MSDS Sheet 4636-4

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MATERIAL SAFETY DATA SHEET Imperial Brake Parts Cleaner Flammability: 4 Instability: 0 Health; 2 Special: - Revision: Printed: 02/14/2005 Date Created: 01/25/2002 1. PRODUCT AND COMPANY IDENTIFICATION Product Code: 4636-4, 4636-3 & 4736 Product Name: Imperial Brake Parts Cleaner Reference #: LAB 306-J Manufacturer Information Company Name; Imperial Supplies LLC 789 Packer Drive P.O. Box 11008 Green Bay, WI. 54307-1008 Emergency Contact 1: Chem Tel (800) 255-3924 Information Contact: (800) 558-2808 2. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Components CAS # Percentage OSHA ACGIH Other Limits (Chemical Name) PEL TLV -------------------------------------------------------------------------------- 1. Heptane 142-82-5 18.0-25.0 % 500 PPM 500 PPM 400 STEL 2. Methylcyclohexane 108-87-2 1.0 - 5.0 % 400 PPM 400 PPM 500 PPM 3.OCTANE MIXTURE NA 1.0-5.0 % 375 PPM 300 PPM 300 STEL 4. Cyclohexane 110-82-7 0.0-3.0 % 300 PPM 300 PPM No data. 5. Toluene 108-88-3 12.0-25.0 % 150 PPM 50 PPM No data. 6. Benzene 71-43-2 0.0-0.018 % No data No data No data 7. Acetone 67-64-1 40.0-60.0 % No data No data No data Hazardous Components RTECS # OSHA OSHA ACGIH ACGIH (Chemial Name) STEL CEIL STEL CEIL -------------------------------------------------------------------------------- 1. Heptane M17700000 No data No data No data No data 2. Methylcyclohexane GV6125000 No data No data No data No data 3. OCTANE MIXTURE NA No data No data No data No data 4. Cyclohexane GU6300000 No data No data No data No data 5. Toluene XS5250000 No data No data No data No data 6. Benzene CY1400000 No data No data No data No data 7. Acetone AL3150000 No data No data No data No data 3. HAZARDS IDENTIFICATION Emergency Overview PHYSICAL STATE; LIQUID COLOR; TRANSPARENT, COLORLESS LIQUID ODOR; LIGHT PARAFFINIC HYDROCARBONS DANGER! Extremely Flammable Liquid: vapor may cause flash fire or explosion! Mist or vapor may irritate the eyes, mucous membranes, and respiratory tract! Liquid contact may cause minimal to mild eye and/or mild to moderate skin irritation and inflammation! May be harmful if inhaled or absorbed through the skin! Over exposure may cause central nervous system (CNS) depression and/or other target organ effects! May be harmful or fatal if ingested! Aspiration into the lungs can cause pulmonary edema and chemical pneumonia! Prolonged and/or repeated inhalation may increase the heart's susceptibility to arrhythmias (irregular beats)! Based upon animal testing, may adversely affect reproduction! Spills may crate a slipping hazard! Route(s) of Entry: Inhalation? Yes Skin? Yes Eyes? Yes Ingestion? Yes Potential Health Effects (Acute and Chronic) EYE CONTACT; Animal test results on similar materials suggest that this product can cause minimal to mild eye irritation upon short-term exposure. Symptoms include stinging, watering, redness, and swelling. SKIN CONTACT; Animal test results on similar material suggest that this product can cause mild to moderate skin irritation. Short-term contact symptoms include redness, itching, and burning of the skin. This material may also be absorbed though the skin and produce CNS depression effects (see inhalation). If the skin is damaged, absorption increases. Prolonged and/or repeated contact may cause moderate to severe dermatitis. Chronic symptoms may include drying, swelling, scaling, blistering, cracking and severe tissue damage. INHALATION: Breathing high concentrations of vapor may cause respiratory irritation, euphoria, excitation or giddiness, headache, nausea, vomiting, abdominal pain, loss of appetite, fatigue, muscular weakness, staggering gait, and central nervous system (CNS) depression. CNS effects include dizziness, drowsiness, disorientation, vertigo, memory loss, visual disturbances, difficulty with breathing, convulsions, unconsciousness, paralysis, coma and even death, depending upon the exposure concentration and/or duration. Vapors can reduce the oxygen content in air. Approximately 20,000 ppm (or 2 vol%) in air is fatal to humans in 5 to 10 minutes. Sudden death from cardiac arrest (heart attack) may result from exposure to 5,000 to 10,000 ppm for only 5 minutes. Oxygen deprivation is possible if working in confined spaces. INGESTION; If swallowed this material may irritate