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MSDS 4600-4 4600-4: Penetrating Oil 1 Gallon [6] (DISCONTINUED)4700: Pent Oil 16 Oz Trigger Bottle [12] MSDS Last updated: 12/21/2009
MATERIAL SAFETY DATA SHEET
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 4700-0 GALLON PENETRATING OIL
IDENTIFICATION NUMBER: 0147-107 DATE PRINTED: 08/06/09
PRODUCT USE/CLASS: PENETRATING OIL
SUPPLIER/DISTRIBUTOR MANUFACTURED BY:
IMPERIAL SUPPLIES LLC IMPERIAL SUPPLIES LLC
789 ARMED FORCES DRIVE 789 ARMED FORCES DRIVE
GREEN BAY, WI 54304 GREEN BAY, WI 54304
INFORMATION#: 800-558-2808 INFORMATION#: 800-558-2808
EMERGENCY#: 800-255-3924 EMERGENCY#: 800-255-3924
CHEM-TEL CHEM-TEL
PREPARER: CUSTOMER SERVICE, PHONE: PREPARE DATE: 08/06/09
SECTION 2 - COMPOSITION / INFORMATION ON INGREDIENTS
ITEM CHEMICAL NAME CAS NUMBER
WT/WT%
LESS THAN
01 HYDROTREATED, SEVERE, LT. 64742-52-5 70-80
NAPHTHENIC DIST.
02 HYDROTREATED MIDDLE DISTILLATES 64742-67-7 10-20
03 CYCLOHEXANONE 108-94-1 1-10
04 DISTILLATES, PETROLEUM, 64742-52-5 1-10
HYDROTREATED NAP
EXPOSURE LIMITS:
ACGIH OSHA COMPANY
ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN
01 5 MG/M3 10 MG/M3 MIS 5 MG/M3 N.E. N.E. NO
MIST MIST
02 5 MG/M3 N.E. 5 MG/M3 N.E. N.E. NO
MIST MIST
03 25 PPM N.E. 25 PPM 50 PPM SKIN N.E. YES
SKIN SKIN
04 5 MG/M3 10 MG/M3 5 MG/M3 N.E. N.E. YES
SKIN
(See Section 16 for abbreviation legend)
SECTION 3 - HAZARDS IDENTIFICATION
*** EMERGENCY OVERVIEW *** Vapors irritating to eyes and
respiratory tract. High vapor concentrations may cause
drowsiness.
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Liquid, aerosols and vapors
of this product are irritating and can cause pain, tearing,
reddening and swelling accompanied by a stinging sensation and/or
a feeling like that of fine dust in the eyes.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Prolonged or repeated
contact can result in defatting and drying of the skin which may
result in skin irritation and dermatitis (rash).
EFFECTS OF OVEREXPOSURE - INHALATION: Headaches, dizziness,
nausea, decreased blood pressure, changes in heart rate and
cyanosis may result from over-exposure to vapor or skin exposure.
Prolonged inhalation may be harmful.
EFFECTS OF OVEREXPOSURE - INGESTION: This material may be harmful
or fatal if swallowed.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Overexposure may cause
nervous system damage.
PRIMARY ROUTE(S) OF ENTRY:
SKIN CONTACT
INGESTION
SKIN ABSORPTION
EYE CONTACT
INHALATION
SECTION 4 - FIRST AID MEASURES
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of
water. Get medical attention, if irritation persists.
FIRST AID - SKIN CONTACT: Immediately flush skin with plenty of
water. Remove clothing. Get medical attention immediately. Wash
clothing separately before reuse.
FIRST AID - INHALATION: Remove to fresh air. If not breathing,
give artificial respiration. If breathing is difficult, give
oxygen. Get immediate medical attention.
FIRST AID - INGESTION: Get medical attention immediately. If
swallowed, do NOT induce vomiting. Give victim a glass of water
or milk. Call a physician or poison control center immediately.
Never give anything by mouth to an unconscious person.
SECTION 5 - FIRE FIGHTING MEASURES
FLASH POINT: LOWER EXPLOSIVE LIMIT: 0.7%.
