MSDS Sheet 0052752

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Material Safety Data Sheet                                                      
Date of Issue: |Revision Date: March 2015  |Revision Number:        
Imperial Supplies Part Number: 0052752                                          

SECTION 1: IDENTIFICATION                                                       

1.1.  Product Identifier
Product Form:                                                                   
Product Name: Energizer Battery                                                 
CAS No:                                                                         

1.2.  Intended Use of the Product
Use of the substance/mixture:                                                   

1.3.  Name, Address, and Telephone of the Responsible Party
Energizer Battery Manufacturing, Inc.                                           
25225 Detroit Rd.                                                               
Westlake, OH 44145                                                              
Phone: 800-383-7323                                                             

1.4.  Emergency Telephone Number
Emergency     |                                                                 
number        |                                                                 

SECTION 2: HAZARDS IDENTIFICATION                                               

2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
N/A           |              

2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |        |        |        |        |        |     
Signal Word (GHS-US)         |N/A                                               
Hazard Statements (GHS-US)   |                                                  
Precautionary Statements     |                                                  
(GHS-US)                     |                                                  

2.3.  Other Hazards
Other Hazards Not Contributing to the Classification:                           

2.4.  Unknown Acute Toxicity (GHS-US)


3.1.  Substance
Name                            |Product identifier   |%       |Classification  
                                |                     |        |(GHS-US)        
                                |                     |        |                
                                |                     |        |                
                                |                     |        |                
                                |                     |        |                
                                |                     |        |                

Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification  
                                |                     |        |(GHS-US)        
Carbon Black                    |1333-86-4            |0-1     |                
1,2-Dimethoxyethane             |110-71-4             |0-6     |                
1,3-Dioxolane                   |646-06-0             |0-8     |                
Graphite                        |7782-42-5            |0-3     |                
Lithium or Lithium Alloy        |7439-93-2            |1-6     |                
Lithium                         |33454-82-9           |0-3     |                
Trifluoromethanesulfonate       |                     |        |                
Lithium                         |90076-65-6           |0-3     |                
Trifluoromethanesulfonimide     |                     |        |                
Manganese Dioxide               |1313-13-9            |12-42   |                
Propylene Carbonate             |108-32-7             |0-8     |                
Non-Hazardous Components:       |                     |        |                
Steel (iron)                    |65997-19-5           |20      |                
Plastic and Other               |                     |Balance |                

SECTION 4: FIRST AID MEASURES                                                   

4.1.  Description of First Aid Measures
First-aid Measures General:                                                     
First-aid Measures After Inhalation: Immediately flush eyes thoroughly with
for at least 15 minutes, lifting upper and lower lids, until no evidence of the 
chemical remains. Seek medical attention.                                       
First-aid Measures After Skin Contact: Remove contaminated clothing and wash
with soap and water.                                                            
First-aid Measures After Eye Contact: Immediately flush eyes thoroughly with
for at least 15 minutes, lifting upper and lower lids, until no evidence of the 
chemical remains. Seek medical attention.                                       
First-aid Measures After Ingestion: Do not induce vomiting or give food or

4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries After Inhalation:                                             
Symptoms/Injuries After Skin Contact:                                           
Symptoms/Injuries After Eye Contact:                                            
Symptoms/Injuries After Ingestion:                                              
Chronic Symptoms:                                                               

4.3.  Indication of Any Immediate Medical Attention and Special Treatment

SECTION 5: FIRE-FIGHTING MEASURES                                               

5.1.  Extinguishing Media
Suitable Extinguishing Media:                                                   
Unsuitable Extinguishing Media:                                                 

5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: In case of fire where lithium batteries are present, flood area
water or smother with a Class D fire extinguishant appropriate for lithium
such as Lith-X. Water may not extinguish burning batteries but will cool the    
adjacent batteries and control the spread of fire. Burning batteries will burn  
themselves out. Virtually all fires involving lithium batteries can be
by flooding with water. However, the contents of the battery will react with
and form hydrogen gas. In a confined space, hydrogen gas can form an explosive  
mixture. In this situation, smothering agents are recommended. A smothering
will extinguish burning lithium batteries.                                      
Emergency Responders should wear self-contained breathing apparatus. Burning    
lithium manganese dioxide batteries produce toxic and corrosive lithium
Explosion Hazard:                                                               