the mucous membranes of the mouth, throat, and esophagus. It can be readily absorbed by the stomach and intestinal tract. Symptoms include a burning sensation of the mouth and esophagus, nausea, vomiting, dizziness, staggering gait, drowsiness, loss of consciousness and delirium. Additional central nervous system (CNS) effects may occur prior to the onset of convulsions, coma and death. Due to its light viscosity, there is a danger of aspiration into the lungs during vomiting. Aspiration can result in severe lung damage or death. Progressive CNS depression, respiratory insufficiency, and ventricular fibrillation may also result in death. CHRONIC HEALTH EFFECTS SUMMARY; Chronic effects of ingestion and subsequent aspiration into the lungs may cause pneumatocele (lung cavity) formation and chronic lung dysfunction. Reports have associated repeated and prolonged occupational over exposure to solvents with irreversible brain and nervous system damage (sometimes called "solvent or Painter's Syndrome"). Intentional misuse by deliberately concentrating and inhaling this product may be harmful or fatal. Available information indicates that toluene is NOT teratogenic, but it can be toxic to the embryo and fetus and may reduce fertility. In animal tests, high inhaled doses of toluene has caused reduced litter seizers, retarded development of the fetus, and increased incidence of non-lethal abnormalities. Signs and Symptoms Of Exposure SEE HEALTH HAZARD SECTION Medical Conditions Generally Aggravated By Exposure Women attempting to conceive should avoid exposure to this product. Personnel with pre-existing central nervous system disease, neurological conditions, skin disorders, liver, or kidney function, or chronic respiratory diseases. Exposure to high concentrations of this material may increase the sensitivity of the heart to epinephrine (adrenalin) and catecholamine-like drugs. Personnel with pre-existing cardiac disorders may be more susceptible to this effect. OSHA Hazard Classes; HEALTH HAZARDS; Reproductive Toxin, Irritant, Sensitizer PHYSICAL HAZARDS; Explosive, Flammable Liquid/Sol TARGET ORGANS & EFFECTS: Lungs, Kidney, Eyes, Skin, Liver, Central Nervous System, Mucous Membranes, Blood. 4. FIRST AID MEASURES Emergency and First Aid Procedures EYE CONTACT: Check for and remove contact lenses. If irritation or redness develops, flush eyes with cool, clean low-pressure water for at least 15 minutes. Hold eyelids apart to ensure complete irrigation of the eye and eyelid tissue. Do not use eye ointment. Seek medical attention immediately. SKIN CONTACT; Remove contaminated shoes and clothing. Flush affected area with large amounts of water. If skin surface is damaged, apply a clean dressing and seek medical attention. Do not use ointments. If skin surface is not damaged, clean affected area thoroughly with mild soap and water. Seek medical attention if tissue appears damaged or if pain or irritation persists. INHALATION; Immediately remove the affected victim to fresh air. Administer artificial respiration if breathing is stopped. If heart has stopped, immediately begin cardiopulmonary resuscitation (CPR). If breathing is difficult, 100 percent humidified oxygen should be administered by a qualified individual. Seek medical attention immediately. INGESTION: Do NOT induce vomiting or give anything by mouth. If spontaneous vomiting is about to occur, place victim's head below knees. If victim is drowsy or unconscious, place on the left side with head down. Never give anything by mouth to a person who is not fully conscious. Do not leave victim unattended. Seek medical attention immediately. Note to Physician NOTES TO PHYSICIAN; Inhalation overexposure can product toxic effects. Monitor for respiratory distress. If cough or difficulty in breathing develops, evaluate for upper respiratory tract inflammation, bronchitis, and pneumonitis Vigorous anti-inflammatory/steroid treatment may be required at first evidence of upper airway or pulmonary edema. Administer 100 percent humidified supplemental oxygen with assisted ventilation, as required. If ingested, this material presents a significant aspiration/chemical pneumonitis hazard. As a result induction of emesis is not recommended. Administer an aqueous slurry of activated charcoal followed by a cathartic such as magnesium