issue;      January, 2004
Supersedes:      December 3, 2000
 

The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance.

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