5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                    
Firefighting Instructions:                                                      
Protection During Firefighting:                                                 

SECTION 6: ACCIDENTAL RELEASE MEASURES                                          

6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures:                                                               

6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                           
Emergency Procedures:                                                           

6.1.2.      For Emergency Responders
Protective Equipment:                                                           
Emergency Procedures:                                                           

6.2.  Environmental Precautions

6.3.  Methods and Material for Containment and Cleaning Up
For Containment: Mechanical Containment: If potting or sealing the battery in an
airtight or watertight container is required, consult your Energizer Battery    
Manufacturing, Inc. representative for precautionary suggestions. Do not
safety release vents on batteries. Encapsulation of batteries will not allow
venting and can cause high pressure rupture.                                    
Methods for Cleaning Up: To cleanup leaking batteries:                          
Ventilation Requirements: Room ventilation may be required in areas where there 
are open or leaking batteries. Respiratory Protection: Avoid exposure to        
electrolyte fumes from open or leaking batteries. Eye Protection: Wear safety   
glasses with side shields if handling an open or leaking battery. Gloves: Use   
neoprene or natural rubber gloves if handling an open or leaking battery.
materials should be collected in a leak-proof container.                        

6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                      

SECTION 7: HANDLING AND STORAGE                                                 

7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Accidental short circuit for a few seconds
not seriously affect the battery. Prolonged short circuit will cause the battery
to lose energy, generate significant heat and can cause the safety release vent
open. Sources of short circuits include jumbled batteries in bulk containers,   
metal jewelry, metal covered tables or metal belts used for assembly of
into devices. Damaging a lithium battery may result in an internal short
The contents of an open battery, including a vented battery, when exposed to    
water, may result in a fire and/or explosion. Crushed or damaged batteries may  
result in a fire.                                                               
If soldering or welding to the battery is required, consult your Energizer      
representative for proper precautions to prevent seal damage or short circuit.  
Charging: This battery is manufactured in a charged state. It is not designed
recharging. Recharging can cause battery leakage or, in some cases, high
rupture. Inadvertent charging can occur if a battery is installed backwards.    
Labeling: If the Energizer label or package warnings are not visible, it is     
important to provide a package and/or device label stating:                     
WARNING: Battery can explode or leak and cause burns if installed backwards,    
disassembled, charged, or exposed to water, fire or high temperature.           
Where accidental ingestion of small batteries is possible, the label should     
(1) KEEP OUT OF REACH OF CHILDREN. Swallowing may lead to serious injury or
in as little as 2 hours due to chemical burns and potential perforation of the  
esophagus. Immediately see doctor; have doctor phone (202) 625-3333. Keep in    
original package until ready to use. Dispose of used batteries immediately.     
Hygiene Measures:                                                               

7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                             
Storage Conditions: Store in a cool, well ventilated area. Elevated temperatures
can result in shortened battery life. In locations that handle large quantities
lithium batteries, such as warehouses, lithium batteries should be isolated from
unnecessary combustibles.                                                       

7.3.  Specific End Use(s)


8.1.  Control Parameters

8.2.  Exposure Controls
Appropriate Engineering      |                                                  
Controls                     |                                                  
Personal Protective Equipment|                                                  
Materials for Protective     |Gloves: Not necessary under normal conditions.    
Clothing                     |                                                  
Hand Protection              |                                                  
Eye Protection               |Not necessary under normal conditions.            
Skin and Body Protection     |                                                  
Respiratory Protection       |Not necessary under normal conditions.            
Thermal Hazard Protection    |                                                  

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                     

9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |Solid                                      
Appearance                          |Solid object                               
Odor                                |No odor                                    
Odor Threshold                      |No odor                                    
pH                                  |Not applicable for an Article.             
Relative Evaporation Rate           |Not applicable for an Article.             
(butylacetate=1)                    |                                           
Melting Point                       |Not applicable for an Article.             
Freezing Point                      |Not applicable for an Article.             
Boiling Point                       |Not applicable for an Article.             
Flash Point                         |Not applicable for an Article.             
Auto-ignition Temperature           |Not applicable for an Article.             
Decomposition Temperature           |Not applicable for an Article.             
Flammability (solid, gas)           |Not applicable for an Article.             
Vapor Pressure                      |Not applicable for an Article.             
Relative Vapor Density at 20 °C     |Not applicable for an Article.             
Relative Density                    |                                           
Specific Gravity                    |                                           
Solubility                          |Not applicable for an Article.             
Partition coefficient:              |Not applicable for an Article.             
n-octanol/water                     |                                           
Viscosity                           |Not applicable for an Article.             
Lower Flammable Limit               |Not applicable for an Article.             
Upper Flammable Limit               |Not applicable for an Article.             