citrate or orbital. Also, treatment may involve careful gastric lavage if performed soon after ingestion or in patients who are comatose or at risk of convulsing. Protect the airway be cuffed end tracheal intubations or by placement of the body in a Trendelenburg and left lateral decubitus position. Obtain chest x-ray and liver function tests. Monitor for cardiac function, respiratory distress and arterial blood gases in severe exposure cases. Epinephrine and other sympathomimetic drugs may initiate cardiac arrhythmias (irregular beating) in persons exposed to high concentrations of this material (e.g. in enclosed spaces or with deliberate abuse). If used, monitor heart action closely. Consider use of other drugs with less arrhythmogenic potential. 5. FIRE FIGHTING MEASURES Flash Point 1.90 F (-16.7 C) Method: Pure Acetone Explosive Limits: LEL; No data UEL: No data. Autoignition Point No data. Fire Fighting Instructions Firefighters must use full bunker gear including NIOSH-approved positive pressure self-contained breathing apparatus to protect against potential hazardous combustion or decomposition products and oxygen deficiencies. Evacuate area and fight the fire from a maximum distance or use unmanned hose holders or monitor nozzles. Cover pooling liquid with foam. Containers can build pressure if exposed to radiant heat: cool adjacent containers with flooding quantities of water until well after the fire is out. Withdraw immediately from the area if there is a rising sound from venting safety devices or discoloration of vessels, tanks or pipelines. Be aware that burning liquid will float on water. Notify appropriate authorities if liquid(s) enter sewers/waterways. Flammable Properties and Hazards EXTREMELY FLAMMABLE LIQUID! This material releases vapors at or below ambient temperatures. When mixed with air in certain proportions and exposed to an ignition source, its vapor can cause a flash fire. Use only with adequate ventilation. Vapors are heavier than air and may travel long distances along the ground to an ignition source and flash back. May create vapor/air explosion hazard in confined spaces such as sewers. If container is not properly cooled, it can rupture in the heat of a fire. Hazardous Combustion Products Smoke, carbon monoxide, carbon dioxide. Extinguishing Media SMALL FIRE; Use dry chemicals, carbon dioxide (CO2), foam, water fog, or inert gas (nitrogen). LARGE FIRE; use foam, water fog or water spray. Water fog and spray are effective in cooling containers and adjacent structures but might cause frothing and/or may not achieve extinguishment. A water jet may be used to cool the vessel's external walls to prevent pressure build-up, autoigniton, or explosion. Never use a water jet directly on the fire because it may spread the fire to a large area. 6. ACCIDENTAL RELEASE MEASURES Steps To Be Taken In Case Material Is Released Or Spilled Flammable Liquid! Release causes an immediate fire or explosion hazard. Evacuate all non-essential personnel from immediate area and establish a "regulated zone" with site control and security. A vapor-suppressing foam may be used to reduce vapors. Eliminate all ignition sources. All equipment used when handling this material must be grounded. Stop the leak if it can be done without risk. Do not touch or walk through spilled material. Remove spillage immediately from hard, smooth walking areas. Prevent its entry into waterways, sewers, basements, or confined areas. Absorb or cover with dry earth, sand, or other non-combustible material and transfer to appropriate waste containers. Use clean, non-sparking tools to collect absorbed material. For large spills, secure the area and control access. Dike far ahead of a liquid spill to ensure complete collection. Water mist or spray may be used to reduce or disperse vapors: but it may not prevent ignition in closed spaces. This material will float on water and its run-off may create an explosion or fire hazard. Verify that responders are properly HAZWOPER- trained and wearing appropriate respiratory equipment and fire-resistant protective clothing during cleanup operations. In an urban area, cleanup spill as soon as possible. In natural environments, cleanup on advise from a specialists. Pick up free liquid for recycle and/or disposal if it can be accomplished safely with explosion-proof equipment. Collect any excess material with absorbent pads, sand, or other inert non-combustible absorbent materials. Place into appropriate waste containers for later disposal. Comply with all laws and regulations. 