SDS Sheet 0091290All MSDS Go Back
SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: 14H THREAD SEALANT W/PTFE 4 FL.OZ. CAS No: Synonyms: None 1.2. Intended Use of the Product Use of the substance/mixture: Sealant 1.3. Name, Address, and Telephone of the Responsible Party Company ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Phone: (877) 376-2839 1.4. Emergency Telephone Number Emergency |800-255-3924, 00+1+ 813-248-0585 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Acute toxicity|Category 4 - Oral | Carcinogenicit|Category 2 y | Specific |Category 1 target organ | toxicity | (single | exposure) | Flammable |Category 3 liquids | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Exclamation Mark |Health Hazard |Flame Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Harmful if swallowed |May cause cancer |Causes damage to organs |Flammable Liquid Precautionary Statements |Prevention: (GHS-US) |Obtain special instructions before use |Do not handle until all safety precautions have been |read and understood |Use personal protective equipment as required |Wash face, hands and any exposed skin thoroughly |after handling |Do not eat, drink or smoke when using this product |Do not breathe dust/fume/gas/mist/vapors/spray |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking |Keep container tightly closed |Take precautionary measures against static discharge | |Response: |IF exposed: Call a POISON CENTER or doctor/physician | |Specific treatment (see supplemental first aid |instructions on this label) |IF ON SKIN (or hair): Remove/Take off immediately |all contaminated clothing. Rinse skin with |water/shower |IF SWALLOWED: Call a POISON CENTER or |doctor/physician if you feel unwell |Rinse mouth |In case of fire: Use Water spray, fog or regular |foam for extinction |Storage: |Store locked up |Disposal: |Dispose of contents/container to an approved waste |disposal plant 2.3. Other Hazards Other Hazards Not Contributing to the Classification: Not applicable. 2.4. Unknown Acute Toxicity (GHS-US) 65.99515% of the mixture consists of ingredient(s) of unknown toxicity. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) TALC |14807-96-6 |15 - 40 | ETHANOL |64-17-5 |10 - 30 | CASTOR OIL |8001-79-4 |10 - 30 | POLYVINYL RESIN |63148-65-2 |5 - 10 | 2-PROPANOL |67-63-0 |1 - 5 | TITANIUM DIOXIDE |13463-67-7 |1 - 5 | METHANOL |67-56-1 |1 - 5 | POLYTETRAFLUOROETHYLENE |9002-84-0 |1 - 5 | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Get medical advice/attention if you feel unwell. First-aid Measures After Inhalation: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. First-aid Measures After Skin Contact: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash with soap and water. If symptoms persist, call a physician. First-aid Measures After Eye Contact: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid Measures After Ingestion: IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: See section 2 for more information. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Note to physicians: Treat symptomatically. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media:Carbon dioxide (CO2), Dry chemical, Foam. Unsuitable Extinguishing Media: None. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Flammable. Keep product and empty container away from heat and sources of ignition. Explosion Hazard: Sensitivity to Mechanical Impact: None. Sensitivity to Static Discharge: None. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Protection During Firefighting: SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Remove all sources of ignition. Use personal protective equipment as required. Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological information. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up: Eliminate all ignition sources if safe to do so. Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Hygiene Measures: Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Store locked up. Incompatible materials: Strong oxidizing agents. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Exposure Guidelines: Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH TALC 14807-96-6 TWA: 2 mg/m3 particulate matter containing no asbestos and <1% crystalline silica, respirable fraction (vacated) TWA: 2 mg/m3 respirable dust <1% Crystalline silica, containing no Asbestos TWA: 20 mppcf if 1% Quartz or more, use Quartz limit IDLH: 1000 mg/m3 TWA: 2 mg/m3 containing no Asbestos and <1% Quartz respirable dust ETHANOL 64-17-5 STEL: 1000 ppm TWA: 1000 ppm TWA: 1900 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m3 IDLH: 3300 ppm TWA: 1000 ppm TWA: 1900 mg/m3 2-PROPANOL 67-63-0 STEL: 400 ppm TWA: 200 ppm TWA: 400 ppm TWA: 980 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 980 mg/m3 (vacated) STEL: 500 ppm (vacated) STEL: 1225 mg/m3 IDLH: 2000 ppm TWA: 400 ppm TWA: 980 mg/m3 STEL: 500 ppm STEL: 1225 mg/m3 TITANIUM DIOXIDE 13463-67-7 TWA: 10 mg/m3 TWA: 15 mg/m3 total dust (vacated) TWA: 10 mg/m3 total dust IDLH: 5000 mg/m3 METHANOL 67-56-1 STEL: 250 ppm TWA: 200 ppm S* TWA: 200 ppm TWA: 260 mg/m3 (vacated) TWA: 200 ppm (vacated) TWA: 260 mg/m3 (vacated) STEL: 250 ppm (vacated) STEL: 325 mg/m3 (vacated) S* IDLH: 6000 ppm TWA: 200 ppm TWA: 260 mg/m3 STEL: 250 ppm STEL: 325 mg/m3 Other Information: Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). 8.2. Exposure Controls Appropriate Engineering |Showers Controls |Eyewash stations |Ventilation systems. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Wear safety glasses with side shields (or goggles). Skin and Body Protection |Wear protective gloves and protective clothing. Respiratory Protection |Use NIOSH-approved air-purifying respirator with |organic vapor cartridge or canister, as |appropriate. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Paste Appearance |White Odor |Alcoholic Odor Threshold |No information available pH |No information available Relative Evaporation Rate |< 1 Butyl acetate = 1 (butylacetate=1) | Melting Point |No information available Freezing Point |No information available Boiling Point |82 °C / 180 °F Flash Point |23 °C / 74 °F Tag Closed Cup Auto-ignition Temperature |No information available Decomposition Temperature |No information available Flammability (solid, gas) |No information available Vapor Pressure |33 mm Hg @ 68°F Relative Vapor Density at 20 °C |>1 Air = 1 Relative Density |1.06-1.10 Specific Gravity | Solubility |Water solubility Partially soluble |Solubility in other solvents No information |available Partition coefficient: |No information available n-octanol/water | Viscosity |No information available Lower Flammable Limit |2.3% Upper Flammable Limit |12.7% 9.2. Other Information Softening point: No information available Molecular weight: No information available VOC Content (%): 36.7% Density: No information available Bulk density: No information available SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No data available. 10.2 Chemical Stability Stable under recommended storage conditions. 10.3 Possibility of Hazardous Reactions None under normal processing. 10.4 Conditions to Avoid Heat, flames and sparks. 10.5 Incompatible Materials Strong oxidizing agents. 10.6 Hazardous Decomposition Products Carbon oxides Fluorides. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: No information available. Germ Cell Mutagenicity: No information available. Carcinogenicity: The table below indicates whether each agency has listed any ingredient as a carcinogen. Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): Blood, Central nervous system, Central Vascular System (CVS), Eyes, Gastrointestinal tract (GI), Liver, Lungs, Reproductive System, Respiratory system, Skin. Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: Harmful by inhalation. Symptoms/Injuries After Skin Contact: May cause skin irritation and/or dermatitis. Symptoms/Injuries After Eye Contact: Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Symptoms/Injuries After Ingestion: May be harmful if swallowed. Chronic Symptoms: Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Ecotoxicity: 35.44605% of the mixture consists of components(s) of unknown hazards to the aquatic environment. Chemical Name Algae/aquatic plants Fish Crustacea TALC 14807-96-6 - 100: 96 h Brachydanio rerio g/L LC50 semi-static - ETHANOL 64-17-5 - 12.0 - 16.0: 96 h Oncorhynchus mykiss mL/L LC50 static 100: 96 h Pimephales promelas mg/L LC50 static 13400 - 15100: 96 h Pimephales promelas mg/L LC50 flow-through 9268 - 14221: 48 h Daphnia magna mg/L LC50 2: 48 h Daphnia magna mg/L EC50 Static 10800: 24 h Daphnia magna mg/L EC50 2-PROPANOL 67-63-0 1000: 96 h Desmodesmus subspicatus mg/L EC50 1000: 72 h Desmodesmus subspicatus mg/L EC50 11130: 96 h Pimephales promelas mg/L LC50 static 9640: 96 h Pimephales promelas mg/L LC50 flow-through 1400000: 96 h Lepomis macrochirus ?g/L LC50 13299: 48 h Daphnia magna mg/L EC50 METHANOL 67-56-1 - 28200: 96 h Pimephales promelas mg/L LC50 flow-through 100: 96 h Pimephales promelas mg/L LC50 static 19500 - 20700: 96 h Oncorhynchus mykiss mg/L LC50 flow-through 13500 - 17600: 96 h Lepomis macrochirus mg/L LC50 flow-through 18 - 20: 96 h Oncorhynchus mykiss mL/L LC50 static - 12.2. Persistence and Degradability No information available. 12.3. Bioaccumulative Potential No information available. 12.4. Mobility in Soil No information available. Chemical Name Partition coefficient ETHANOL 64-17-5 -0.32 2-PROPANOL 0.05 67-63-0 METHANOL -0.77 67-56-1 12.5. Other Adverse Effects No information available. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Additional Information: Contaminated packaging: Do not reuse container. US EPA Waste Number: D001 Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes METHANOL 67-56-1 - Included in waste stream: F039 - U154 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status ETHANOL 64-17-5 Toxic Ignitable 2-PROPANOL 67-63-0 Toxic Ignitable METHANOL 67-56-1 Toxic Ignitable SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Adhesives, Limited Quantity (LQ) Hazard Class |3 |
Identification Number|UN1133 | Label Codes | | ERG Number |128 14.2 In Accordance with IMDG Proper Shipping Name |Adhesives, Limited Quantity (LQ) Hazard Class |3 Identification Number|UN1133 Label Codes | | ntification Of The | | Substance/m | | EmS-No. (Fire) |F-E | EmS-No. (Spillage) |S-D | 14.3 In Accordance with IATA Proper Shipping Name |Consumer commodity Identification Number|ID 8000 | Hazard Class |9 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) |9L SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations SARA 313: Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. Chemical Name SARA 313 - Threshold Values % 2-PROPANOL - 67-63-0 1.0 METHANOL - 67-56-1 1.0 CWA (Clean Water Act): This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). CERCLA: This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302). Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) METHANOL 67-56-1 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ SARA Section 311/312 Hazard Classes |Acute health hazard Yes |Chronic Health Hazard No |Fire hazard Yes |Sudden release of pressure hazard No |Reactive Hazard No Toxic Substances Control Act (TSCA) |Complies 15.2 US State Regulations California Proposition 65: This product contains the following Proposition 65 chemicals. Chemical Name California Proposition 65 ETHANOL - 64-17-5 Carcinogen Developmental TITANIUM DIOXIDE - 13463-67-7 Carcinogen METHANOL - 67-56-1 Developmental Carcinogen METHYL ISOBUTYL KETONE - 108-10-1 Developmental U.S. State Right-to-Know Regulations: Chemical Name New Jersey Massachusetts Pennsylvania TALC 14807-96-6 X X X ETHANOL X X X 64-17-5 2-PROPANOL X X X 67-63-0 TITANIUM DIOXIDE 13463-67-7 X X X WATER - - X 7732-18-5 METHANOL X X X 67-56-1 POLYTETRAFLUOROETHYLENE - - X 9002-84 METHYL ISOBUTYL KETONE 108-10-1 X X X U.S. EPA Label Information: EPA Pesticide Registration Number: Not applicable. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |24-Apr-2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.