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SDS Sheet 0076050

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SECTION 1: IDENTIFICATION                                                       
 


1.1.  Product Identifier
Product Form:                                                                   
 
Product Name: Marvel Air Tool Oil                                               
 
CAS No:                                                                         
 
Synonyms:                                                                       
 


1.2.  Intended Use of the Product
Use of the substance/mixture: Engine Oil Additive - Fuel additive (EPA
Registered)


1.3.  Name, Address, and Telephone of the Responsible Party
Company                                                                         
 
Marvel Oil Company, Inc.                                                        
 
625 Willowbrook Centre Parkway                                                  
 
Willowbrook, Illinois 60527                                                     
 
Phone: 1(630)455-3700                                                           
 


1.4.  Emergency Telephone Number
Emergency     |Phone Number: 1(630)455-3700                                     
 
number        |Fax Number: 1(630)455-3868                                       
 
              |Transportation: 1(800)424-9300 (CHEMTREC)                        
 
              |Medical Assistance: Call your local Poison Control Center        
 

SECTION 2: HAZARDS IDENTIFICATION                                               
 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Flammable     |3             
liquid        |              
Skin          |2             
irritation    |              
Reproductive  |2             
Toxicity      |              
Aspiration    |1             
toxicity      |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Flame |Exclamation Mark |Health Hazard
       
Signal Word (GHS-US)         |Danger                                            
 
Hazard Statements (GHS-US)   |Flammable liquid and vapor. Causes skin
irritation. 
                             |Suspected of damaging fertility of the un-born    
 
                             |child. May be fatal if swallowed and enters
airways.
Precautionary Statements     |Keep away from heat, sparks, open flames or hot   
 
(GHS-US)                     |surfaces. Do not smoke. Keep containers tightly   
 
                             |closed. Ground all containers and receiving       
 
                             |equipment. Use explosion proof electrical,        
 
                             |ventilation, and lighting equipment. Use only     
 
                             |non-sparking tools. Take precautionary measures   
 
                             |against static discharge. Wear protective gloves, 
 
                             |clothing, eye glasses and face shield. Do not
handle
                             |until all safety precautions have been read and   
 
                             |understood. Wash hands thoroughly after handling.
If
                             |exposed, get medical attention. If on skin or
hair, 
                             |remove immediately all contaminated clothing and  
 
                             |launder before re-use. Wash skin with soap and    
 
                             |water. If skin irritation occurs, get medical     
 
                             |attention. If swallowed, immediately call a poison
 
                             |control center or doctor. Do NOT induce vomiting. 
 
                             |Store in a well ventilated place. Dispose of      
 
                             |contents and container in accordance with all
local,
                             |state, national and international regulations.    
 


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification: None                      
 


2.4.  Unknown Acute Toxicity (GHS-US)
                                                                                
 

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                               
 


3.1.  Substance
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
Petroleum Distillates           |64742-52-5           |60-100% |                
 
(Hydrotreated Heavy Naphthenic) |                     |        |                
 
Petroleum Distillates (Stoddard |8052-41-3            |10-30%  |                
 
Solvent)                        |                     |        |                
 
Tricresyl Phosphate             |1330-78-5            |0.1-1.0%|                
 
Ortho Dichlorobenzene           |95-50-1              |0.1-1.0%|                
 
Para Dichlorobenzene            |106-46-7             |<0.1%   |                
 


SECTION 4: FIRST AID MEASURES                                                   
 


4.1.  Description of First Aid Measures
First-aid Measures General:                                                     
 
First-aid Measures After Inhalation: Remove to fresh air and promote deep       
 
breathing. Get medical attention if effects persist or you feel un-well.        
 
First-aid Measures After Skin Contact: In case of skin contact, wash thoroughly 
 
with soap and water. Remove contaminated clothing and footwear. Launder clothing
 
before re-use. Call a physician if irritation develops or persists.             
 
First-aid Measures After Eye Contact: In case of eye contact, immediately flush 
 
eyes with plenty of water. Remove contact lenses if worn. If irritation
persists, 
get medical attention                                                           
 
First-aid Measures After Ingestion: If swallowed, do not induce vomiting. Never 
 
give anything by mouth to an unconscious person. Immediately call a poison
control
center or physician.                                                            
 


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries:                                                              
 
Symptoms/Injuries After Inhalation: May cause respiratory tract irritation.
Vapors
may cause drowsiness or dizziness.                                              
 
Symptoms/Injuries After Skin Contact: Cause skin irritation. Symptoms may
include 
redness, edema, drying, defatting, and cracking of skin.                        
 
Symptoms/Injuries After Eye Contact: May cause temporary eye irritation.
Symptoms 
may include discomfort or pain, excess blinking and tearing, with redness and   
 
swelling.                                                                       
 
Symptoms/Injuries After Ingestion: May be fatal if swallowed and enters airways.
 
This product may be aspirated into the lungs and cause chemical pneumonitis. May
 
cause stomach distress, nausea, and vomiting.                                   
 