7. HANDLING AND STORAGE Precautions To Be Taken In Handling HANDLING: A spill or leak can cause an immediate fire/explosion hazard. Keep containers closed and do not handle or store near heat, sparks, or any other potential ignition sources. Bond and ground all equipment before transferring this material from one container to another. Do not contact with oxidizable materials. Do not breathe vapor. Use only with adequate ventilation/ personal protection. Never siphon by mouth. Avoid contact with eyes, skin and clothing. Prevent contact with food, chewing or smoking material. Do not take internally. When performing repairs and maintenance on contaminated equipment, keep unnecessary persons away from the area. Eliminate all potential ignition sources. Drain and purge equipment, as necessary, to remove material residues. Use gloves constructed of impervious materials. And protective clothing if direct contact is anticipated. Provide ventilation to maintain exposure potential below applicable exposure limits. Promptly remove contaminated clothing. Wash exposed skin thoroughly with mild soap and water after handling. Empty containers may contain material residues which can ignite with explosive force. Misuse of empty containers can be dangerous if used to store toxic, flammable, or reactive materials. Cutting or welding of empty containers can cause fire, explosion or release of toxic fumes from residues. Do not pressurize or expose empty containers to open flame, sparks or heat. Keep container closed and drum bungs in place. All label warnings and precautions must be observed. Return empty drums to a qualified reconditioner. Consult appropriate federal, state, and local authorities before reusing, reconditioning, reclaiming, recycling or disposing of empty containers and/or waste residues of this material. Precautions To Be Taking In Storing STORAGE; Store and transport in accordance with all applicable laws. Keep containers closed and store in a cool, dry, well-ventilated place, plainly labeled, and out of closed vehicles. Keep away from all ignition sources! Ground all equipment containing this material. Containers should be able to withstand pressures expected from warming and cooling in storage. This flammable liquid should be stored in a separate safety cabinet or room, and preferably refrigerated. All electrical equipment in areas where this material is stored or handled should be installed in accordance with applicable requirements of the NFPA's national Electrical code (NEC). Other Precautions None 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Respiratory Equipment (Specify Type) For unknown vapor concentrations use a positive-pressure-demand, self-contained breathing apparatus (SCBA). For known vapor concentrations above the occupational exposure guidelines (see below) use a NIOSH-approved organic vapor respirator if adequate protection is provided. Protection factors vary depending upon the type of respirator used. Respirator use should follow OSHA requirements (29CFR 1910.134) or equivalent standard. Eye Protection Safety glasses with side shields are recommended as a minimum protection. During transfer operations or when there is a likelihood of misting, splashing, or spraying, chemical goggles and face shield should be worn. Suitable eye wash water should be readily available. Protective Gloves Avoid skin contact and use gloves (disposable PVC, neoprene, nitrile vinyl or PVC/NBR). Before eating, drinking, smoking, use of toilet facilities, or leaving work, wash hands with plenty of mild soap and water. Do NOT use gasoline, kerosene, other solvents, or harsh abrasive skin cleaners. Other Protective Clothing Avoid skin contact. It is recommended that fire-retardant garments (eg Nomex) be worn while working with flammable and combustible liquids. If splashing or spraying is expected, chemical-resistant protective clothing should be worn (Tyvek, nitrile or neoprene). This might include long-sleeves, apron, slicker suit, boots and additional facial protection. If general contact occurs, immediately remove soaked clothing and take a shower. Contaminated leather goods should be removed promptly and discarded. Engineering Controls (Ventilation etc.) Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapor and/or mists below the pertinent exposure limits (see below). All electrical equipment should comply with the NFPA NEC standards. Ensure that an emergency eye wash station and safety shower are near the work-station location. Work/Hygienic/Maintenance Practices Personal protective equipment should be selected based upon the conditions under which this material is used. A hazard assessment of the work area for PPE requirements should be conducted by a qualified professional pursuant to OSHA regulations. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical States: [ ] Gas [X] Liquid [ ] Solid Melting Point No data. Boiling Point No data Specific Gravity: 0.775 Density: No data Vapor Pressure: No data Vapor Density: No data Evaporation Rate; No data Solubility in Water: No data Other Solubility Notes; Not soluble Percent Volatile: No data VOC / Volume: 45.0000 HAP / Volume: 0.0000 Saturated Vapor Concentration; No data Viscosity: No data pH; No data Appearance and Odor Clear colorless liquid with a hydrocarbon odor. 10. STABILITY AND REACTIVITY Stability; Unstable [ ] Stable [X] Conditions To Avoid - Instability Keep away from extreme heat, strong acids, and strong oxidizing conditions. Incompatibility - Materials To Avoid Strong acids, alkalies, and oxidizers such as liquid chlorine, hydrogen peroxide and oxygen. n-Heptane will dissolve some plastics. Hazardous Decomposition Or Byproducts No substances are readily identified from composition: but, no degradation data is available. Hazardous Polymerization: Will occur [ ] Will not occur [X] Conditions To Avoid - Hazardous Polymerization Will Not Occur 11. TOXICOLOGICAL INFORMATION Toxicological Information Acetone: INHALATION (LC50): 50,000 mg/m3 8 hours (Rat) DERMAL (LD50): 20,000 gm/kg (Rabbit) INGESTION (LD50): 5.8 g/kg (Rat) Cyclohexane: GAS (LC50): Acute: 22,500 ppm for 4 hours (Rabbit) ORAL (LD50): Acute: 12,705 mg/kg (Rat) ORAL (LD50): Acute: 813 to 1300 mg/kg (Mouse) ORAL (LD50) Acute: GT 180,000 mg/kg (Rabbit) - Severe diarrhea, vascular damage and collapse, hepatocellular degeneration, and glomerulonephritis. Toluene: ORAL (LD50) Acute; 636 mg/kg or (Rat) ORAL (LD50) Acute: 4,000 mg/kg or (Cat) GAS (LC50) Acute: 400 ppm for 24 hours (Mouse) GAS (LC50) Acute: 49,000 mg/m3 for 4 hours (Rat) GAS (LC50) Acute: 5,320 ppm for 8 hours (Mouse) DERMAL (LC50) Acute: 14,100 uL/kg or 12,125 mg/kg (Rabbit) INTRAVENOUS (LD50) Acute: 1960 mg/kg (Rat) INTRAVENOUS (LD50) Acute: 2,000 gm/kg (Mouse) n-Heptane: Gas LC50; Acute: 103,000 mg/m3 for 4 hours (rat)-convulsions: Dermal LD50: Acute > 2,000 mg/kg rabbit Intravenous LD50: Acute 222 mg/kg mouse Methylcyclohexane: ORAL LD50: Acute 2250 mg/kg mouse GAS LC50: Acute 41,500 mg/m3 for 2 hours mouse-hyper motility and diarrhea. GAS LC50; Acute: 15,227 ppm for 1 hour, rabbit-general anesthetic, convulsions, and changes in the salivary glands. n-Octane: Gas (LC50) Acute: 118,000 mg/m3 for 4 hours, rat. Cyclohexane is an eye, skin and mucous membrane irritant, CNS depressant, and causes narcosis at high concentrations in air. There is a narrow margin between narcosis, loss of reflexes, and death. In experimental animals exposed to lethal concentrations by inhalation or oral route, there was generalized vascular damage and severe degenerative changes in the heart, lungs, liver, kidneys, and brain. Cyclohexane does not act as a promoter for tumors or mice when exposed to dimethylbenzanthracene: and, it did not induce unscheduled DNA synthesis in cultured human lymphocytes. It is not mutagenic in the Salmonella/micosome (Ames) or the mouse lymphoma L5178Y assays, with or without metabolic activation: however, it did increase the number of chromosomal aberrations in bone marrow cells of rats exposed to between 100 and 300 ppm for 6 hours/day for 5 days. These chromosomal aberrations did not appear to be dose-related. Toluene (methylbenzene) has been a major solvent of intentional inhalation abuse. Deliberate long-term inhalation of high concentrations of toluene (glue sniffing, etc.) (has been shown to cause liver, kidney, central nervous system, and permanent brain damage. Effects such as impaired speech, visual