111 F
UPPER EXPLOSIVE LIMIT: 9.4%
AUTO IGNITION TEMPERATURE: N.D.
EXTINGUISHING MEDIA: ALCOHOL FOAM CO2 DRY CHEMICAL FOAM
UNUSUAL FIRE AND EXPLOSION HAZARDS: "Empty" containers retain
product residue (liquid and/or vapor) and can be dangerous. DO NOT
PRESSURIZE, CUT, WELD, BRAZE,SOLDER, DRILL, GRIND, OR EXPOSE SUCH
CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER
SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
Empty drums should be completely drained, properly bunged and
promptly returned to a drum reconditioner, or properly disposed
of.
SPECIAL FIREFIGHTING PROCEDURES: Containers can build up pressure
if exposed to heat (fire). As in any fire, wear self-contained
breathing apparatus pressure-demand (MSHA/NIOSH approved or
equivalent) and full protective gear.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Absorb
spill with inert material (e.g. dry sand or earth)then place in a
chemical waste container. Avoid runoff into storm sewers and
ditches with lead to waterways.
SECTION 7 - HANDLING AND STORAGE
AEROSOL LEVEL: N/A
HANDLING: Wash thoroughly after handling.
STORAGE: Keep from freezing.
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: Good general ventilation should be
sufficient to control airborne levels. Local exhaust ventilation
may be necessary to control any air contaminants to within their
TLVs during the use of this product.
RESPIRATORY PROTECTION: A respiratory protection program that
meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed
whenever workplace conditions warrant a respirator's use.
SKIN PROTECTION: No Information.
EYE PROTECTION: Wear safety glasses with side shields (or goggles)
and a face shield
OTHER PROTECTIVE EQUIPMENT: STANDARD INDUSTRIAL CLOTHING
STANDARDS SHOULD BE FOLLOWED.
HYGIENIC PRACTICES: Wash hands before eating. Remove contaminated
clothing and wash before reuse. Use only in a well ventilated
area. Follow all MSDS/label precautions even after container is
emptied because they may retain product residues. Avoid prolonged
or repeated contact with skin. Avoid breathing vapors from heated
material. Avoid contact with eyes, skin, and clothing.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
BOILING RANGE: 309-563 F VAPOR DENSITY: Is heavier than
air
ODOR: PETROLUEM ODOR THRESHOLD: ND
APPEARANCE: AMBER LIQUID EVAPORATION Is faster than
RATE: Butyl Acetate
SOLUBILITY IN NIL
H20:
FREEZE POINT: ND SPECIFIC 0.8561
GRAVITY:
VAPOR PRESSURE: ND pH @ 0.0%: NA
PHYSICAL STATE LIQUID VISCOSITY: ND
COEFFICIENT OF WATER/OIL DISTRIBUTION: N.D.
VOLATILE ORGANIC COMPOUNDS (VOCS): 0.95 lbs/gal, 114 grams/lts
VOC, % (wt): 13.37%
(See Section 16 for abbreviation legend)
SECTION 10 - STABILITY AND REACTIVITY
CONDITIONS TO AVOID: ALL SOURCES OF IGNITION, WELDING ARCS, AND
OPEN FLAMES.
INCOMPATIBILITY: STRONG ACIDS, ALKALIS, OXIDIZERS, AND AMINES.
HAZARDOUS DECOMPOSITION PRODUCTS: OXIDES OF CARBON, OXIDES OF
NITROGEN, AND MAY PRODUCE FORMS OF CHLORIDE, CHLORINE, AND
PHOSGENE.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage
conditions.
SECTION 11 - TOXICOLOGICAL PROPERTIES
PRODUCT LD50: 5000 mg/kg
PRODUCT LC50: 4600 ppm
COMPONENT TOXICOLOGICAL INFORMATION:
CHEMICAL NAME LD50 LC50
HYDROTREATED, SEVERE, LT. NE NE
NAPHTHENIC DI
HYDROTREATED MIDDLE DISTILLATES >5000 MG/KG/RAT 4600 MG/M3/4H/RAT
CYCLOHEXANONE 162000 MG/KG/RAT >8000 GM/M3/4H/RAT
DISTILLATES,PETROLEUM, ND ND
HYDROTREATED
SECTION 12 - ECOLOGICAL INFORMATION
ECOLOGICAL INFORMATION: No Information.