9.2.  Other Information

SECTION 10: STABILITY AND REACTIVITY                                            

10.1      Reactivity
Lithium manganese dioxide batteries contain no sulfides or cyanides and they do 
not meet any other reactivity criteria including "reacts violently with water"
therefore do not meet any of the criteria established in 40 CFR 261.2 for       

10.2      Chemical Stability

10.3      Possibility of Hazardous Reactions

10.4      Conditions to Avoid

10.5      Incompatible Materials

10.6      Hazardous Decomposition Products

SECTION 11: TOXICOLOGICAL INFORMATION                                           

11.1. Information on Toxicological Effects
Acute Toxicity: Under normal conditions of use, lithium manganese dioxide       
batteries are non-toxic.                                                        
Skin Corrosion/Irritation:                                                      
Serious Eye Damage/Irritation:                                                  
Respiratory or Skin Sensitization:                                              
Germ Cell Mutagenicity:                                                         
Reproductive Toxicity:                                                          
Specific Target Organ Toxicity (Single Exposure):                               
Specific Target Organ Toxicity (Repeated Exposure):                             
Aspiration Hazard:                                                              
Symptoms/Injuries After Inhalation:                                             
Symptoms/Injuries After Skin Contact:                                           
Symptoms/Injuries After Eye Contact:                                            
Symptoms/Injuries After Ingestion:                                              
Chronic Symptoms:                                                               

SECTION 12: ECOLOGICAL INFORMATION                                              

12.1. Toxicity
Issues such as ecotoxicity, persistence and bioaccumulation are not applicable

12.2. Persistence and Degradability

12.3. Bioaccumulative Potential

12.4. Mobility in Soil

12.5. Other Adverse Effects

13.1. Waste treatment methods
Waste Disposal Recommendations: Lithium iron disulfide batteries are not
waste per the United States Resource Conservation and Recovery Act (RCRA) - 40
Part 261 Subpart C. Dispose of in accordance with all applicable federal, state 
and local regulations.                                                          
Additional Information:                                                         

SECTION 14: TRANSPORT INFORMATION                                               

14.1 In Accordance with DOT
Proper Shipping Name |                                                          
Hazard Class         |                       |                
Identification Number|                       |                                  
Label Codes          |                       |                                  
ERG Number           |                                                          

14.2 In Accordance with IMDG
Proper Shipping Name |                                                          
Hazard Class         |                                                          
Identification Number|                                                          
Label Codes          |                      |                 
ntification Of The   |                      |                                   
Substance/m          |                      |                                   
EmS-No. (Fire)       |                      |                                   
EmS-No. (Spillage)   |                      |                                   

14.3 In Accordance with IATA
Proper Shipping Name |                                                          
Identification Number|                       |                
Hazard Class         |                       |                                  
Label Codes          |                       |                                  
ntification Of The   |                       |                                  
Substance/m          |                       |                                  
ERG Code (IATA)      |                                                          

SECTION 15: REGULATORY INFORMATION                                              

15.1      US Federal Regulations
Outside of the transportation requirements noted in Section 14, lithium
dioxide batteries marketed by Energizer Battery Manufacturing, Inc. are not     
SARA/TITLE III - As an article, this battery and its contents are not subject to
the requirements of the Emergency Planning and Community Right-To-Know Act.     
SARA Section 311/312 Hazard Classes |                                           
Toxic Substances Control Act (TSCA) |                                           

15.2      US State Regulations


Revision date   |                                                               
Other           |This document has been prepared in accordance with the SDS     
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR  
GHS Full Text Phrases:                                                          
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Grainger disclaimer.

The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'MSDS' shall be created or inferred by any statement in this 'MSDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'MSDS'. The user is responsible for full compliance.