Chronic Symptoms:                                                               
 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
Symptoms may not appear immediately. Seek medical attention if effects develop
or 
persist and you feel un-well.                                                   
 

SECTION 5: FIRE-FIGHTING MEASURES                                               
 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Carbon dioxide, dry chemical, and alcohol foam    
 
Unsuitable Extinguishing Media:                                                 
 


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: CO2, CO, and hydrocarbons                                          
 
Explosion Hazard:                                                               
 
Reactivity:                                                                     
 


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                    
 
Firefighting Instructions: Keep up wind of fire. Wear full firefighting turn out
 
gear (full bunker gear) and respiratory protection (SCBA). Cool closed
containers 
exposed to fire with water. See Section 8 for personal protection.              
 
Protection During Firefighting:                                                 
 

SECTION 6: ACCIDENTAL RELEASE MEASURES                                          
 


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Use personal protection recommended in Section 8. Isolate the 
 
hazard area and deny entry to unnecessary and unprotected personnel. Eliminate
all
source of ignition.                                                             
 


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.1.2.      For Emergency Responders
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.2.  Environmental Precautions
                                                                                
 


6.3.  Methods and Material for Containment and Cleaning Up
For Containment: Contain and absorb spill with inert material. Place in suitable
 
container for disposal. Do not flush to sewer or allow to enter waterways. See  
 
section 8 for PPE.                                                              
 
Methods for Cleaning Up: Take up material and place in a suitable container.    
 
Vapors may be heavier than air and may travel along the ground to a distant
source
of ignition. Provide adequate ventilation.                                      
 


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                      
 


SECTION 7: HANDLING AND STORAGE                                                 
 


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Keep away from source of ignition. Do not    
 
smoke. Take precaution to eliminate static discharge. Avoid contact with skin
and 
eyes. Avoid breathing vapor or mist. Do not swallow. Do not eat or drink while  
 
handling. Wash hands with soap and water after handling. Use only non-sparking  
 
tools.                                                                          
 
Hygiene Measures:                                                               
 


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                             
 
Storage Conditions: Keep out of reach of children. Store in a well ventilated   
 
place. Do not store above 49°C (120°F).                                         
 


7.3.  Specific End Use(s)
Shelf Life: Shelf life is considered to be 7 - 10 years when properly stored.   
 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                
 


8.1.  Control Parameters
Exposure Limits             8 hr TWA:                                           
 
(OSHA PEL)                                (ACGIH TWA)                           
 
Petroleum Distillates (Hydrotreated Heavy                         not applicable
 
not applicable                                                                  
 
Naphthenic)                                                                     
 
Petroleum Distillates (Stoddard Solvent)                             500 ppm    
 
100 ppm                                                                         
 
Tricresyl Phosphate                                                             
 
not applicable                           not applicable                         
 
Ortho Dichlorobenzene                                                          
50
ppm                                       25 ppm                                
 
Para Dichlorobenzene                                                            
 
75 ppm                                       10 ppm                             
 
                                                                                
 


8.2.  Exposure Controls
Appropriate Engineering      |Use adequate ventilation to keep exposure below   
 
Controls                     |recommended limits. Ensure that eye wash station
and
                             |safety shower are close to work station.          
 
Personal Protective Equipment|                                                  
 
Materials for Protective     |                                                  
 
Clothing                     |                                                  
 
Hand Protection              |Wear chemical resistant gloves to prevent skin    
 
                             |contact.                                          
 
Eye Protection               |Wear safety glasses or splash goggles to prevent
eye
                             |contact.                                          
 
Skin and Body Protection     |Wear suitable protective clothing.                
 
Respiratory Protection       |Provide good ventilation.                         
 
Thermal Hazard Protection    |                                                  
 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                     
 


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |thin liquid                                
 
Appearance                          |                                           
 
Odor                                |typical oily                               
 
Odor Threshold                      |not available                              
 
pH                                  |not applicable - oil based product         
 
Relative Evaporation Rate           |not available                              
 
(butylacetate=1)                    |                                           
 
Melting Point                       |-51?C (-60?F)                              
 
Freezing Point                      |-51?C (-60?F)                              
 
Boiling Point                       |not available                              
 
Flash Point                         |53?C (128?F)                               
 
Auto-ignition Temperature           |not available                              
 
Decomposition Temperature           |                                           
 
Flammability (solid, gas)           |not applicable                             
 
Vapor Pressure                      |not available                              
 
Relative Vapor Density at 20 °C     |not available                              
 
Relative Density                    |                                           
 
Specific Gravity                    |0.876                                      
 
Solubility                          |Insoluble (Water)                          
 