SECTION 13 - DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: DISPOSE IN ACCORDANCE WITH ALL FEDERAL, STATE, AND LOCAL
REGULATIONS.
SECTION 14 - TRANSPORTATION INFORMATION
DOT PROPER SHIPPING NAME: CONSUMER COMMODITY
DOT TECHNICAL NAME:
DOT TECHNICAL NAME: ORM-D
DOT HAZARD CLASS: ORM-D HAZARD SUBCLASS:
DOT UN/NA NUMBER: PACKING GROUP: RESP. GUIDE PAGE:
DOT EXEMPTIONS:
DOT SPECIAL INSTRUCTIONS:
IMDG SHIPPING INFORMATION
UN1993
IMDG PROPER SHIPPING NAME: FLAMMABLE LIQUID, N.O.S.
IMDG TECHNICAL NAME: CYCLOHEXANONE
IMDG HAZARD CLASS: 3
HAZARD SUBCLASS:
PACKING GROUP: III
FLASH POINT, C:44
IMDG EXEMPTIONS: LIMITED QUANTITY
IATA SPECIAL INSTRUCTIONS:
SECTION 15 - REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS: AS FOLLOWS -
OSHA: Hazardous by definition of Hazard Communication Standard (29
CFR 1910.1200)
CERCLA -SARA HAZARD CATEGORY: This product has been reviewed
according to the EPA 'Hazard Categories' promulgated under
Sections 311 and 312 of the Superfund Amendment and
Reauthorization Act of 1986 (SARA Title III) and is considered,
under applicable definitions, to meet the following categories:
IMMEDIATE HEALTH HAZARD CHRONIC HEALTH HAZARD FIRE HAZARD
SARA SECTION 313:
This product contains the following substances subject to the
reporting requirements of
Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 and 40 CFR Part 372:
CHEMICAL NAME CAS NUMBER WT/WT% IS
LESS THAN
No SARA Section 313 components exist in this product.
TOXIC SUBSTANCES CONTROL ACT:
This product contains the following chemical substances subject to
the reporting requirements Of TSCA 12(B) if exported from the
United States:
CHEMICAL NAME CAS NUMBER
No information is available
U.S. STATE REGULATIONS: AS FOLLOWS -
NEW JERSEY RIGHT-TO-KNOW:
The following materials are non-hazardous, but are among the top
five components in this product:
CHEMICAL NAME CAS NUMBER
No non-hazardous materials are among the top five ingredients.
PENNSYLVANIA RIGHT TOKNOW:
The following nonhazardous ingredients are present in the product
at greater than 3%:
CHEMICAL NAME CAS NUMBER
No non-hazardous ingredients are present at greater than 3%.
CALIFORNIA PROPOSITION 65:
WARNING: The chemicals (s) noted below and contained in this
product, are known
To the state of California to cause cancer, birth defects or other
reproductive harm:
CHEMICAL NAME CAS NUMBER
No Proposition 65 chemicals exist in this product.
INTERNATIONAL REGULATIONS: AS FOLLOWS -
CANADIAN WHMIS: This MSDS has been prepared in compliance with
Controlled Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: No information available
SECTION 16 - OTHER INFORMATION
HMIS RATINGS - HEALTH:2
FLAMMABILITY: 1
REACTIVITY: 0
PREVIOUS MSDS REVISION DATE: 07/29/09
REASON FOR REVISION: UPDATE
LEGEND: N.A. - Not Applicable, N.E. - Not Established, N.D. -
Not Determined
*** THIS MSDS IS NOT FOR REPRODUCTION OR REPRODUCTION OR
DISTRIBUTION ***
The information contained on this MSDS has been checked and should
be accurate. However, it is the responsibility of the user to
comply with all Federal, State, and Local laws and regulations.
<END OF MSDS>
The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance. For more product information by email, click here Imperial Supplies LLC does not provide services and products outside the United States |