disturbances, and hearing loss, loss of balance and/or muscle control, and memory loss have been reported. Exposures of 100 to 200 ppm in the air for 24 hours cause hallucinations, distorted perceptions, and changes in motor activity. Studies have indicated that children of women who sniffed massive exposure of toluene during pregnancy are at significant risk for pre-term delivery, prenatal death, growth retardation, and other adverse developmental effects. Isolated case reports have suggested a spectrum of congenital defects similar to those seen in fetal alcohol (ethanol) syndrome. These children's defects included microcephaly (small head size), central nervous system (CNS) eficiencies, facial abnormalities, and reduced growth rate. Animal studies suggest that toluene causes kidney, liver, and/or lung dysfunction and cardiac (heart muscle) sensitization to epinephrine or other adrenalin-like agents. This sensitization may cause fatal changes in heart beat rhythms. Also, this later effect was shown to be enhanced by hypoxia (oxygen deficiency). Long-term rodent inhalation studies with toluene produced kidney damage, enlargement of the liver and thymus, heart palpitations, brain damage, general weakness, and impaired reaction time. Also, rats exposed to 1,200 ppm and 1,400 ppm of toluene in air for 14 hours per day for 5 or 4 weeks (respectively) exhibited high-frequency hearing loss. Several animal studies using pregnant rodents have shown that toluene exposures may all cause embryo and/or feto-toxicity. Adverse effects include decreased fetal body weight and increased skeletal variations. In chronic feeding and inhalation studies, toluene has not been shown to be carcinogenic, nor is it mutagenic in the Salmonella/microsome (Ames) assay, the in-vivo rat bone marrow cell chromosome aberrations assay, the in-virto mouse lymphoma assay, 8-week dominant lethal assay, and the in-vitro human adult male lymphocyte ister chromatid exchanges assay. The significance of these animal study results to humans is not known. 2,2,4-Trimethylpentane (Iso-octane) was highly irritating to mice at a 1,000 ppm in air exposure for 5 minutes and respiratory arrest occurred at exposure above 10,000 ppm for 5 minutes. CNS depression was observed at concentrations between 8,000 and 10,000 ppm in air. Kidney tubule necrosis, hyaline droplet formation, and acute renal failure were seen in male rats following oral administration of 10 gm/kg, 8 mL/kg, or 2,100 mg/kg of iso-octane for 2,3, and 4 weeks, respectively. n-Heptane is a mucous membrane and respiratory tract irritant, but non-irritating to the eyes. It is irritating to the skin and readily absorbed by either inhalation or dermal exposure. Exposure may cause decreased red blood cell counts, liver and heart damage, and central nervous system depression. Repeated direct skin application can produce defatting dermatitis. n-Heptane is metabolized in the liver to form alcohols and ketones, including nuerotoxic 2,5 heptanedione which is detectable in small amounts in the urine of exposed humans. In a controlled study, human volunteers exposed to an airborne concentration of n-heptane of 1,000 ppm for 6 minute or 2,000 ppm for 4 minutes experienced slight dizziness and incoordination. Higher-level exposures produced hilarity, dizziness, and semi-consciousness. Inhaling a concentration of 5,000 ppm for 15 minutes caused stupor and a gasoline-like taste. These higher exposures also decreased the myocardial threshold to the arrhythmogenic effects (irregular heart beats) of epinephrine, producing only a narrow margin of safety between exposures causing CNS effects, cardiac effects, and loss of consciousness. One occupational exposure study involving a 95% purity n-heptane from 1-9 years duration concluded that it could produce minimal peripheral nerve damage with numbness and tingling of the extremities in the stocking-and-glove areas. In the same study, there was a decrease in motor nerve conduction velocities correlated with duration of exposure and adjusted for age effects: however, the average motor nerve conduction velocity in exposed workers was normal. Polyneuropathy associated with n-heptan exposure was reversible within a year following removal of exposure. n-Heptane was not neurotoxic to rats exposed for up to 7 months. But based