Partition coefficient:              |not available                              
 
n-octanol/water                     |                                           
 
Viscosity                           |2.0 - 3.0 cSt                              
 
Lower Flammable Limit               |not available                              
 
Upper Flammable Limit               |not available                              
 


9.2.  Other Information
% NVM by Weight:                75.0%                                           
 
% VOC Content (California): 24.92%                                              
 

SECTION 10: STABILITY AND REACTIVITY                                            
 


10.1      Reactivity
Does not react under normal conditions                                          
 


10.2      Chemical Stability
Stable                                                                          
 


10.3      Possibility of Hazardous Reactions
Does not react under normal conditions                                          
 


10.4      Conditions to Avoid
Heat and incompatible materials                                                 
 


10.5      Incompatible Materials
Strong oxidizers such as bleach and peroxides                                   
 


10.6      Hazardous Decomposition Products
CO2, CO and hydrocarbons                                                        
 

SECTION 11: TOXICOLOGICAL INFORMATION                                           
 


11.1. Information on Toxicological Effects
Acute Toxicity:                                                                 
 
Skin Corrosion/Irritation: Causes skin irritation                               
 
Serious Eye Damage/Irritation: Based on available data, classification data are 
 
not met                                                                         
 
Respiratory or Skin Sensitization: Based on available data, classification data 
 
are not met                                                                     
 
Germ Cell Mutagenicity: Based on available data, classification data are not met
 
Carcinogenicity: Based on available data, classification data are not met       
 
o-Dichlorobenzene (95-50-1)             IARC Group 3 - Not Classified           
 
p-dichlorobenzene (106-46-7)           IARC Group 2B - Possible carcinogen to   
 
humans.                                                                         
 
NTP 1-Evidence of Carcinogenicity 3, Reasonably anticipated to be a human       
 
Carcinogen                                                                      
 
Reproductive Toxicity: Suspected of damaging fertility of un-born child         
 
Specific Target Organ Toxicity (Single Exposure): Based on available data,      
 
classification data are not met                                                 
 
Specific Target Organ Toxicity (Repeated Exposure): Based on available data,    
 
classification data are not met                                                 
 
Aspiration Hazard: May be fatal if swallowed and enters air ways.               
 
Symptoms/Injuries After Inhalation: May cause respiratory tract irritation.
Vapors
may cause drowsiness and dizziness.                                             
 
Symptoms/Injuries After Skin Contact: Cause skin irritation. Symptoms may
include 
redness, edema, drying, defatting, and cracking of skin.                        
 
Symptoms/Injuries After Eye Contact: May cause temporary eye irritation.
Symptoms 
may include discomfort or pain, excess blinking and tearing, with redness and   
 
swelling.                                                                       
 
Symptoms/Injuries After Ingestion: May be fatal if swallowed and enters airways.
 
This product may be aspirated into the lungs and cause chemical pneumonitis. May
 
cause stomach distress, nausea, and vomiting.                                   
 
Chronic Symptoms:                                                               
 

SECTION 12: ECOLOGICAL INFORMATION                                              
 


12.1. Toxicity
Not recommended for release into aquatic systems without treatment              
 


12.2. Persistence and Degradability
Not established                                                                 
 


12.3. Bioaccumulative Potential
Not established                                                                 
 


12.4. Mobility in Soil
Not established                                                                 
 


12.5. Other Adverse Effects
None known                                                                      
 

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations:                                                 
 
Waste Disposal Method: Dispose of in accordance with local, state and federal   
 
regulations                                                                     
 
Waste Disposal Vessel: Metal drums are recommended.                             
 
Additional Information:                                                         
 

SECTION 14: TRANSPORT INFORMATION                                               
 


14.1 In Accordance with DOT
Proper Shipping Name |                                                          
 
Hazard Class         |                       |                
 
Identification Number|                       |                                  
 
Label Codes          |                       |                                  
 
ERG Number           |                                                          
 


14.2 In Accordance with IMDG
Proper Shipping Name |                                                          
 
Hazard Class         |                                                          
 
Identification Number|                                                          
 
Label Codes          |                      |                 
 
ntification Of The   |                      |                                   
 
Substance/m          |                      |                                   
 
EmS-No. (Fire)       |                      |                                   
 
EmS-No. (Spillage)   |                      |                                   
 


14.3 In Accordance with IATA
Proper Shipping Name |                                                          
 
Identification Number|                       |                
  
Hazard Class         |                       |                                  
  
Label Codes          |                       |                                  
  
ntification Of The   |                       |                                  
  
Substance/m          |                       |                                  
  
ERG Code (IATA)      |                                                          
 

SECTION 15: REGULATORY INFORMATION                                              
 

15.1      US Federal Regulations
                                                                     
 
SARA Section 311/312 Hazard Classes |                                           
 
Toxic Substances Control Act (TSCA) |All ingredients are commercially available 
 
                                    |and listed by the manufacturer under TSCA. 
 

15.2      US State Regulations
                                                                     
 
The following chemicals are specifically listed by individual states; other     
 
product specific health and safety data in other sections of the SDS may also be
 
applicable for state requirements. For details on your regulatory requirements, 
 
contact the appropriate agency in your state.                                   
 
California Prop 65:                                                             
 
CAS Number                                             Concentration            
 
State Code                                                                      
 
p-Dichlorobenzene (106-46-7)             <0.1%                                  
 
Cancer                                                                          
 
                                                                                
 

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION   
 

Revision date   |March 10, 2015                                                 
 
Other           |This document has been prepared in accordance with the SDS     
 
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR  
 
                |1910.1200.                                                     
 
GHS Full Text Phrases:                                                          
 
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Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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