upon limited lab animal studies, n-heptane and its metabolites were found in low levels (<135 ppm) in the brain or rats exposed to airborne concentrations of 100, 500, or 1500 ppm for 6 hours each day, five days per week, for 1 or 2 weeks. These substances disappeared within 2 weeks following removal of exposure. N-Heptane was not mutagenic in the Salmonella/microsome (Ames) assay and is not expected to be carcinogenic. Rats inhaling methylcyclohexane at an airborne concentration of 15,250 ppm for 1 hour displayed tremors, loss of coordination, anesthesia, and convulsions. Inhalation of 10,050 ppm for 6 hours per day for 14 days showed rodent weight loss or decreases weight gain and changes in the structure of their salivary glands. Using rabbits, methylcyclohexane was shown to have an LD50 somewhere between 3300 ppm and 7300 ppm when exposed repeatedly for 6 hours per day, 5 days per week, for 3 weeks. Death was preceded by conjunctival congestion with mucoid secretion and lacrimation, salivation, coughing, sneezing, labored breathing, and diarrhea. Lethal oral dosing of rabbits caused lethargy, severe diarrhea, and circulatory collapse. Vascular and degenerative lesions were observed in the kidneys and liver. Carcinogenicity/Other Information This product does not contain any components at concentrations above .1% which are considered carcinogenic by OSHA, IARC, or NTP. Carcinogenity: NTP? No IARC Monographs? No OSHA Regulated? No 12. ECOLOGICAL INFORMATION Ecological Information Ecological effects testing has not been conducted on this material. If released from its container, this material will probably contribute to the creation of atmospheric smog. N-Heptane, heptane isomers and octane isomers all have estimated half-lives of between 2.4 and 4.4 days in air when photochemical hydroxyl and/or nitrate radicals are present. Toluene has a half-life of from 3 hours to slightly over 1 day and cyclohexane has a half-life of from 6 hours to over 4 days when hydroxyl radicals are present. ENVIRONMENTAL FATE: For additional ecological information concerning components of this product, users should refer to the Hazardous Substances Data Bank and the Oll and Hazardous Materials/Technical Assistance Data System (OHM/TADS) maintained by the US National Library of Medicine. 13. DISPOSAL CONSIDERATIONS Waste Disposal Method Hazard characteristics and regulatory waste stream classification can change with product use. Accordingly, it is the responsibility of the user to determine the proper storage, transportation, treatment and/or disposal methodologies for spent materials and residues at the time of disposition. Recovered non-usable material may be regulated by US EPA as a hazardous waste due to its ignitability (D001) and / or its toxic (D018) characteristics. In addition, conditions of use may cause this material to become a hazardous waste, as defined by Federal or State regulations. It is the responsibility of the user to determine if the material is a RCRA "hazardous waste" at the time of disposal. Transportation, treatment, storage, and disposal of waste material must be conducted in accordance with RCRA regulations (see 40 CFR parts 260-271). State and/or local regulations might be even more restrictive. Contact the RCRA/Superfund Hotline at 800-424-9346 or your nearest regional US EPA office for guidance concerning case specific disposal issues. 14. TRANSPORT INFORMATION LAND TRANSPORT (US DOT) DOT Proper Shipping Name Flammable liquids, (acetone, heptane), 3, UN 1993, PG II DOT Hazard Class: 3 DOT Hazard Label: FLAMMABLE LIQUID UN/NA Number: UN1993 DOT Packing Group: II Additional Transport Information Per 49CFR, this product may be reclassed as a Consumer Commodity ORM-D Shipment with in the US. 15. REGULATORY INFORMATION US EPA SARA Title III Hazardous Components CAS # Sec. 302 Sec. 304 Sec. 313 Sec. 110 (Chemical Name) (EHS) RQ (TRI) -------------------------------------------------------------------------------- 1. Heptane 142-82-5 No No No No 2. Methylcyclohexane 108-87-2 No No No No 3. OCTANE MIXTURE NA No No No No 4. Cyclohexane 110-82-7 No Yes 1000LB Yes No 5. Toluene 108-88-3 No Yes 1000LB Yes Yes 6. Benzene 71-43-2 No Yes 10 LB Yes Yes 7. Acetone 67-64-1 No Yes 5000LB No Yes US EPA CAA, CWA, TSCA Hazardous Components CAS # EPA CAA EPA CWA EPA TSCA CA PROP (Chemical Name) NPDES 65 -------------------------------------------------------------------------------- 1. Heptane 142-82-5 No No 8A PAIR, 8D No 2. Methylcyclohexane 108-87-2 No No 8A PAIR, 8D No 3. OCTANE MIXTURE NA No No No No 4. Cyclohexane 110-82-7 No Yes 8A PAIR,8D No TERM 5. Toluene 108-88-3 HAP Yes 8A CAIR, 8A Yes PAIR 6. Benzene 71-43-2 HAP YES 8A CAIR Yes 7. Acetone 67-64-1 No No No No SARA (Superfund Amendments and Reauthorization Act of 1986) Sec. 302: EPA SARA Title III Section 302 Extremely Hazardous Chemical With TPQ. * indicates 10000 LB TPQ if not volatile. Sec. 304: EPA SARA Title III section 304: CERCLA Reportable + Sec. 302 With Reportable Quantity. ** indicates statutory RQ. Sec. 313: EPA SARA Title III Section 313 Toxic Release Inventory. Note: -Cat indicates a member of a chemical category. Sec. 110; EPA SARA 110 Superfund Site Priority Contaminant List. Other Important Lists: CWA NPDES: EPA Clean Water Act NPDES Permit Chemical CAA HAP: EPA Clean Air Act Hazardous Air Pollutant. CAA ODC: EPA Clean Air Act Ozone Depleting Chemical (1=CFC,2=HCFC) CA PROP 65: California Proposition 65 TSCA (Toxic Substances Control Act) Lists: 5A (2): Chemical Subject to Significant New Rules (SNURS) 6A: Commercial Chemical Control Rules 8A: Toxic Substances Subject To Information Rules on Production 8A CAIR: Comprehensive Assessment Information Rules - (CAIR) 8A PAIR: Preliminary Assessment Information Rules - (PAIR) 8C; Records of Allegations of Significant Adverse Reactions 8D: Health and Safety Data Reporting Rules 8D TERM: Health and Safety Data Reporting Rule Terminations Regulatory Information TSCA: This product and/or its components are listed on the Toxic Substances Control Act (TSCA) inventory. Prop 65: This material may contain the following chemical substances which are known to the State of California to cause cancer, birth defects or other reproductive harm: and therefore it may be subject to requirements of California Health and Safety Code Section 25249.5: Benzene 71-43-2 and Toluene 108-88-3 Under Section 12(b) of the Toxic Substances Control Act: Because it contains detectable amounts of cyclohexane, this product might be subject to US EPA's one-time only per country export notification requirements. In regulations promulgated pursuant to the Clean Air Act - Section 111 "Standards of Performance for New Stationary Sources" (40CFR 60.489). the EPA classifies the following minor components of this material as "Volatile Organic Compounds (VOCs)" which contribute significantly to air pollution which endangers public health and welfare: Cyclohexane, benzene, methylcycloheanxe, and toluene. Under the Federal Hazardous Substances Act. Related statues, and Consumer Product Safety Commission regulations, as defined by 116 CFR 15.0014 (b)(3) AND 1500.83 (A)(13): This product contains Petroleum distillates which may require special labeling if distributed in a manner intended or packaged in a form suitable for use in the household or by children. Precautionary label dialogue should display the following; Contains Petroleum Distillates. May be harmful or fatal if swallowed! Keep out of the reach of children. EPA Hazard Categories; This material meets the EPA "Hazard Categories" defined for SARA Title III Sections 311/312 as indicated: [X] Yes [ ] No Acute (immediate) Health Hazard [X] Yes [ ] No Chronic (delayed) Health Hazard [X] Yes [ ] No Fire Hazard [ ] Yes [X] No Reactive Hazard [ ] Yes [X] No Sudden Release of Pressure Hazard The information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. Vendor assumes no responsibility for injury to vendee or third person proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Additionally, vendor assumes no responsibility for injury to vendee or third persons proximately caused by abnormal use of the material even if reasonable safety procedures are followed. Furthermore, vendee assumes all risk in use of the material. 16. OTHER INFORMATION THIS INFORMATION IS FURNISHED WITHOUT WARRANTY, EXPRESSED OR IMPLIED, EXCEPT THAT IS ACCURATE TO THE BEST KNOWLEDGE OF EXCELDA MANUFACTURING. THE DATA ON THIS SHEET RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED HEREIN. EXCELDA MANUFACTURING ASSUMES NO LEGAL RESPONSIBILITY FOR USE OR RELIANCE UPON THIS DATA. Licensed to Excelda Manufacturing, Inv. ANSI Format